Angewandte Chemie International Edition
Articles in this Issue
Catalytic C–F Bond Activation at Room Temperature: Enolate Cross‐Couplings Enabled by [Pd(1‐MeNAP)TFA] <sub>2</sub> and LiHMDS
ABSTRACT Due to their exceptional stability, only few transition metal catalysts are capable of activating C─F bonds for C–C‐coupling reactions, usually under ha...
Water Is Not Universally Promotional: Size‐Dependent Inversion of Water Effects in Methanol Steam Reforming
ABSTRACT Water is widely assumed to be universally promotional in methanol steam reforming. Here, we show that this assumption fails when metal nuclearity and su...
Additive‐Free, Efficient, and Stable All‐Polymer Solar Cells Enabled by Congeneric Molecule Construction for Integrated Solar‐Storage Applications
ABSTRACT Organic solar cells are attractive for wearable electronics, in particular, all‐polymer solar cells (all‐PSCs) offer superior intrinsic stability and hi...
Supramolecular Polymer‐Surfactant Co‐Assemblies for Multivalent HSV‐1 Inhibition
ABSTRACT Supramolecular assemblies are of fundamental importance for cellular life and bio‐interactive materials. The structure and function of these assemblies...
Palladium‐Catalyzed Annulations of an Anti‐Bredt Olefin
ABSTRACT A famous class of alkene‐containing compounds that have intrigued chemists for more than a century are anti‐Bredt olefins (ABOs). ABOs are a subclass of bridgehead alkenes t...
Leveraging the Enantiomeric Excess of Catalyst for Precise Stereocontrol in Poly(3‐hydroxybutyrate)
ABSTRACT The properties of polymers are governed by multi‐level structural parameters, with tacticity being particularly critical for crystallization, thermal, a...
Isotope‐Labeled Methanol‐Derived <i>O</i> ‐Alkylisoureas as Versatile and Practical Agents for d <sub>3</sub> ‐Methylation, <sup>13</sup> C‐Methylation, and <sup>13</sup> CD <sub>3</sub> ‐Methylation
ABSTRACT The development of highly efficient and practical methods for the incorporation of stable isotopes into organic molecules are valuable for the pharmaceu...
Proximal Ir–Ir Cooperativity for Reprogramming the CO <sub>2</sub> ‐to‐DMF Hydrogenation Pathway
ABSTRACT The hydrogenation of CO 2 to N , N...
Ligand‐Enabled Chemical‐Potential Modulation of A‐Site Cation Reactivity Stabilizes Tin Halide Perovskite Nanocrystals
ABSTRACT Tin halide perovskite nanocrystals offer a lead‑free platform for optoelectronics, but their practical use is severely hampered by rapid oxidation degra...
Excited‐State Conformational Dynamics Enables Visible‐Light‐Activated Near‐Infrared Phosphorescent Nano‐Assemblies for Bioimaging
ABSTRACT Visible‐light‐excited near‐infrared ultralong organic phosphorescence (NIR‐UOP), has attracted increasing attention due to its unique advantages. Howeve...
Expanding the Design Rules for Discriminating Nucleic Acid Mutations via Mismatch‐Exchange
ABSTRACT Complementarity between nucleic acids via Watson–Crick base pairing formulates the basic principle for designing hybridization probes but often suffers low sequence selectiv...
Topological Isomerism of Möbius‐Shaped Aramide Macrocycles Induced by Host‐Guest Interactions
ABSTRACT In contrast to traditional Möbius molecules characterized by fully conjugated backbones, synthetic amide‐linked Möbius‐shaped macrocycles represent a hi...
Hydrogen‐Bond‐Induced Switching of Interaction Hierarchy in Dipolar D–A Chromophores for NIR Circularly Polarized Photodetection
ABSTRACT Dipolar donor–acceptor (D–A) chromophores exhibit strong near‐infrared (NIR) absorption but are intrinsically biased toward electrostatically complementary hetero‐associatio...
Correlating Electronic Transition With Electrical Output to Reveal Photon‐Mediated Energy Conversion Mechanism in Inner‐Shell Electron Battery
ABSTRACT Inner‐shell electron batteries present a promising route to ultrahigh‐density energy storage by harnessing the potential energy confined within inner‐sh...
Corannulene‐Driven Curvature Engineering Enhances Fullerene Encapsulation in a Carbon Nanohoop
ABSTRACT Integrating intrinsically positively curved polycyclic aromatic hydrocarbons (PAHs) into cycloparaphenylene (CPP) frameworks remains challenging. In thi...
Unperturbed π‐Methyl Electrostatic Interactions Enable Efficient Toluene Adsorption on Graphdiyne Under High Humidity
ABSTRACT The efficiency of volatile organic compounds (VOCs) abatement in humid industrial streams is critically hindered by competitive moisture adsorption and the structural vulner...
A Homoleptic Ga <sub>4</sub> Radical Anion: Isolation, Characterization, and Reactivity
ABSTRACT We report the synthesis and characterization of a homoleptic Ga 4 radical anion ([Li +...
Zero‐Valent Nickel Stabilized in Surface‐Supported Metal–Organic Chains
ABSTRACT The stabilization of zero‐valent nickel Ni(0) centers in extended coordination networks remains a major challenge due to their pronounced reactivity and susceptibility to ox...
A Programmable and Printable Microbial Bioelectronic Sensor for Real‐Time and Targeted Pollutant Monitoring in Water
ABSTRACT Rapid detection of toxic trace contaminants is critical for global water security, yet routine monitoring relies on costly, time‐consuming laboratory an...
Bis‐ <i>S</i> ‐Glycosylation of Disulfides
ABSTRACT Carbohydrates play essential roles throughout biology, making them key targets in biological research and drug development. While multivalent presentati...
Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal
ABSTRACT The pursuit of high‐performance infrared nonlinear optical crystals is perpetually constrained by the inherent trade‐offs among second‐harmonic generati...
Beyond Canonical CO Oxidation: Structural and Evolutionary Insights Into a Non‐Canonical Carbon Monoxide Dehydrogenase
ABSTRACT Carbon monoxide dehydrogenases (CODHs) catalyse the reversible oxidation of CO to CO 2 and play central roles in...
Processable Inverse‐Vulcanized Polymers With Silicon‐Like High Refractive Index and Transmittance for Infrared Optics
ABSTRACT Polymers prepared by inverse vulcanization have demonstrated overwhelming superiority over traditional organic materials for application as infrared opt...
Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture
ABSTRACT The reversible molecular motions of mechanically interlocked molecules (MIMs) have played a crucial role in realizing stimuli‐responsive functions. While the reversible swit...
Mimicking Enzyme Activation Within an Ionic Liquid‐Immobilized Coordination Capsules for Electroreduction of N <sub>2</sub> to NH <sub>3</sub>
ABSTRACT Electrochemical nitrogen reduction powered by renewable electricity plays a crucial role in sustainable and eco‐friendly ammonia (NH...