Angewandte Chemie International Edition
Articles in this Issue
Ultrafast Single Electron Transfer Enables General Visible Light C─X (S, SS, Se) Coupling via Carbonyl Activation
Abstract The formation of carbon─heteroatom bonds is a key strategy that enables the modular construction of molecules in synthetic chemistry, but activating ine...
A Photo‐ and Cobalt‐Catalyzed Enantioselective Hydroamination of Unactivated Alkenes with Amines
Abstract The transition‐metal‐catalyzed direct enantioselective addition of N─H bonds to unactivated alkenes is of great significance as it creates high‐value‐ad...
An Intrinsically Conductive Cross‐Conjugated Polymer with a Quinhydrone‐Like Donor–Acceptor Charge‐Transfer Network
Abstract Intrinsically conductive polymers free of unstable mobile dopants are highly sought after for stable and reliable electronic performance, yet remain sca...
Substituent‐Generated Electric Fields and Ligand Non‐Innocence Drive the Record‐High Efficiency of Iron Tetraphenylporphyrin Catalysts for CO <sub>2</sub> ‐to‐CO Conversion
Abstract Electrochemical CO 2 ‐to‐CO conversion is a critical step in sustainable catalysis, with iron‐tetraphenylporphyr...
The Chemistry of Space: From Crystallographic Abstraction to Framework Design
Abstract The 2025 Nobel Prize in Chemistry celebrates the groundbreaking development of metal–organic frameworks (MOFs), which revolutionised porous materials through the application...
Direct Deoxyarylation of Non‐Activated Alcohols
Abstract The formation of carbon–carbon bonds constitutes the most critical fundamental reaction in organic synthesis. Although synthetic chemists have achieved...
Nucleophilic Oxygen‐Engineering Dual‐Gradient Cathode‐Electrolyte‐Interphase for High‐Voltage Lithium‐Rich Manganese Oxide Cathodes
Abstract The high‐voltage stability of lithium‐rich manganese‐based layered oxide (LRMO), particularly at voltages approaching 4.8 V, is governed by the structur...
High‐Capacity Metastable Li <i> <sub>x</sub> </i> CoO <sub>2</sub> Cathode Enabled by Coherent Intergrowth of T <sup>#</sup> 2 and O2 Phases
Abstract O2‐type Li x CoO 2 (O2‐LCO)...
Nickel‐Mediated Synthesis of Fused Heterocycle‐Linked Covalent Organic Frameworks for Self‐Sensitized Photocatalysis
Abstract Conjugated and chemically robust covalent organic frameworks (COFs) incorporating metal ions hold great promise in diverse applications due to their fin...
Marc Guerre
Engineering Supramolecular Assemblies via Metal–Metal Interactions for Biological Applications
Abstract Over the past decades, self‐assembly has become a pivotal strategy for the construction of tunable supramolecular nanoarchitectures. In particular, supr...
Unlocking the Critical Role of Noncovalent Interactions Between Alkali Metal Cations and Nitrate in Promoting the Reduction of Nitrate to Ammonia
Abstract The electrochemical nitrate reduction reaction (NO 3 − RR) is widely investigated for sustai...
Suppression of Excimer Formation via Conjugation‐Driven Interactions in Crosslinked Hole Transport Layer for Efficient Blue Quantum Dot Light‐Emitting Diodes
Abstract Blue quantum dot light‐emitting diodes (QLEDs), underperforming relative to red and green counterparts, shoulder the critical responsibility for full‐co...
Elucidating Highly Activated Transition Metal Redox Chemistry in Low‐Nickel O3‐Type Layered Oxide Cathodes for Sodium‐Ion Batteries
Abstract Low‐nickel O3‐type layered oxides have emerged as cost‐effective cathode candidates for sodium‐ion batteries (SIBs). However, their practical viability...
Ultrabright Gold Nanoclusters with Intra‐Cluster Hydrogen Bonding Enable Near‐Zero‐Thickness Electrochemiluminescence Imaging of Subcellular Structures
Abstract Endowing electrochemiluminescence (ECL) imaging technologies with the capability to resolve fine subcellular structures at high spatial resolution remai...
Plasmon‐Enhanced CO <sub>2</sub> Methanation over Au@Ru/TiO <sub>2</sub> via Nanoscale Control of Ru Shell Thickness
Abstract Plasmonic‐catalytic nanostructures enable coupling light harvesting with chemical transformations, yet their performance critically depends on nanoscale...
CrystalGAT: An AI‐Based Intelligent Flexible Crystal Materials Design Computing Platform
Abstract Endowing functional crystals with flexibility significantly broadens their potential applications in the field of flexible smart devices. Despite tremen...
Phase‐Transition Intervention Engineered Amorphous Vanadium Oxide for High‐Performance Aqueous Zinc‐Ion Batteries
Abstract Amorphous vanadium oxide (AVO) has emerged as a promising cathode material for aqueous zinc‐ion batteries (AZIBs), combining the high theoretical capaci...
Tuning Asymmetric Isomers in One‐Dimensional Covalent Organic Frameworks to Enhance Oxygen Reduction Activity
Abstract Embedding isomers into crystalline skeletons with well‐defined spatial structures represents a feasible way to improve the catalytic activity for the ox...
“Living Nanosheets” of Covalent Organic Frameworks Aligned into Laminar Membranes for Sharp and Durable Molecular Separations
Abstract Organic solvent nanofiltration (OSN) requires membranes to have exquisite pore structures and excellent solvent resistance to alter energy‐intensive sep...
Visualization of Electrical Trees: Oxygen Metabolism Insights and Organic Room Temperature Phosphorescent Materials
Abstract Electrical treeing, manifesting as Lichtenberg figures (LFs) is a major cause of dielectric failure in power, communication, and aerospace systems. Visualization of LF evolu...
Mirror‐Symmetric Nanoarray Networks of Atomic Ni‐Incorporated Tungsten Oxynitride for Efficient and Robust Alkaline Hydrogen Evolution
Abstract The development of alkali‐efficient hydrogen evolution reaction (HER) electrocatalysts is essential for future deployment of anion‐exchange membrane wat...
Strong, Yet Split Hydrogen Bonding with Ice Rules in Delafossite (H/D)RhO <sub>2</sub>
Abstract Despite remaining enigmatic, strong hydrogen bonding provides an advanced design handle for tailoring the properties of functional materials. Here, 3...
Integrated Conversion of Polyesters, CO <sub>2</sub> , and Glycerol via Ethylene Oxide‐Mediated Tandem Process
Abstract The co‐conversion of poly(ethylene terephthalate) (PET), CO 2 , and renewable carbon resources offers a sustaina...
All‐ <i>Nido</i> ‐Carborane‐Protected Copper Clusters
Abstract Peripheral ligands of metal nanoclusters play a crucial role in determining their structures and modulating their physicochemical properties. Therefore,...