Angewandte Chemie International Edition
Articles in this Issue
Correction to “Photoinduced Deoxygenative Borylations of Aliphatic Alcohols”
Small Fluorinated Aromatic Molecule‐Based Radiofrequency Identification Tags Enabled by Stepwise Tuning of Nuclear Shielding
Abstract In the Internet of Things (IoT) network, radiofrequency identification (RFID) is a key enabler for wireless communication, facilitating real‐time monito...
Surface Halide Manipulation for Stable Inorganic Perovskite Solar Cells and Modules
Abstract Iodine‐rich inorganic perovskites possessing desirable bandgaps as well as high thermal and chemical stability are facing serious issues of low polymorp...
Impeding Thermal Atomization Enables Synthesizing Fe <sub>2</sub> N Cluster Liganded Single Fe‐Atom Catalyst for Highly Efficient Oxygen Reduction Reaction
Abstract Anchoring a ligand, such as a functional group or a cluster, on the active metal center is an effective strategy for regulating the electronic structure...
Metal‐Free Electrochemistry‐Driven Decarboxylative Primary Alkyl‐Alkoxylation of Olefins
Abstract Here, a primary alkylative difunctionalization of olefins based on the decarboxylation of carboxylate ions to obtain alkyl radicals by electrochemical anodic oxidation is re...
Branching‐Induced Intermolecular Repulsion Effects Drive Stable and Sustainable Flow Batteries on Condensed Nitroxyl Radicals
Abstract Aqueous organic redox flow batteries (AORFBs) play a critical role in scalable energy storage applications where safety, cost, and lifetime matter most....
Topologically Entangled Network Polymer Electrolyte with Ionophilic–Protonation Dual Side Chains for High‐Voltage Lithium‐Metal Batteries
Abstract The development of high‐voltage solid‐state lithium‐metal batteries (HVSSLMBs) is severely limited by unstable ion transport, insufficient oxidative sta...
Supramolecular Structure Enabled Photo‐Responsive Charge Transport in Porphyrin‐Based Junctions
Abstract Supramolecular electronics offers a valuable opportunity to fabricate functional devices with tunable charge transport (CT) behaviors. Their diverse and non‐covalent structu...
Engineering Robust Hydrophilic–Hydrophobic Interface via π‐electron Delocalization for Ultralong‐Lived Zinc–Ion Batteries
Abstract Aqueous zinc ion batteries (AZIBs) are hindered by the severe interfacial issues of Zn anode such as side reactions and dendrite growth. The in‐situ con...
Dissected MACl Involved Reaction Pathway for Low Temperature Fabrication of High‐Efficiency Flexible Perovskite Solar Cells
Abstract FAPbI 3 ‐based perovskite solar cells (PVSCs) are highly promising due to their excellent power conversion effic...
Deciphering the N─N Coupling Mechanism Over Iron–Copper Alloy Catalysts During Ammonia Decomposition
Abstract The production of CO x ‐free hydrogen via the ammonia decomposition reaction (ADR) using Fe‐based non‐precious m...
Enhancing the Built‐In Electric Field of Thickness‐Insensitive Small Molecule Cathode Interlayers for High‐Efficiency and Stable Organic Solar Cells
Abstract The built‐in electric field (BEF) is proposed as a critical design parameter for optimizing small‐molecule cathode interlayer materials (SM‐CIMs) in org...
Uniform Half‐Substituted Chiral Arylcycloparaphenylene: Synthesis, Crystal Structure, and Chiroptical Properties
Abstract The strategic implementation of aryl‐functionalization in every phenyl group in organic architectures presents a transformative approach to constructing...
Lattice Compression‐Driven Electron Localization and Ir‐O Coupling Synergistically Enable Ultralow Overpotential Li‐CO <sub>2</sub> Batteries
Abstract Developing efficient cathode catalysts plays a crucial role in improving the CO 2 reduction reaction (CO...
Steric‐Dominated Intermediate Stabilization by Organic Cations Enables Highly Selective CO <sub>2</sub> Electroreduction
Abstract Precisely modulating the binding energies of intermediates through cationic engineering remains a pivotal challenge in controlling reaction pathways and...
Room‐Temperature Material Recycling/Upcycling of Polyamide Waste Enabled by Cosolvent‐Tunable Dissolution Kinetics
Abstract Polyamides (PAs, nylons) are a ubiquitous class of high‐performance plastics used extensively in a wide range of applications. Their high resistance to...
All Iron‐Group and Platinum‐Group Elements Metal High‐Entropy Alloy Nanoparticles
Abstract High‐entropy alloys (HEA) are promising catalyst materials for important energy transformations. So far, the focus has been on platinum‐group metals, wh...
Photo‐Controlled Dynamics of Cholesteric Polymer Coatings via Hydrazone Crosslinking
Abstract Developing responsive coatings and materials requires discovering a breadth of mechanisms by which external stimuli can be converted into useful signals. Here, we demonstrat...
Solid‐Phase Parallel Synthesis of Photocleavable Bifunctional Molecules Enables Efficient Phenotypic Protein Degrader Discovery
Abstract Phenotypic screening offers an effective path for discovering protein degraders, particularly targeting proteins that are poorly characterized or lack s...
Carboxylate‐Based Electrolyte with Bilateral Functions Enable Working Sodium‐Metal Batteries at −60°C
Abstract Sluggish interfacial reaction kinetics and unstable electrode/electrolyte interphases seriously hinder the practical applications of sodium‐metal batter...
Evidence for Methylaluminoxane (MAO) Molecular Structure and Reactivity from Ultrahigh Magnetic Field <sup>27</sup> Al MAS NMR Spectroscopy Combined with DFT Calculations
Abstract The structure and reactivity of methylaluminoxane (MAO), a reagent of major interest for olefin polymerization, both industrially and academically, has...
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes
Abstract Despite the intensive studies on the synthesis and application of aryl boronates, most focus on mono‐borylated arenes. The multi‐borylated arenes, on the other hand, have re...
Photoexcited Hole‐Enabled Synthesis of Surface High‐Valent Cobalt‐Oxo Species with Water as the Oxygen Atom Source for Water Purification
Abstract High‐valent cobalt‐oxo species (Co IV ═O) are key intermediates in catalytic chemistry but suffer a great challe...
Single‐Crystal‐to‐Single‐Crystal Transformation in a Thermally Stable All‐Inorganic Polyoxoniobate Framework Boosts Lithium Ion Battery Anode Performance
Abstract Niobium oxides are considered as promising anode materials for lithium‐ion batteries (LIBs) due to their excellent rate‐performance. However, the practi...
Dynamic Evolution of Structural Ordering and Aluminum Redistribution During ZSM‐5 Zeolite Crystallization
Abstract Improving the comprehension of intricate crystallization processes at the molecular level is crucial for the customized design of efficient zeolite materials. However, the a...