Angewandte Chemie International Edition
Articles in this Issue
Decoy DNA Protects Molecular Tension Probes from DNase Degradation
Abstract DNA‐based molecular probes are essential tools for visualizing and quantifying mechanotransduction at the single‐molecule level. However, their application in live‐cell envi...
Hybrid Cathode Interlayer Engineering Enables Over 20% Efficiency of Organic Solar Cells
Abstract The capability of cathode interlayer (CIL) in regulating the conductivity, interfacial dipole, and work function of the electrode plays a critical role in determining the ph...
Decoupling Activity‐Selectivity Trade‐off in Photothermal Catalytic CO <sub>2</sub> Hydrogenation: A Hydrogen Spillover‐Assisted Dual‐Site Synergy Mechanism
Abstract The persistent trade‐off between catalytic activity and selectivity remains a critical barrier to efficient CO 2...
Self‐Assembled π‐Conjugated Hole‐Selective Molecules for UV‐Resistant High‐Efficiency Perovskite Solar Cells
Abstract Ultraviolet (UV) light‐induced degradation, particularly occurring at the buried interface, has emerged as a significant stability challenge, severely l...
Linking Metallacycle Transfer with Ring‐Opening Metathesis to Generate Polyacetylenes of Unprecedented Structure
Abstract A hafnium‐based bicyclic precursor ( COT‐2B‐Hf ) has been prepared that enables tandem Hf/E metallacycle transfe...
Plasmonic Nanoparticle Monolayer‐Decorated Nanopipette Enabling in Situ Monitoring of Single‐Cell Redox Metabolism
Abstract The in‐depth study of how single cells respond to redox perturbations is pivotal for predicting cell fate decisions. Surface‐enhanced Raman spectroscopy (SERS)‐active nanopi...
Engineering Crystalline/Amorphous Interfaces for Enhanced CO <sub>2</sub> Electroreduction
Abstract In the request for carbon neutrality, CO 2 electroreduction to high‐value fuels and chemicals, particularly form...
Tynchtyk Amatov
Synthesis of Chirally Chimeric Protein Nanoparticle Vaccines via Mirror‐Image Spy Chemistry
Abstract Mirror‐image proteins and nucleic acids exhibit remarkable biostability and bioorthogonality, offering a promising strategy to enhance the longevity of...
Selective Phosphorylation of Phenols and Benzenediols by the Kinase PsiK and Variants Thereof
Abstract Phosphorylation plays important roles in biology by modulating the structure, reactivity, and biological function of a broad range of molecules. Biocata...
Visible‐Light‐Mediated Intramolecular Dearomatization of Naphthalene and Anthracene with Bicyclo[1.1.0]butanes Through Energy Transfer Catalysis
Abstract Cyclization of bicyclo[1.1.0]butanes (BCBs) is an effective way to construct saturated polycyclic 3D structures. Herein we report a visible‐light‐induced intramolecular dear...
Precise Molecular Engineering of Heptamethine Cyanine‐Based Near‐Infrared Type‐I Photosensitizers for Pro‐Death Autophagy and Hypoxia‐Tolerant Antitumor Treatment
Abstract Heptamethine cyanine ( Cy7 ) dyes have excellent near‐infrared (NIR) fluorescence imaging capability but competi...
Counterion‐Mediated Luminophore Dimerization
Abstract Emissive organic salts have long been integral to the discovery of fluorescence phenomena and functional luminescent dyes. Typically, one component of t...
Photoswitchable Catalytic Divergent Synthesis by a Viologen‐Functionalized Lanthanide‐Organic Tetrahedral Cage
Abstract Photoswitchable catalysis presents a significant challenge, particularly in the modulation of reaction pathways. In this study, we describe a redox‐acti...
Articular Cartilage Inspired Ultra‐Strong and Tough Bio‐Based Polyurethane Nanofiber Membranes
Abstract Bio‐based polyurethanes are promising sustainable elastomers whose polymeric network structure has a decisive impact on their properties. However, exist...
Divergent Asymmetric Synthesis of Bonnadiene and <i>ent</i> ‐Polytrichastrene B
Abstract We report herein the first asymmetric total synthesis of bonnadiene and ent ‐polytrichastrene B, two diterpenoid...
The Iron–Sulfur Cluster of Bacterioferritin‐Associated Ferredoxin (Bfd): a “Biological Fuse” that Prevents Oxidative Damage to Cells?
Abstract Iron is in an essential micronutrient in living systems. However, it is also potentially toxic and so the concentration of chelatable iron within cells is tightly regulated...
Bone‐Inspired Sustainable Hydrogel Electrolytes for Zn Metal Batteries
Abstract Hydrogels are promising electrolytes for use in aqueous Zn metal batteries (AZMBs). However, the problems associated with the Zn anodes cannot be elimin...
A Polyaromatic Metallotube With a Dual Multi‐Functionalization Ability
Abstract Post‐functionalization is an advanced, key synthetic method in supramolecular systems, whereas the previous method relies heavily on the substitution on...
Highly Crystalline and Oriented Thin Films of Fully Conjugated 3D‐Covalent Organic Frameworks
Abstract Fully conjugated 3D covalent organic frameworks (COFs) are a newly emerged class of materials that expands reticular chemistry to extended electron delo...
Intracellular Delivery of Native Proteins by BioReversible Arginine Modification (BioRAM) on Amino Groups
Abstract Protein‐based tools are emerging as innovative solutions to interfere with biological pathways in molecular biology and medicine. They offer advantages over traditional smal...
A Recyclable Cooperative Approach for Selective Lithium Recovery from Industrial‐Grade Spent Lithium‐Ion Battery Black Mass via Oxidative Delithiation and Complexation Mechanism
Abstract Extracting lithium selectively from an industrial‐grade lithium‐ion battery (LIB) black mass having multiple metal ions is challenging but crucial from...
Divergent Upcycling of Polystyrene into Phenol and Hydroquinone Derivatives by Photocatalysis and Electrocatalysis
Abstract The selective upcycling of polystyrene (PS) waste into value‐added aromatics has emerged as a compelling strategy toward sustainable plastic valorizatio...
Direct Asymmetric α‐C Addition of Glycinate to Nitroalkenes by Pyridoxal/Nd Dual Catalysis
Abstract Direct enantioselective α‐C Michael addition of NH 2 ‐unprotected glycinate to nitroalkenes is a significant org...
Copper‐Catalyzed Radical Enantioconvergent C─O Bond Formation for Asymmetric Cross‐Coupling of Allylamines and CO <sub>2</sub>
Abstract Upgrading abundant carbon dioxide (CO 2 ) into high‐value organic molecules has garnered broad research interest...