Angewandte Chemie International Edition
Articles in this Issue
Electrified Isoreticular Synthesis of Zeolitic Imidazolate Framework‐90 Membrane Through Self‐Templating for Tunable Gas Separations
Abstract Metal–organic frameworks (MOFs) are amenable to isoreticulation, which provides a handle to fine‐tune the pore apertures and thus their gas separation capabilities as molecu...
Toward Practical Ultralong‐Life Li‐Air Batteries in High‐Humidity Environments: A Synergistic Strategy for Dual‐Interfacial Engineering
Abstract Maintaining the operational stability of Li–air batteries (LABs) in high‐humidity environments is crucial for their transition from laboratory research...
Inversely Induced Circularly Polarized Luminescence of Achiral Luminophores in the Inner and Outer Surface Helical Nanotube
Abstract Co‐assembling nanostructures with achiral luminescent moieties represents a significant approach for developing circularly polarized luminescence (CPL)...
Descriptor‐Inspired Oligomer Additives Enabling Long‐Life Zinc Metal Batteries
Abstract Interfacial dendrite growth and parasitic reactions pose major challenges to the stability and efficiency of zinc metal batteries, prompting the explora...
Single‐Site Pd Coupling with Jahn–Teller Active Cu as Pair Sites for Simultaneous Activation of Alkyne and Hydrogen Toward Efficient Semihydrogenation
Abstract Single‐site pairs are promising in achieving high selectivity and activity in alkyne semihydrogenation, but its applicability is limited by the insuffic...
Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL
Abstract Cyclic gallaphosphene L(PCO)GaPGaL 1 (L = HC[C(Me)NAr] 2 ; Ar = 2,6‐...
Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos
Abstract Atropisomeric biaryls are increasingly important in molecules of pharmaceutical interest. Asymmetric versions of the Suzuki–Miyaura coupling arguably co...
Access to Axially Chiral Vinyl Sulfilimines via Copper‐Catalyzed Enantioselective Radical Relay Trifluoromethyl‐Sulfilimination of Terminal Alkynes
Abstract Sulfilimines have garnered increasing attention as valuable scaffolds in drug discovery and asymmetric synthesis. Nevertheless, catalytic enantioselecti...
Reversing V═O Orientation of Vanadyl Phthalocyanine as "Molecular Switch" on Carbon Nitride Boosts CO <sub>2</sub> Photoreduction
Abstract The precise engineering of catalytic microenvironments in single‐atom site photocatalysts is critical yet challenging for optimizing CO...
Acid‐Stable Ruthenium‐Based Solid Solution for Oxygen Evolution in Proton Exchange Membrane Electrolyzers
Abstract Proton exchange membrane (PEM) water electrolysis offers a promising route for green hydrogen production, yet balancing catalytic activity and durabilit...
Solubility Activation of Recessive Solvent Mitigates Interphase Dissolution for High‐Performance Sodium‐Ion Batteries
Abstract Solid electrolyte interphase (SEI) dissolution in sodium‐ion batteries (NIBs) triggers electrolyte decomposition and gas evolution, resulting in capacit...
Gaseous SO <sub>2</sub> Additive for High‐Energy‐Density Li‐Ion Battery
Abstract Electrolyte additive engineering is pivotal for suppressing interfacial degradation and enhancing the cycling stability of high‐energy‐density batteries...
Robust Interface Enabled by Bicontinuous‐Structured Electrolyte Elastomers for Solid‐State Battery Applications
Abstract Solid‐state electrolytes (SSEs) with high ionic conductivity, superior electrochemical stability, and mechanical durability are safe and reliable for so...
Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances
Abstract Nonlinear optical (NLO) crystals with second‐harmonic generation (SHG) are crucial in laser technology for extending spectral ranges. However, achieving...
Lattice Oxygen Mediated C(OH)−C(OH) Bond Cleavage to Promote Alcohols Electrooxidation
Abstract Selective cleavage of C(OH)−C(OH) bond is crucial for valorization of biomass, waste plastics and other organic compounds, while facing thermodynamic and kinetic barriers. U...
Synergistic Co‐Doping of Barium and Cobalt Enables Stable and Active RuO <sub>2</sub> for Acidic Water Oxidation
Abstract Developing acid‐stable and active non‐iridium oxygen evolution reaction (OER) electrocatalysts is crucial to facilitating the cost‐effective and large‐s...
Interfacial π–π Stacking Interaction Promotes H <sub>2</sub> ‐Driven Enzymatic Asymmetric Reduction
Abstract In situ H 2 ‐driven NAD(P)H regeneration offers a sustainable approach for chemoenzymatic reduction in vitro; ho...
Mitigating Concentration Polarization via Ion‐Sieving Interlayer Towards Long‐Life 510 Wh Kg <sup>−1</sup> Lithium Metal Pouch Cells
Abstract Uncontrolled transport of lithium‐ion and anion induce concentration polarization and Li dendrite growth, severely hindering the development of high‐ene...
Programmable Nanoscale Motion via Molecular Patterning on DNA Origami
Abstract Asymmetry in enzymatically driven nanomotor design, both structural and functional, is widely considered essential for propulsion. However, the interplay between particle ge...
Dynamic H‐Bonding Mediates Stimuli‐Responsive Chiral Induction in Porous Aromatic Cages with Multicolor Chiral Afterglow
Abstract The origin of biological chirality remains a fundamental scientific mystery. Developing artificial systems with on‐off responsive chiral induction and t...
Chiral Phosphoric Acid–Functionalized Three‐Dimensional Covalent Organic Frameworks with Exceptional Chemical Stability for Asymmetric Catalysis
Abstract The design of three‐dimensional covalent organic frameworks (3D COFs) incorporating chiral phosphoric acids represents a promising strategy to enhance e...
Pulse‐Electrodeposited Single‐Atom Alloys with Steered Surface Hydrogenation Dynamics for Air‐to‐Fertilizer Synthesis
Abstract Harnessing renewable electricity to transform abundant environmental resources into fertilizers is central to sustainable development. Electrochemical n...
Dual‐Type Polarization‐Triggered Spontaneous Exciton Dissociation in Conjugated Polymers for Enhanced Photocatalytic H <sub>2</sub> O <sub>2</sub> Evolution in Pure Water
Abstract Severe exciton effect significantly hinders free‐charge‐involved water redox reactions, limiting the improvement of photocatalytic performance. Herein,...
Inside Back Cover: Support‐Induced Interfacial Effects Steer Methanol Selectivity in CO2 Electroreduction by Immobilized Cobalt Phthalocyanine (Angew. Chem. Int. Ed. 8/2026)
Manganese‐Coordinated Polyvalent Aptameric System (COMPASS) Enables DC‐Targeted mRNA/Mn <sup>2</sup> <sup>+</sup> Co‐Delivery for Cancer Immunotherapy
Abstract mRNA vaccines hold remarkable promise for cancer immunotherapy, yet current nanoparticle systems face challenges in efficacy, dendritic cell (DC) target...