Angewandte Chemie International Edition

Correction to “Ligand Effects in Regio‐ and Enantioselective Cobalt‐Catalyzed Intramolecular [4 + 2]‐ and [2 + 2]‐Cycloaddition Reactions of Unactivated 1,3‐Diene‐8‐ynes and 1,3‐Diene‐8‐enes”

Flavio Siro Brigiano

Modular Assembly of Dynamic Polymer Networks From Heteroaffinity Cross‐Links to Multivalent Proteins

ABSTRACT Dynamic polymer networks (DPN) leverage transient cross‐linking to yield macroscopic materials that exhibit self‐healing and environmentally responsive behaviors. Despite th...

Outside Front Cover: Investigation Into the Dynamics of the Cupula in the Vestibular Organ of Adult Zebrafish Using Metabolic Glycoengineering (Angew. Chem. Int. Ed. 17/2026)

Inside Front Cover: On the Discorhabdins Leading to the Aleutianamine Ring System: A One‐Step in Situ Transformation Characterized Through Computational and Experimental Studies and Its Implications on Biosynthesis, Synthesis, and Pharmacology (Angew. Chem. Int. Ed. 17/2026)

MOF Ceramic‐Like Membrane With High Proton Conduction and Tunable Transparency

ABSTRACT The industrial deployment of metal‐organic frameworks (MOFs) is hindered by their particulate morphology, while the fabrication of macroscopic architectures—particularly con...

Near‐Infrared‐Light‐Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology

ABSTRACT Near‐infrared (NIR) photochemistry and photocatalysis have emerged as powerful extensions of analogous visible‐light methods, offering unique advantages, such as deeper pene...

Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross‐Coupling

ABSTRACT Aryl sulfonium salts are indispensable partners in cross‐coupling reactions, allowing access to aryl metal or aryl radical intermediates, and offering a...

Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion

ABSTRACT A “bioinspired” silylarylation of unactivated terminal alkenes involving formal thiosilylation of the C═C double bond followed by an intramolecular elec...

Iron‐Catalyzed Anti‐Markovnikov Hydroxyazidation of Unactivated Alkenes

ABSTRACT Anti‐Markovnikov oxidation of alkenes to access primary alcohols remains a significant synthetic challenge due to inherent regioselectivity constraints....

Interatomic Spacing‐Dependent Electrocatalytic CO ₂ Reduction: Inert Te Heteroatom Modulation in Hexagonal Pd Nanoplates

ABSTRACT Metallic interatomic spacing emerges as a key activity descriptor in electrocatalysis, yet achieving angstrom‐level precision in its dynamic modulation...

Unlocking Latent Titanium Active Centers Through the Synergistic Effect of Oxygen Vacancies and Boron Doping for Accelerated Sulfur Redox Reactions in Silicon‐Sulfur Batteries

ABSTRACT The introduction of multiple defects into a single electrocatalyst enables precise modulation of active centers electronic states, thereby accelerating...

Second‐Generation Crystalline Sponges Enabling Consistent Structure Analysis Under Standardized Conditions for Diverse Molecules

ABSTRACT Crystallization is typically highly sensitive to even minor structural differences in target molecules. As a result, obtaining crystals of complex compounds often requires e...

A Dearomative [3,3]‐Sigmatropic Rearrangement Strategy for the <i>meta</i> ‐Thiolation of Azaarenes

ABSTRACT Direct C–H functionalization of azaarenes stands as a remarkably powerful tool for diversifying these heterocycles. However, precise control over chemo‐...

Bridged Pyrroloindole‐CAYC‐Gold Complexes: Harnessing Weak Secondary Intramolecular Au···H−C( <i> sp ³ </i> ) Interactions in Gold(I) Catalysis

ABSTRACT Gold(I) catalysis has been established as a tremendously powerful tool in organic synthesis and catalysis. Herein, we introduce a new class of electroni...

Rh‐Catalyzed Chemodivergent Parallel Kinetic Resolution and Desymmetrization of Enynes and Dienynes with Acrylamides

ABSTRACT Catalytic enantioselective synthesis of structurally diverse 3D molecules remains a central challenge in organic chemistry. Intermolecular chemodivergent parallel kinetic re...

Multi‐Site Synergistic Regulation Towards Highly Efficient and Stable Perovskite Solar Cells

ABSTRACT Perovskite solar cells (PSCs) have attracted considerable scientific interest due to their remarkable power conversion efficiency (PCE) and economically...

Fluorine‐18‐Labeled Nucleotide Analogs Targeting Ecto‐5'‐Nucleotidase (CD73) for Positron Emission Tomography Imaging of Solid Tumors

ABSTRACT Ecto‐5’‐nucleotidase (CD73) is a potential new drug target for cancer immunotherapy. Its overexpression is associated with various aggressive cancers, i...

NiH‐Catalyzed Enantioconvergent <i>α</i> ‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation

ABSTRACT β ‐Methylene carbonyl motifs constitute privileged structural frameworks that play vital roles as a pharmacophore and serve as key i...

Glycinamide‐Driven Coumarin Construction (GDCC): A Mild Strategy for Fluorescent Labeling and Macrocyclization of Peptides

ABSTRACT Peptidic macrocycles have attracted increasing attention due to their well‐defined structures and enhanced biological activities. However, efficient cyc...

Efficient Circularly Polarized Near‐Infrared Luminescence from Zero‐Dimensional Hybrid Copper Bromides

ABSTRACT Circularly polarized luminescence (CPL) provides an additional degree of freedom for light manipulation beyond intensity and wavelength and is essential...

Wash‐Free Multi‐Target Super‐Resolution Microscopy With Photocaged DNA Labels

ABSTRACT Super‐resolution microscopy with DNA‐fluorophore labels is primed for multi‐target imaging of cell biological samples. However, direct interaction with the sample is require...

A Smart Non‐Sacrificial Interphase for Improved Lithium Reversibility in Anode‐Free Solid‐State Lithium Metal Batteries

ABSTRACT Anode‐free solid‐state lithium metal batteries offer high energy density and enhanced safety, but their development is hindered by unstable solid electr...

Extended Fused Carbazole‐BODIPY, High Brightness NIR Organic Dyes

ABSTRACT Fluorescence‐based bioimaging enables noninvasive visualization of molecular and cellular processes with high sensitivity and without ionizing radiation...

Deciphering the Role of Bi Single Atoms in Bi‐In ₂ S ₃ for Robust Solar H ₂ O ₂ Photosynthesis: From Adsorption Geometry to Band Structure

ABSTRACT Achieving efficient solar‐to‐chemical conversion for H 2 O 2 synthesis i...