Angewandte Chemie International Edition
Articles in this Issue
Thermodynamic Control of Oxygen Vacancies for Li‐Rich Cathode Materials
Abstract Oxygen vacancies (OVs) play a critical role in tuning the properties of oxides, yet their rational control remains challenging. We present a meticulous...
Suppressing Non‐Radiative Decay via Cyanation: A Promising Design Strategy for Bright Organic NIR‐II Fluorophores
Abstract Achieving high fluorescence efficiency in organic fluorophores within the second near‐infrared window (NIR‐II, 1000∼1700 nm) remains challenging, as ext...
Circularly Polarized MR‐TADF Emitters with an Asymmetric Spiro‐Carbon‐Locking Architecture for Concentration‐Quenching‐Resistant Narrowband Circularly Polarized Electroluminescence
Abstract Highly efficient circularly polarized luminescence (CPL) emitters with narrowband emission are promising for ultra‐high‐definition (UHD) and three‐dimen...
Unlocking Durable and Efficient Nitrate‐to‐Ammonia Electrocatalysis via Interface‐Stabilized Trivalent Cobalt
Abstract Although cobalt‐based materials are promising catalysts for electrochemical nitrate‐to‐ammonia reduction, achieving stable operation at high current den...
Strain‐Release Induced 1,2‐Metallate Rearrangement of Geminal Diborons: Multicomponent 1,5‐Difunctionalization via Ring‐Opening Coupling
Abstract 1,2‐metallate rearrangement of geminal diboryl alkanes typically requires an α‐leaving group and results in monofunctionalization at the proximal carbon...
Synergistic Interplay of Ni Single Atoms and Neighboring Mn <sub>2</sub> Dual Atoms Enabling Selective Photocatalytic Reduction of CO <sub>2</sub> to Propane
Abstract The photocatalytic conversion of CO 2 and H 2 O into long carbon chain p...
Boosting Cancer Chemoimmunotherapy with Mitochondria‐Targeting Iridium(III)‐Based Immunogenic Oncosis Inducers
Abstract Most clinically used chemotherapeutic agents act by inducing apoptosis. However, their clinical effectiveness is often limited by poor therapeutic efficacy and the rapid dev...
Aqueous and Surfactant‐Free Synthesis of Nanoscale Covalent Organic Frameworks
Abstract The synthesis of nanosized covalent organic frameworks (nanoCOFs) with good dispersibility is vital for optical and optoelectronic applications. However, conventional method...
Giant Cycloparaphenylene‐Scaffolded Porphyrins as Photocatalysts
Abstract The efficient synthesis of cycloparaphenylenes (CPPs) with the designated functional groups still remains challenging. Meanwhile, the applications of fu...
The Expanding Horizons of Chemodynamic Therapy: From Fenton Chemistry to Radical‐Driven Biological Applications
Abstract Since the integration of Fenton chemistry into biomedicine, chemodynamic therapy (CDT) has rapidly emerged as a vibrant interdisciplinary research frontier. In recent years,...
Correction to “Metal‐Free Catalysis Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds”
Direct Air Capture and Photoconversion of CO <sub>2</sub> to Ethylene by Defect‐Tailored Cu <sub>3</sub> ‐Based Metal–Organic Frameworks
Abstract The development of efficient direct air capture (DAC) systems coupled with photocatalytic CO 2 conversion is sti...
Photochemical Deracemization of Chromanes and its Application to the Synthesis of Enantiopure Bioactive Compounds
Abstract Chromanes are frequently encountered as chiral structure elements in active pharmaceutical ingredients (APIs). We have now discovered an access to enant...
A 4+3 <i>β</i> ‐Ketoenamine‐Linked Covalent Organic Framework Membrane for High‐Performance Film‐Based Fluorescent NO <sub>2</sub> Sensor
Abstract Developing compact and structurally simple sensors for reliable and rapid monitoring of nitrogen dioxide (NO 2 )...
Outside Front Cover: Mechanistic Insights of Bipolar Redox Cathodes for Organic Rechargeable Batteries: LUMO Anti‒Bonding Contributions (Angew. Chem. Int. Ed. 5/2026)
Inside Back Cover: Giant Cycloparaphenylene‐Scaffolded Porphyrins as Photocatalysts (Angew. Chem. Int. Ed. 5/2026)
Tin—Tin π Bonding as a Conduit for Alkali‐Metal Reduction
Abstract Reactions of the doubly reduced distannynes, [Ar′SnSnAr′M 2 ], (Ar′ = C 6...
Laser‐Induced Size‐Focusing Synthesis of High‐Quality Colloidal Quantum Dots
Abstract Laser‐assisted chemical synthesis has emerged as a promising toolkit for producing unconventional nanomaterials otherwise not readily accessible. However, it remains challen...
Synthesis of Perdeuterated Pentane and THF Under Mild Conditions by Silica‐Supported Ta/M (M = Co, Ir) Heterobimetallic Catalysts
Abstract The catalytic hydrogen‐isotope exchange (HIE) of unactivated C(sp 3 )─H bonds remains a formidable challenge, re...
Harnessing Photoenzymatic Systems for Intermolecular C–H Fluorination
Abstract Organofluorine compounds are vital in pharmaceuticals, and enzymes, nature's most efficient catalysts, offer tremendous potential for precise fluorination. However, no enzym...
Mechanistic Insights of Bipolar Redox Cathodes for Organic Rechargeable Batteries: LUMO Anti‒Bonding Contributions
Abstract The search for sustainable organic cathode materials has been constrained by intrinsically low redox potentials and limited understanding of...
Targeting the Spliceosomal Protein USP39 Through Allosteric Ligands and PROTAC‐Induced Degradation
Abstract The precise regulation of gene expression is fundamental to cellular homeostasis and diversity. Dysregulation of splicing has been implicated in a range of diseases, includi...
Atomic‐Layered Platinum‐Based Intermetallic with Phosphorus Pillar Nanoengineering Enables pH‐Universal Hydrogen Oxidation Catalysis
Abstract Layered materials boost hydrogen energy catalytic efficiency by expanding electrochemically surface area and elevating the intrinsic site activity. Howe...
Leveraging 3d‐4f Coordination: Molecular Quantum Spring‐Magnet Behavior in Axial Ni <sub>2</sub> Ln Complexes
Abstract We report heterotrimetallic 3d–4f complexes, mimicking classical exchange spring magnets at the molecular scale. The complexes feature a linear Ni···Ln·...
Twisted Tin‐Chloride Perovskite Single‐Crystal Heterostructures
Abstract Self‐assembly affords simpler synthetic routes to heterostructures compared with manual layer‐by‐layer stacking, yet controlling interlayer twist angles...