Angewandte Chemie International Edition
Articles in this Issue
Regio‐ and Enantioconvergent Hydroallylation of Acrylates Enabled by γ‐Silyl‐Substituted Allyl Acetates
Abstract Transition‐metal‐catalyzed asymmetric allylic substitution provides an efficient route to chiral organic molecules featuring an allyl moiety, key intermediates in the synthe...
High‐Density Post‐Perovskite for Ultra‐Sensitive Hard X‐Ray Detection
Abstract The density properties of semiconductors play a crucial role in applications, such as radiation detection, electronic devices, and aerospace technologie...
Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene
Abstract While existing literature has primarily focused on carbene‐stabilized amino‐ and arylborylenes of the form [(carbene)BR] (R = substituent), herein we re...
Biphenylene Coordination and Ring‐Opening by Alkali‐Metal Nickelates
Abstract The pre‐coordination of substrates to heterobimetallic complexes plays a key role in facilitating challenging bond activations and catalytic reactions....
Merging Hydrogen‐Atom‐Transfer and the Truce‐Smiles Rearrangement for Synthesis of β‐Arylethylamines from Unactivated Allylsulfonamides
Abstract Arylethylamines are crucial elements in pharmaceutical molecules, making methods for their synthesis highly significant. The Truce–Smiles rearrangement...
Synthesis of Glycolipid Library Reminiscent of Mycobacterial Cell Wall Motif A and Its Significance by Microscopy
Abstract The cell wall of Mycobacterium tuberculosis (MTb) is distinguished by its unique glycolipid composition, notably...
NIR‐Sensitized Activated Formation of Lophyl Radicals by Heptamethine Cyanines Enables Dry Film Photoresists
Abstract The near‐infrared ( NIR ) sensitized generation of lophyl radicals ( L·...
Palladium‐Catalyzed Meta C─H Alkoxylation and Amidation via Polarity Reversal of Nucleophilic Reagents
Abstract Norbornene‐mediated remote metaselective C─H functionalization of arenes have been limited to relatively weakly electronegative and “soft” species, such as aryl, alkyl, and...