Angewandte Chemie International Edition
Articles in this Issue
Monomer‐Ratio Controlled Pyridinic‐N Enrichment Modulating p‐Band Centers in Carbon Nanospheres for Efficient Zinc‐Air Batteries
Abstract Rational design of high‐performance, low‐cost oxygen reduction reaction (ORR) catalysts is critical for advancing zinc‐air batteries (ZABs). This study...
Photothermal Conversion Promotes Challenging S <sub>N</sub> Ar for Facile C─N Bond Formation
Abstract Nucleophilic aromatic substitution (S N Ar) is a widely used method for forming aromatic C─N bonds, which are of...
Transforming RNA Degradation into Accurate RNA Detection: RNase I–Assisted Rolling Circle Amplification for Clinical Samples
Abstract Ribonucleases are powerful degradative enzymes that rapidly cleave RNA and have long been regarded as obstacles to RNA diagnostics. Detecting large, str...
Host‐Guest Doping Enables Room Temperature Phosphorescence from Triarylboranes
Abstract Revisiting our previous report of RTP in triarylboranes, we found that pure crystalline triarylboranes do not exhibit RTP as initially reported, although all but one purifie...
Universal Catalyst Design Framework for Electrochemical Hydrogen Peroxide Synthesis Facilitated by Local Atomic Environment Descriptors
Abstract A universal design framework for high‐performance catalysts remains challenging due to diverse structures and active sites. We developed a framework int...
Construction of a Two‐Dimensional Molecular Slab with a π‐Extended Hexaarylbenzene Molecule
Abstract We demonstrate a unique approach to a 2D molecular slab in the solid state by designing a π‐extended hexaarylbenzene molecule, hexa(naphthothiophene dii...
Structural Revision of the C <sub>16</sub> Sesquiterpene Hegelenether and the Mechanism of C6‐Methylation in Terpene Biosynthesis
Abstract Non‐canonical methylation events generate terpene structures that evade classical biosynthetic predictions, as exemplified by the proposed C...
Reversible Dimensional Programming of Covalent Organic Frameworks
Abstract While the dimensionality of covalent organic frameworks (COFs) is a fundamental determinant of their physicochemical properties, their precise control r...
Water‐Resistant Defective iMOFs via Halogen Coordination for CO <sub>2</sub> Capture and Size‐Selective Cycloaddition
Abstract A bottom‐up ligand engineering strategy enables the construction of ionic metal‐organic frameworks (iMOFs) with hierarchical porosity and abundant unsat...
Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal
Abstract Short‐wave ultraviolet (200–280 nm) crystals with large birefringence are important but scarce for polarization state modulation. The optical anisotropy...
Ultralow H <sub>2</sub> O <sub>2</sub> ‐Triggered Electron Transfer over Single‐Atom Iron Catalysts for Long‐Term Recyclable Fenton‐Like Reactions
Abstract Excessive consumption of hydrogen peroxide (H 2 O 2 ) in Fenton and Fent...
Dual‐Synergistic S‐Scheme Heterojunction for Targeting Dibenzylamine via Cascade Photoredox Catalysis of Benzylamine
Abstract Photocatalysis integrates oxidation and reduction processes, offering significant potential for driving synthetic transformations under mild conditions....
Molecular Cages as Probes in Indicator Displacement Assays: The Case of Scopolamine Detection
Abstract A study of the Pd‐based molecular cage C1 host–guest properties against fluorescein and the drug scopolamine is...
Membrane‐Penetrating Molecular Device Based on a Triplex Containing Acyclic L‐Threoninol Nucleic Acid Functionalized with Cholesterol
Abstract Membrane‐penetrating molecular devices are valuable biological tools. Herein, we describe membrane‐targeting molecular devices based on the triplexes of...
Synthetic Applicability Domain (SynAD): Navigating Chemical Space for Reliable AI‐Driven Reaction Prediction
Abstract Organic synthetic chemistry has undergone a paradigm shift driven by breakthroughs in artificial intelligence (AI). Data‐driven methods help accelerate...
Surface Modulated Platinum Electrocatalyst via Single Atom Nickel Promoter for Durable Non‐aqueous Hydrogen Oxidation
Abstract Electrocatalytic hydrogen oxidation reaction (HOR) plays crucial role in various renewable energy conversion processes. Particularly, it offers new oppo...
Positive Feedback‐Driven NiRu Frustrated Lewis Pairs Catalyst Enables a Self‐Reinforcing Catalytic Cycle for Cascade‐Coupled Hydrogen Production
Abstract The alkaline hydrogen evolution reaction (HER) associated with anion exchange membrane water electrolyzers (AEMWEs) is kinetically hindered by sluggish...
Molecular‐Level Energy Dissipation and Micropore Engineering Synergistically Enhance Anion Exchange Membrane Performance
Abstract Overcoming the intrinsic trade‐off between ionic conductivity and mechanical robustness remains a long‐standing challenge for anion exchange membranes (...
Experimental Observation of a Calcium Silicon Double Carbonate
Abstract Reactions between carbon dioxide (CO 2 ) and silica (SiO 2 ), as well as...
Manipulating the Active Sites in Single‐Nanocluster Catalysis by Heterometallic Coordination Hybridization at Atomic Precision
Abstract Constructing accessible active sites on the surface of catalysts at the atomic precision remains challenging in heterogeneous single‐nanocluster catalys...
Breaking Metal‐Organic Cage Symmetry Enhances Diels–Alder Catalytic Specificity and Proficiency
Abstract Biomimetic catalysts that rely on hollow, synthetic hosts lack the sophistication of an enzyme active site. One reason for this is that synthetic hosts, particularly those p...
Nucleophilic Substitution Enables Robust Fluorinated Interphase for Low <i>N</i> / <i>P</i> Ratio Zinc Battery
Abstract Aqueous zinc (Zn) batteries have garnered considerable interest as a promising, safe, and sustainable energy storage technology. Nevertheless, their wid...
Mild‐Condition Upcycling of Polyolefins Enabled by Micropore Confinement in Zeolites
Abstract The catalytic upcycling of polyolefin waste into valuable chemicals offers a sustainable strategy to mitigate plastic pollution and advance resource sus...
Harnessing Reversible 0D–1D Transformation in Chiral Mn(II) Halides for Smart Circularly Polarized Luminescence Switching and Multi‐Level Encryption
Abstract Circularly polarized luminescence (CPL) active materials with dynamically tunable properties are highly desirable for next‐generation photonics and encryption technologies,...
Unexpected Dual Function of Plant YUCCA Enzymes Links Chlorophyll Catabolism to Auxin Homeostasis
Abstract Chlorophyll (Chl) metabolism is pivotal to both photosynthesis and plant senescence and represents one of the most fundamental biological processes on E...