Angewandte Chemie International Edition
Articles in this Issue
Spatially Homogeneous Mg <sub>3</sub> (Sb, Bi) <sub>2</sub> With Suppressed Parasitic Transport Enables Ultrahigh Thermoelectric Performance
ABSTRACT Chemical inhomogeneity widely exists in thermoelectric materials, yet its effects are mainly ascribed to local interface scattering and compositional fl...
Stable Full‐Color and Single‐Phase White Emission in a Family of Isomeric Organic Cu(I) Iodides
ABSTRACT Organic Cu(I) halides feature highly designable structures, systematic tunability, and efficient emission; however, simultaneously achieving full‐color...
Inside Back Cover: A Cholesterol Analogue for Cell‐Surface Enzyme Display
Vicinal‐Diboron Reinforced [9]Helicene Enables Narrowband Blue Circularly Polarized Emitter With Large Dissymmetry Factor and High Device Efficiency
ABSTRACT Circularly polarized multiple‐resonance thermally activated delayed fluorescence (CP‐MR‐TADF) emitters that simultaneously combine narrowband emission,...
Triple Framework Isomerism and Efficient Ethane/Ethylene Separation of Single‐Crystal Covalent Organic Frameworks With 2D hcb Sheets
ABSTRACT Constructing triple framework isomerism with atom‐resolution structures is of great significance but remains highly challenging for covalent organic fra...
Inside Back Cover: Recyclable Pt‐Catalyzed Biphase Hydrosilylation on Water: From Functionalized Monomers to Polymer Materials
Solvent Hydrogen Bonding Determines Adsorption Geometry of Trimesic Acid on Cu
ABSTRACT The adsorption geometry of functional molecules largely determines the interfacial behaviour in various applications like catalysis, photovoltaics and molecular electronics....
Network‐Anchored Nanocages Create Weakly Solvating Electrolytes for Subzero Aqueous Zinc Batteries
ABSTRACT Low‐temperature operation of aqueous zinc batteries is fundamentally limited by electrolyte freezing and sluggish interfacial kinetics, originating from...
White‐Light‐Mediated Imidazole Catalysis Toward Terpene‐Based Thermosets
ABSTRACT Light‐mediated curing of terpene‐derived polymers generally depends on UV irradiation and photoinitiators. We report herein that environmentally friendl...
Outside Back Cover: Rhodium(III)‐Catalyzed Asymmetric Synthesis of Silanes and Cyclopropanes From Diazo Compounds Using Chiral <i>α</i> ‐Pinene‐Derived Indenyl Ligands
Structure‐Guided Redesign of Terminal Deoxynucleotidyl Transferase Enables Scalable Enzymatic DNA Synthesis for Data Storage
ABSTRACT DNA, with its exceptional information capacity and chemical stability, represents a promising material for next‐generation data storage to meet the expo...
Inside Back Cover: High‐Entropy Catalyst Activated Molecular Oxygen for Oxidative Coupling Under Ambient Conditions
Narrowband Deep‐Red and Near‐Infrared Tetradentate Platinum(II) Complexes for High‐Performance OLEDs With Emission Peaks up to 715 nm and EQEs Over 20%
ABSTRACT Narrowband heavy‐metal phosphorescent complexes have been achieved in the visible region recently, yet such narrowband deep‐red/near‐infrared (DR/NIR) e...
Outside Back Cover: A Multi‐Stimuli Transformational Network of Benzil‐Based Pd(II) Assemblies
Outside Back Cover: Bifluorinated Motif‐Tailored Hybrid Membranes for Ultra‐Permeable CO <sub>2</sub> Separation From Air Under High Humidity
Photoinduced Copper‐Catalyzed Stereoselective C(sp <sup>3</sup> )‐H Amination Enabled by Preorganized Multiple Noncovalent Interactions
ABSTRACT Chiral α ‐amino cyclic amines are essential bioactive molecular skeletons that play a crucial role in regulating...
Harnessing Supramolecular Circularly Polarized Scattering for Enhanced Chiroptical Performance
ABSTRACT Recent advancements in circularly polarized luminescence (CPL) materials have shifted the emphasis from optimizing intrinsic CPL properties to leveragin...
Inside Front Cover: Metal–Organic Framework‐Gated Biocatalysis Enables Triggered Depolymerization of Melt‐Processed Polyesters
Polymer Brushes Govern Defect‐Selective Oxidative Etching of Penta‐Twinned Gold Nanorods
ABSTRACT Oxidative etching of plasmonic nanoparticles provides an effective approach to the variation of their morphology and optical properties, yet polymer ligands are generally tr...
Oxygen‐Radical Capture Enabled Nickel‐Catalyzed Carbon(sp <sup>2</sup> )‐Heteroatom Coupling of Two Nucleophiles
ABSTRACT Hypervalent transition‐metal complexes serve as pivotal intermediates enabling reductive elimination for carbon–heteroatom bond formation. Significant e...
n‐Type Oxazine‐Fused Higher‐Acene Analogues With High Stability and High Charge Mobility
ABSTRACT Acenes are a fascinating class of molecules. And higher‐acenes (>7 rings) with big beautiful structures are more likely to be continuously pursued. H...
The Reproducibility Crisis: Shining a Light Where Photo‐Induced Process Descriptions Fall Short
ABSTRACT Ensuring reproducibility should be a central priority for authors, editors, and reviewers throughout manuscript preparation and evaluation. Reports of photo‐mediated process...
Kinetic Trapping of Pressure‐Induced Symmetry Breaking in Hybrid Metal Halides via Fluorine‐Mediated Molecular Locking
ABSTRACT Permanently capturing pressure‐induced metastable phases at ambient conditions is a fundamental challenge that, if solved, would unlock a new realm of m...
Light‐Induced Alternating Catalysis on Single‐Atom Ruthenium Embedded in Covalent Organic Frameworks for High‐Performance Photo‐Assisted Li–O <sub>2</sub> Batteries
ABSTRACT The development of high‐efficiency cathode catalysts is crucial for advancing photo‐assisted non‐aqueous lithium–oxygen (Li–O 2...
Engineering Surface Hydroxyls of Zeolites to Suppress Sintering of Confined PtSn Clusters for Stable Propane Dehydrogenation
ABSTRACT Propane dehydrogenation (PDH) is an attractive on‐purpose route for propylene production, yet catalyst deactivation under harsh hydrogen‐free conditions...