Angewandte Chemie International Edition
Articles in this Issue
X‐Ray and Mechano‐Induced Valence Transition and Luminescence of Ln <sup>3+</sup> /Ln <sup>2+</sup> in CsCaCl <sub>3</sub>
ABSTRACT Lanthanide (Ln)‐doped perovskites show immense potential in luminescence. Although Ln 2+ ions offer superior lum...
Micro‐Stepwise (100) Crystal Face Coupling Molecular‐Layer Engineering Promises High‐Performance Zn‐Iodine Batteries in Wide pH and Seawater Electrolytes
ABSTRACT Aqueous zinc–iodine batteries (ZIBs) are promising for large‐scale energy storage but suffer from interfacial challenges in wide pH and seawater electro...
Aethrene: A Stable Polycyclic Aromatic Hydrocarbon With a Triplet Ground State
ABSTRACT Owing to their unique electronic structures and magnetic properties, high‐spin radicals have garnered significant interest in the fields of organic elec...
Carbohydrate Physicochemical Properties: The Innate Hydrogen Bond Donating Capacities of α‐Glucoside and α‐Galactoside Alcohol Groups
ABSTRACT Despite the significance of hydrogen bonding in protein‐carbohydrate interactions, carbohydrate conformation, and crystallinity (solubility), relative h...
Quadruple Hydrogen‐Bonds Engineering for Intrinsically Stretchable and Healable Semiconducting Polymers
ABSTRACT Developing intrinsically stretchable and healable semiconducting polymers with high charge‐carrier mobility is critical for next‐generation flexible electronics; however, in...
Dual‐Affinity Interphase Engineering Enables Stable Aqueous Zn–S Batteries
ABSTRACT Aqueous Zn–S batteries have garnered significant attention for grid‐scale storage but suffer from rapid capacity fade and sluggish reaction kinetics. Al...
Structural Control of Dual Emission in Coumarin Fluorophores for Visualizing Protein Droplet Maturation
ABSTRACT Proteins droplets formed by liquid–liquid phase separation (LLPS) gradually lose fluidity and mature into aggregated and fibrillar states, initiating fibrillation of amyloid...
Ultrahigh Density Ir Single‐Atom Catalysts With Synergistic Ir‐Ir Pairs for Efficient Acidic Oxygen Evolution
ABSTRACT Constructing neighboring active sites in single‐atom catalysts (SACs) provides a new strategy for enhancing acidic oxygen evolution reaction (OER) perfo...
Heat Transfer Fluids as Co‐Diluents in Localized High‐Concentration Electrolytes for High‐Rate Lithium Metal Batteries With Enhanced Safety
ABSTRACT Localized high‐concentration electrolytes (LHCEs) have been identified as promising electrolyte formulations for lithium metal batteries, due to their e...
Molecular‐Rotor‐Enhanced Pore‐Space Partition in Metal–Organic Frameworks for Boosting One‐Step Ethylene Purification
ABSTRACT One‐step ethylene purification from the ternary acetylene/ethane/ethylene (C 2 H 2...
Synthesis of Uniform 6‐Armchair Graphene Nanoribbons and Their Isotope and Nitrogen‐Doped Derivatives
ABSTRACT On‐surface synthesis enables precision synthesis of graphene nanoribbons (GNRs), allowing for tailored edge structures and widths through engineered pol...
Electron‐Induced C─F Bond Activation in Sn <sub>6</sub> ‐oxo Cluster Resist for Enhanced Sensitivity and Sub‐10‐nm Patterning
ABSTRACT Metal‐oxo cluster (MOC) resists are promising candidates for extreme ultraviolet lithography (EUVL), but optimizing the resolution, line‐edge roughness (LER), and sensitivit...
Phosphoryl‐Engineered MOFs Promote Interfacial Reconstruction for Efficient Seawater Ethanol Electrooxidation
ABSTRACT The hydrogen production efficiency of hybrid seawater electrolysis devices hinges on high‐performance catalytic materials with superior activity and chl...
Coordination‐Driven Direct C─H Metalation of <i>N</i> ‐Heterocycles With a Superbasic Co(II) Amide Co(TMP) <sub>2</sub>
ABSTRACT Metalation of N ‐heterocycles such as pyridines or diazines with conventional alkali metal bases is particularly...
Diastereodivergent Hydroamidation of Methylenecyclohexanes With Differentiated Active Catalytic Species
ABSTRACT The construction of three‐dimensional (3D) organic molecular structures is pivotal in modern organic chemistry. For three dimensionally structured disub...
Decoupling Electronic Effects in Oxygen Reduction Catalysts via a Model Nanowire Platform
ABSTRACT Understanding the intrinsic role of electronic structure in governing oxygen reduction reaction (ORR) activity on Pt‐based catalysts remains a long‐standing challenge due to...
Protonation‐Triggered Unlocking of Interlayer Carbon Nitride for Rapid Nanosheet Preparation
ABSTRACT The intrinsic topological and electronic merits of graphitic carbon nitride (g‑C 3 N 4...
4‐Formyl‐N‐Methylpyridinium‐Mediated N‐Terminal Cysteine Modification/Removal Facilitates One‐Pot Multiplex Peptide Ligation
ABSTRACT The chemical synthesis of proteins with site‐specific modifications remains a fundamental challenge in chemical biology. One‐pot peptide ligation strate...
Uncovering Aggregation‐Induced Emission in Carbon Dots for Color‐Changing Hydrogels and Information Encryption
ABSTRACT Since the discovery of carbon dots (CDs), the typical precursor combination of citric acid (CA)‐urea has been widely used in the scientific community to explore the formatio...
CO <sub>2</sub> ‐Derived Degradable Polythioester Adhesives From Proton‐Trap‐Assisted S/O Isomerization‐Driven Cationic Ring‐Opening Polymerization
ABSTRACT The development of degradable pressure‐sensitive adhesives (PSAs) holds great promise for enabling the recycling of adhesive‐containing materials. Howev...
Unlocking an All‐Anisotropic‐Component Integrated Paradigm Toward Practical Solid‐State Zinc Metal Pouch Cells
ABSTRACT High‐safety and low‐cost Zn metal batteries hold great promise for energy storage, but their limited energy density remains a major bottleneck restricti...
Synergistic Interaction Between N‐Heterocyclic Carbene (NHC)‐Anchored Cu(I) Atom and In Situ‐Generated Cu Nanoparticles in a Post‐Modified MOF‐808 Framework Promoting C─C Coupling in CO <sub>2</sub> Reduction
ABSTRACT The electrochemical reduction of CO 2 to high‐value chemicals like C 2 H...
Charge‐Directed Photothermal Methane Dry Reforming Enabled by Interfacial TiO <i> <sub>x</sub> </i> Nanodomains
ABSTRACT Photothermal dry reforming of methane (DRM) enables solar‐driven upgrading of CH 4 and CO 2...
Predictive Registry Optimization of Molecular Adsorbates on Solid Surfaces
ABSTRACT Understanding and predicting how large organic molecules adsorb on crystalline substrates is essential for designing functional surfaces in electronics, catalysis, and supra...
Incorporation of Organic Counter‐Cations Into Poly(Heptazine Imide) Networks for Promoting Proton‐Coupled Electron Transfer During Photocatalytic H <sub>2</sub> O <sub>2</sub> Evolution
ABSTRACT Nitrogen based onium ions such as methylammonium (MA + ), formamidinium (FA +...