Angewandte Chemie International Edition
Articles in this Issue
Tae Su Choi
Outside Back Cover: Fortification of FeS Clusters Reshapes Anaerobic CO Dehydrogenase into an Air‐Viable Enzyme through Multilayered Sealing of O <sub>2</sub> Tunnels
Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels–Alder Reaction
Abstract Fleeting molecules possessing strained multiple bonds are important components in organic synthesis due to their ability to undergo various chemical reactions driven by the...
Self‐Driven Seeding, Acid Stalling, and Solidifying: Time‐Resolved Mapping of Nonclassical Pathways in Metal–Organic Gel Assembly
Abstract Metal‐organic gels (MOGs), an innovative subset of metal‐organic frameworks (MOFs), feature hierarchically porous architecture and self‐shaping monolith...
Enhancing Clinical Detection Accuracy of Large Structured Viral RNA via DNAzyme Cleavage and Antisense‐Assisted Rolling Circle Amplification
Abstract Sensitive detection of viral RNA is critical for accurate diagnostic testing, particularly during outbreaks of emerging infectious diseases. Rolling circle amplification (RC...
Correction to “Dynamic Phosphorescence Behavior of Carbene‐Metal‐Amide Complexes from the Perspective of Excited State Modulation”
Twisting Chiral Aggregation‐Induced Emission Macrocycles into a Microhelix with Boosted Circularly Polarized Luminescence
Abstract The design and assembly of chiral macrocycles remain an underexplored frontier in supramolecular science. In this study, we synthesized a pair of enanti...
Carbocation‐Based Multiresonance Thermally Activated Delayed Fluorescent Emitters with Efficient Narrowband Electroluminescence
Abstract Multiresonance thermally activated delayed fluorescent (MR‐TADF) emitters hold great promise for ultrahigh‐definition displays, but are fundamentally re...
Phosphorylation Regulation Promotes Bidirectional Dynamic Adaptive Interface for Achieving Stable Zn–I <sub>2</sub> Batteries
Abstract Unstable electrode–electrolyte interfaces resulting from severe cathodic polyiodide shuttling, anodic parasitic corrosion reactions, and dendrite growth...
Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation
Abstract Transition‐metal‐free aluminosilicate FER‐type zeolite has been demonstrated to effectively catalyze methane to methanol using N 2...
Corrosion of Calcium Metal in Ca(TFSI) <sub>2</sub> /DMAc Electrolyte and its Solution via Alloy Interface and Competitive Solvation
Abstract Calcium metal batteries (CMBs) are promising for large‐scale energy storage due to calcium‘s abundance and high theoretical capacity, but hindered by po...
Embedded‐Type Cu Nanoparticle with Largely Enhanced Catalytic Activity and Stability Toward Methanol Steam Reforming
Abstract Hydrogen production through low‐temperature methanol steam reforming (MSR) reaction plays a critical role in the development of new energy but remains a...
Ultrafast (600 ps) Vacuum‐UV Reflective Scintillation Enabled by Surface Exciton Recombination in Layered Perovskite PEA <sub>2</sub> PbBr <sub>4</sub>
Abstract Vacuum ultraviolet (VUV) photodetection is pivotal for space exploration and radiation monitoring, yet its dynamic imaging capability is significantly h...
Stimuli‐Responsive Catenane‐Branched Dendrimers with Tunable Dimension for Reversible Guest Binding
Abstract To tackle the challenge of the precise construction of catenane‐based mechanically interlocked macromolecules with well‐defined topological arrangements, starting from a nov...
Highly Efficient Suzuki–Miyaura Polymerization Enabled by Direct Transmetalation with Boronic Esters
Abstract The Suzuki–Miyaura cross‐coupling reaction plays a pivotal role in the construction of carbon–carbon bonds, utilizing low‐toxicity and readily available organoboron substrat...
An Integrated Tandem‐Structured Separator Enables Dual‐Enhanced Stable Interfaces for Long‐Cycle‐Life and High‐Areal‐Capacity Aqueous Zinc–Iodine Batteries
Abstract Aqueous zinc–iodine batteries (AZIBs) hold great promise for next‐generation energy storage technologies due to their inherent safety, cost‐effectivenes...
Strain‐Induced Benzannulation of Oxaquadricyclanes Promoted by a Polyoxometalate Photocatalyst
Abstract Given the significance of strain‐release reactions, various spring‐loaded molecules have emerged as important building blocks in diverse fields of chemi...
Gram‐Scale Ammonia Synthesis via Electrochemical Nitrate Reduction Using Enzyme‐Inspired Dual‐Atomic Cu Catalyst
Abstract The potential application prospects of green electricity‐driven electrocatalytic nitrate reduction (NO₃RR) technology for the production of valuable amm...
Advancing Sulfinyl Radical Chemistry: An Asymmetric Smiles Rearrangement with Chiral Sulfoxides
Abstract Chiral N‐sulfinyl amides have recently emerged as powerful reagents for asymmetric, radical‐mediated Smiles rearrangements, imparting excellent levels of relative and absolu...
Deciphering the Role of Lattice Selenium in Electrocatalytic Self‐Reconstruction for Boosting Alkaline Hydrogen Evolution
Abstract Cathode reconstruction is equally crucial for water electrolysis, yet it has received less attention than anode. Lattice selenium (Se) doping is an effe...
Realizing Persistent Lithium Protection and Revival with Dissolution‐Equilibrium‐Driven Sustainable Additives Reservoir
Abstract Additive chemistry plays a pivotal role in enhancing the cycling stability of lithium metal batteries. Conventional additives with high solubility facil...
Modulating Spin State of Ni Single Atomic Center for High‐Performance Electrocatalytic Carbon Dioxide Reduction
Abstract Single‐atom catalysts (SACs) have been widely investigated and regarded as promising electrocatalysts for carbon dioxide reduction. However, studies on...
Strategic Secondary Coordination Implantation Towards Efficient and Stable Fe─N─C Electrocatalysts for the Oxygen Reduction Reaction in PEMFCs
Abstract While state‐of‐the‐art Fe─N─C catalysts demonstrate platinum‐comparable initial activity for the oxygen reduction reaction (ORR), their operational dura...
Modular Synchronous Synthesis of Amides and α‐Ketoamides Realized by Matching Electrolysis‐Paired Tandems
Abstract Feasible electrolysis‐paired tandem synthesis represents an elaborately organized and high‐efficiency strategy balancing energy consumption and value‐ad...
Nitrogen‐Centered Organic Persistent Radicals Catalyze Redox‐Neutral C─C Bond Forming Reactions
Abstract We report that nitrogen‐centered persistent radicals, Kuhn verdazyls, are effective, tunable ground‐state redox organocatalysts for single electron transfer (SET)‐initiated...