Angewandte Chemie International Edition
Articles in this Issue
H<i><sup>δ</sup></i><sup>−</sup>–H<i><sup>δ</sup></i><sup>+</sup> Comproportionation Enables Stable Li–N–H–F Solid Electrolyte
AbstractNitride family compounds are among the earliest explored materials for solid electrolytes (SEs). The main challenge lies in effectively enhancing their electrochemical stability without compro...
Dendritic Pillar[6]Arenes with Fixed Planar Chirality for Stereoselective Inclusions in Water: A Case of Facile Differentiation of Cocaine Adulterants, Levamisole and Dexamisole
AbstractWe describe the preparation, conformational dynamics, and stereoselective recognition characteristics of water‐soluble pillar[6]arenes pS–212− and pR–212−. These two novel and diastereomeric c...
A Water Soluble and Solid‐State Molecular Solar Thermal (MOST) System as Renewable Solar Fuel
AbstractSolar energy storage is key to overcome the intermittent character of sunlight. We present a sustainable solution based on norbornadiene–quadricyclane pairs for molecular solar thermal (MOST)...
Programmable Circularly Polarized Electroluminescence Through Stereocontrol of Chiral Liquid‐Crystalline Co‐Assemblies
AbstractCircularly polarized organic light‐emitting diodes (CP‐OLEDs) are essential to prospective 3D displays and advanced polarized lighting systems. The rational design of programmable circularly p...
Convergent Electrochemical–Chemical Tandem Catalysis Synthesis of Ethylene Oxide from CO<sub>2</sub> and Water at Ambient Conditions
AbstractEthylene oxide (EO) is an important commodity chemical, and its production currently relies on fossil fuel‐based energy‐intensive thermocatalysis associated with substantial CO2 emissions or t...
Tuning Surface Concentrations of Building Units to Enable the Cathodic Deposition of Metastable ZIF‐L Films for Gas Separations
AbstractCathodic deposition is an emerging technique for the preparation of metal–organic framework (MOF) films. However, monitoring and controlling the concentrations of MOF building units (i.e., met...
Harnessing Dual Hydrogen Bonding and <i>Lewis</i> Acid–Base Interactions for Bio‐Inspired Symmetry‐Breaking Electrolytes in Aqueous Zinc‐Ion Batteries
AbstractAqueous zinc‐ion batteries (ZIBs) offer a safe, cost‐effective alternative for large‐scale energy storage but are hindered by zinc dendrite growth, hydrogen evolution reactions (HER), and unst...
A Genetically Encoded Assay System to Quantify <i>O</i>‐GlcNAc Transferase (OGT) Activity in Live Cells
AbstractO‐GlcNAc transferase (OGT) catalyzes O‐GlcNAcylation of many nucleocytoplasmic proteins and plays important roles in regulating diverse cellular functions. Dysregulation of OGT is implicated i...
Ampere‐Level Electrosynthesis of <sup>15</sup>N‐Labeled Oximes by Alloy Synergy Activation and Hydroxylamine Overhydrogenation Inhibition
Abstract15N‐labeled molecules are essential for industrial drug development and medical imageology. However, the synthesis of 15N‐labeled molecules suffers from the complex procedure of de novo synthe...
Adaptive Hydration Chemistry Enables Fast and Durable Zinc‐Ion Batteries
AbstractAqueous zinc‐ion batteries (AZIBs) are promising candidates for large‐scale energy storage; however, uncontrolled interfacial water remains a major hurdle, limiting both anode stability and io...
Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals
AbstractChiral organic–inorganic hybrid metal halides have emerged as a promising class of materials for spin‐controlled optical and optoelectronic effects and related applications. Chiral hybrid meta...
Ligand‐Engineered All‐In‐One Cu(I) Iodide Complex Enables Near‐Unity Photoluminescence and Advanced 3D X‐ray Image Reconstruction
AbstractHigh‐performance X‐ray detectors are essential for 3D X‐ray imaging in computed tomography (CT), but conventional systems require high radiation doses to achieve fine resolution. All‐In‐One (A...
Transforming Crowded Coacervates into Multi‐Compartmental Hybrid Microreactors for Practical Enzymatic Catalysis
AbstractAdvancing the design and construction of artificial protocells with organized complexity, diverse functionality and practical applicability is urgently demanded in vitro synthetic biology and...
Precisely Bonded Fe─Cu Diatomic Sites with Nitrogen‐Bridged Coordination on Hollow C<sub>3</sub>N<sub>4</sub> Spheres for Efficient C─N Coupling and Selective Photocatalytic Urea Synthesis
AbstractThe photocatalytic synthesis of urea from CO2 and N2 co‐reduction presents a promising alternative to the conventional energy‐intensive Haber–Bosch process. However, competitive adsorption on...
A Universal Voltage‐Enhancement Strategy Based on Multifunctional Ligand‐Mediated Modulation for Na‐Layered Oxide Cathode
AbstractSodium‐ion batteries (SIBs) have emerged as promising energy storage solutions due to resource abundance and low cost, yet their practical deployment is hindered by limited operating voltages...
“Dual‐Key”‐Controlled Activatable Semiconducting Polymer Nanoprobe for Highly Precision Phototheranostics Under NIR‐II Light Excitation
AbstractThe development of activatable optical probes has proved to be a promising approach to improve the accuracy of phototheranostics. However, most such probes are usually responsive to single pat...
Cyclometalating Ligand Affords NIR Absorption in Ruthenium Complexes for Type‐I Photodynamic Therapy
AbstractThe development of NIR photosensitizers (PSs) based on Ru complexes with Type‐I process holds substantial promise for photodynamic therapy (PDT) of cancer, though this breakthrough remains unr...
“Twisted” Terpolymer Donor Enabling High‐Performance Intrinsically Stretchable Organic Solar Cells
AbstractIntrinsically stretchable organic solar cells (is‐OSCs) hold great potential for next‐generation wearable power generators. Currently, high‐efficiency polymeric donor materials are based on ri...
Control Over S(VI) Stereogenicity for the Asymmetric Synthesis of Sulfonimidoyl Derivatives by Isothiourea‐Catalyzed Covalent Activation of Sulfur(VI) Atoms
AbstractIn contrast to the notable advancements focusing on the preparation of optically enriched S(IV) frameworks in recent years, achieving catalyst stereocontrol over S(VI) stereogenicity to genera...
Sustained Release of Underpotential Deposition Initiators for Ah‐Level Zinc Metal Batteries
AbstractElectrolyte additives effectively stabilize aqueous zinc‐ion batteries (AZIBs), yet their depletion during long‐term cycling leads to eventual battery failure. Here, we address this common iss...
Toward Bimetallic Nanowire Arrays with Controlled Compositions Using Block Copolymer Films: The Interplay Between Metal Precursors
AbstractMetallic nanowire (NW) arrays are promising components for nanotechnology owing to their elongated, continuous, and directional structure. Bimetallic NWs present synergistic effects that are a...
Sustained, Reversible, and Adaptive Non‐Equilibrium Steady States of a Dissipative DNA‐Based System
Abstract Inspired by nature, researchers have developed several chemical fuel‐driven supramolecular systems aimed at achieving improved kinetic control over their formation and funct...
Mechanistically Engineered Heterojunction From Spent LFP for Efficient Oxygen Evolution Electrocatalysis
AbstractThe large‐scale retirement of LiFePO4 (LFP) batteries demands sustainable strategies for material recovery and functional repurposing. However, the inert micrometer‐scale morphology and electr...
Micellar Brush‐Directed Oxophilic Zr‐Doped RuO<sub>2</sub> Nanoarrays for Durable Acidic Oxygen Evolution Reaction
AbstractAlthough being considered as a promising alternative to iridium‐based catalysts in proton exchange membrane water electrolysis (PEM‐WE), cost‐effective ruthenium (Ru)‐based anodic catalysts ge...
Orthogonal Control of Lattice Oxygen Activation and Oxygen Evolution Reaction Suppression via “Molecular Gates” for High‐Efficiency Nitrile Electrosynthesis
AbstractA fundamental barrier to industrial electrosynthesis is the inescapable trade‐off between activity and selectivity at high current densities, where parasitic reactions overwhelm the desired in...