Angewandte Chemie International Edition

Interface‐Targeting Integrated Sandwich‐Structured Na ₃ Zr ₂ Si ₂ PO ₁₂ Composite Electrolyte for Ultra‐Long Cycle Life Sodium Metal Batteries

Abstract Na 3 Zr 2 Si 2 PO...

Enhancing the Self‐Assembly of Step‐Growth Polymers by Narrowing Their Molar Mass Distribution: A Dynamic Bond‐Mediated Approach

Abstract Step‐growth polymerization (SGP) typically produces polymers with exceptional versatility in terms of applications, but its inherently uncontrolled natu...

Reversing Pt/C Degradation Via Ni(OH) ₂ ‐Wrapping Induced Spreading of Electric Field for Alkaline Hydrogen Evolution Reaction

Abstract Low mass activity due to unfavorable water dissociation and insufficient stability are two primary challenges for Pt catalysts. Herein, we find that the...

Size‐Selective Functionalization of Sugars and Polyols Using Zeolites for Renewable Surfactant Production

Abstract Diol functionalization with acetals in carbohydrates and polyols is ubiquitously used in protection chemistry and in the manufacture of several platform chemicals. However,...

Single‐Molecule Protein Profiling Using Nanopores and Dimeric Aptamer‐Modified DNA Carriers

Abstract Single‐molecule protein profiling offers unparalleled sensitivity for detecting rare biomarkers, with significant potential for early disease diagnosis and monitoring. Nanop...

Reactions of Difluorocarbene with Organogold(I) Complexes: Synthesis of Gem‐Difluoromethylene Organometallics via Difluorocarbene Insertion and Cycloaddition Reactions

Abstract The g em ‐difluoromethylene functional group is an important motif in medicinal chemistry, and development of ne...

Inter‐Nanoparticle FRET for Biosensing: Photophysics Versus Size

Abstract Förster resonance energy transfer (FRET) enables the quantification of nanoscale distances and biomolecular interactions. Luminescent nanoparticles (NPs) are frequently comb...

Supramolecular Confinement of Cyclodextrin‐Like Host–Guest Polyoxovanadate in Giant Ag ^0/I Nanoclusters

Abstract Although polyoxovanadates (POVs) and their silver nanocluster composites have attracted significant research attention owing to their remarkable structu...

Edge/Corner‐Sharing 2D Perovskite Functional Layer for Efficient and Stable Inverted Perovskite Solar Cells

Abstract Tuning the surface structure of perovskite films based on two‐dimensional (2D) perovskites with narrow octahedral interlayer spacing is essential yet ch...

An Electrochemical Study of Key Catalytically Active Gold Complexes

Abstract Gold catalysis has long been dominated by the ability of gold(I) to activate unsaturated systems as a carbophilic Lewis acid. However, recent advances h...

Deoxygenative Functionalization of Alcohols and Carbonyl Compounds via Electrochemical Reduction

Abstract Oxygen‐containing functional groups are prevalent motifs in natural products and feedstock chemicals, but direct methods for their deoxygenative transformation remain rare d...

Polymerisation‐Induced Self‐Assembly on Planar Surfaces: A New Approach for Controlling Surface Topography and Modulating Material‐Bio Interactions

Abstract Polymerisation‐induced self‐assembly (PISA) has emerged as a highly efficient method for synthesising polymeric nanoparticles with diverse and well‐defined morphologies for...

Postassembly Modification of Interior Spaces Within M ₁₂ L ₂₄ Nanospheres

Abstract Post assembly modification (PAM) of coordination‐based supramolecular self‐assemblies has developed in the past 10 years as a tool that allows expansion...

A Chiral Organic Radical Ferroelectric with Magnetic Circular Dichroism

Abstract Chiral ferroelectrics are attracting tremendous interest because of their unique intrinsic chirality and various intriguing optical properties, such as...

Outside Back Cover: C ₆₀ Fullerene as the Active Site for CO ₂ Electroreduction (Angew. Chem. Int. Ed. 39/2025)

Atomically Dispersed Zn and Ir Synergistic Modulation of Substrate and Active Sites for High‐Performance Ammonia Oxidation

Abstract A rationally designed, bifunctional ammonia‐oxidation catalyst spatially decouples NH 3 activation and *OH adsor...

Switching‐Off to Switching‐On Triplet Formation Through Singlet–Triplet Intersystem Crossing in Porphyrin Metal–Organic Frameworks

Abstract Solid‐state artificial photosystems need precise control over their singlet or triplet excited states to enable desired photochemical transformations. W...

Three Is Better than One: A Multimetal Complex that Triggers Immunogenic Cell Death

Abstract Immunogenic cell death (ICD) is a form of regulated cell death capable of stimulating an adaptive immune response through release of damage‐associated m...

Simultaneous Charge Extraction Enhancement and Defect Passivation Via a Planar Conjugated Molecular Interface Enable 22.49%‐Efficient Inorganic Perovskite Solar Cells

Abstract Rational molecular design at the perovskite/hole transport layer (HTL) interface presents a viable strategy to suppress nonradiative recombination in Cs...

Spatially Engineered Ternary Schottky/S‐Scheme Heterojunctions for Artificial Photosynthesis

Abstract Photocatalytic CO 2 reduction into solar fuels presents a promising strategy for carbon mitigation and sustainab...

Bispecific DNA‐Peptide Probes for Targeting Receptor Pairs on Live Cells

Abstract Chemical modification and nucleic acid self‐assembly can be used to make protein receptor ligands form specific arrangements. While this property has be...

The Pentafluorophenyl Cation: A Superelectrophile and Diradical

Abstract We report the first direct observation of the pentafluorophenyl cation in the gas phase via vacuum ultraviolet (VUV) photoionization (PI) of the thermal...

Specific Recognition of Cysteine in a Mixed‐Valence Bimetallic Organic Framework with Unique Channel Properties

Abstract We have successfully designed and synthesized a mixed‐valence bimetallic metal‐organic framework (MOF), denoted ZnCoBTCHx, featuring periodic tubular an...

Social Chiral Self‐Sorting Synthesis of [9]Cycloparaphenylene‐Pillar[5]arene Heterochiral Multicavity Macrocyclic Trimers with Circularly Polarized Luminescence

Abstract The precise synthesis of stereochemically controlled multicavity macrocyclic hosts based on pillar[ n ]arenes pr...

Tailoring Dual‐Site Defect Passivation Molecules to Minimize Buried Interface Energy Loss for Highly Efficient and Stable Perovskite Solar Cells

Abstract The modification of interfaces in perovskite solar cells (PSCs) to achieve mitigation of carrier transport barriers and suppression of non‐radiative rec...