Angewandte Chemie International Edition
Articles in this Issue
Nickel‐Catalyzed Chemo‐ and Diastereoselective Dearomative Dialkylation of Indoles with Two Different Alkyl Halides
Abstract The catalytic dearomative dicarbofunctionalization of indoles constitutes one of the most efficient ways to access poly‐substituted indolines that are p...
Open‐Air, Ultrafast Photoiniferter Polymerization Enables 3D Printing with Low‐Viscosity Resins
Abstract Photo‐curing 3D printing is fundamentally challenged by the formation of heterogeneous networks with uneven cross‐linking densities and unreacted monome...
Additive Luminescence Lifetime Tuning of Upconversion Nanoparticles for High‐Capacity Optical Encoding
Abstract The tunable upconversion luminescence lifetime of lanthanide‐doped upconversion nanomaterials offers great potential for stable and precise optical encoding in the temporal...
Selective Hydrodemethylation of Methylalkylbenzenes on Potassium Hydride
Abstract Dealkylation and hydrodealkylation of alkylaromatics are key processes in the petrochemical industry. The typical susceptibility of alkyl groups to remo...
A General Strategy to Access Pharmaceutically Relevant Pyridines from Nitroarenes
Abstract The incorporation of nitrogen atoms into aromatic systems is a cornerstone of modern drug design, enabling precise modulation of molecular properties and enhanced bioactivit...
Interfacial Charge Orchestration for Durable Aqueous Zn Batteries
Abstract Aqueous Zn||MnO 2 batteries offer a compelling solution for large‐scale, low‐cost, and safe energy storage, yet...
One‐Pot Incorporation of Quantum Defects into Single‐Walled Carbon Nanotubes with Arylazo Sulfonates
Abstract Single‐walled carbon nanotubes (SWCNTs) consist of a carbon monolayer and fluoresce in the near‐infrared (NIR, 800–2500 nm) region. Introduction of sp...
Orbital Charge Exchange Transition Conceptually Activates Multi‐Bifunctional Li–O <sub>2</sub> and Li–CO <sub>2</sub> Pathways at Deep and Shallow Energy Levels in Li–Air Batteries
Abstract In Li‐air batteries (LABs), the deep and shallow orbital distributions of reactants in Li–O 2 and Li–CO...
Ampere‐Level Membrane‐Free Bipolar Ammonia Electrosynthesis with Faradaic Efficiency Exceeding 100% on a Surface‐Reconstructed NiFe‐Hydroxide
Abstract Awaking the force of materials for specific efficacy by precise electronic modulation remains a fundamental challenge in catalysis. Herein, we transform...
Stabilizing Intrinsic Phase of Phase‐Pure FAPbI <sub>3</sub> by Organic Molten‐Salt Molecular Bridges
Abstract Phase‐pure formamidinium lead iodide (FAPbI 3 ) is a highly promising absorber for perovskite solar cells (PSCs)...
Dynamic Metal‐Organic Tube Isomers
Abstract Preparing artificial assemblies that can achieve multi‐stimuli‐responsive and multi‐level transformations remains a huge challenge. Here, a pair of dyna...
Low‐Concentration Electrolytes Based on Weakly Coordinating Anions for Applications in Lithium‐Ion‐Batteries and Lithium‐Metal‐Batteries
Abstract 0.2 M Low Concentration Electrolytes (LCEs) for lithium‐based batteries formed from lithium salts with very weakly coordinating anions, i.e., the alumin...
Hierarchical Helical Toroids Constructed from One‐pot Controllable Self‐Assembly of Polypeptides
Abstract Self‐assembly has proven to be a robust strategy for constructing intricate hierarchical structures. The construction of chiral or toroidal nanostructures has attracted cons...
Promoting Water Dissociation and Acetylene Transfer to Lower the Energy Consumption of Ethylene Electrosynthesis via Microenvironment Regulation
Abstract The critical challenge in the conversion of electrocatalytic acetylene (C 2 H 2...
Site‐Selective Ligand Selection by Mutational Profiling for Covalent RNA Targeting
Abstract To facilitate the design of RNA‐targeted covalent probes we report a bottom‐up, structure‐informed approach using mutational profiling. We designed a co...
Enhanced Resolution in EPR Spectroscopy Using <i>para</i> ‐Hydrogen Matrices
Abstract We developed a matrix isolation experiment utilizing a closed‐cycle helium cryostat, which operates at 2.5 K and enables electron paramagnetic resonance...
Atomically Isolated Cd Sites Boosting CO Electroreduction to C <sub>2+</sub> Alcohols at Ampere‐Level Current Densities
Abstract Herein, two Cu‐based model electrocatalysts, Cu nanosheets modified with Cd single atoms (Cd‐SACs@Cu NS) and unmodified Cu nanosheets (Cu NS), were rati...
A Photoelectrocatalytic Platform for Sequence‐Unrestricted Modification of Oligonucleotide Backbones
Abstract Oligonucleotide‐based therapeutics represent a transformative modality for treating genetic disorders, yet their clinical translation is often hindered...
Zwitterion‐Induced Interfacial‐Potential Regulation Stabilizes Micron‐Sized Silicon Anodes in Quasi‐Solid‐State Lithium‐Ion Batteries
Abstract Micron‐sized silicon (μ‐Si) is an attractive anode material for high‐energy lithium‐ion batteries owing to its high tap density, large specific capacity...
Enantioselective Total Synthesis of (−)‐Bisabosqual F via N‐Heterocyclic Carbene Catalyzed (4+2) Annulation
Abstract In 2001, a family of meroterpenoids, the bisabosquals, were isolated from the Stachybotrys fungi during studies...
Brominated Pd‐on‐Au Nanostructures Enable Reductive Relay Isomerization of Alkynes to <i>E</i> ‐alkenes
Abstract Achieving stereoselective alkyne semi‐hydrogenation to E ‐alkenes remains a persistent challenge due to inherent...
Unlocking the Continuous Flow Asymmetric Hydrogenation of Olefins Through the Development of a Non‐Deactivating Immobilized Iridium Catalyst
Abstract Asymmetric hydrogenation (AH) is a leading method for producing enantiopure compounds and several industrial processes rely on its chemical efficiency. However, these proces...
Single MOF Based on Asymmetric Intramolecular Electron Compartments Enables Highly Efficient Photocatalytic CO <sub>2</sub> Overall Reaction to Methanol
Abstract The development of single‐component photocatalysts that can achieve highly efficient photocatalytic CO 2 overall...
Adapting Direct Arylation Polycondensation for Arbitrary Mixed Ionic and Electronic Conductors
Abstract Direct arylation polycondensation (DArP) has been developed as a straightforward method for synthesis of conjugated polymers. However, it encounters sev...
Photo‐Activated Emission and Chirality Transfer Based on Host–Guest Chemistry of a Motorized All‐Benzene Nanohoop
Abstract In this study, a series of motorized carbon nanohoops M[8]CPP , M[9]CPP...