Angewandte Chemie International Edition
Articles in this Issue
Programming Palladium Cage Geometry through Ligand Redox Modulation
ABSTRACT Incorporating redox active ligands into coordination cages offers a direct way to reach architectures whose structure or composition can be modulated in...
Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO <sub>2</sub> Capture for Sustainable Agriculture via a Robust CuPd Heterojunction
ABSTRACT The transition to sustainable agriculture requires technologies that simultaneously enhance crop yields and reduce environmental impacts. Solar‐driven n...
Asymmetric Fe–Te Pairs Enhance Peroxymonosulfate Activation via Surface‐Bound Hydroxyl Radicals Pathways
ABSTRACT Controlling peroxymonosulfate (PMS) activation at the atomic scale is crucial for steering reactive oxygen species (ROS) pathways, yet design principles...
An Ultrastable Hydrogen‐Bonded Organic Framework With Two‐Dimensional Pores for Rapid Adsorption Kinetics and Efficient Xe/Kr Separation
ABSTRACT Developing hydrogen‐bonded organic frameworks (HOFs) for highly efficient Xe/Kr separation is an attractive alternative for producing high‐purity noble...
Helical Ladder Bottlebrush Polymers With Tunable Helicity and Circularly Polarized Luminescence
ABSTRACT Helical ladder polymers possess rigid, helically fused backbones that confer distinctive chiroptical properties, yet their integration into polymer brush architectures remai...
A Circular and Tacticity‐Independent Crystalline Mono‐Substituted Nylon‐6 Platform: Unexpected Large Positional Effects on Crystallizability and Performance
ABSTRACT Seeking recyclable, more sustainable alternatives to nylon 6 has drawn much attention, but achieving its variants with both crystallinity and enhanced recyclability still re...
Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds
ABSTRACT Geminal difunctionalization of carbonyl‐derived building blocks represents a versatile strategy for the rapid generation of sp 3...
Catalytic Asymmetric Construction of Si‐Chiral Silabicyclo[3.3.1]Nonanes Using Functionalized Prochiral Silacyclohexanones
ABSTRACT The development of chiral three‐dimensional, sp 3 ‐rich architectures to facilitate the discovery of potent func...
Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the <i>As</i> , <i>CC</i> , <i>As</i> Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne
ABSTRACT Alkyne complexes are known for transition metals across the d‐block with exception of the radioelement technetium despite considerable synthetic efforts...
Anomeric‐Effect‐Guided Saturated Weakly Solvating Electrolytes for Ultrastable High‐Voltage Sodium Metal Batteries
ABSTRACT Sodium metal batteries are promising for next‐generation energy storage, leveraging low‐cost sodium and highly reversible sodium metal anodes enabled by...
Ordered Ba <sub>2</sub> EuIrO <sub>6</sub> Double Perovskite With Active Ir─O <sub>bri</sub> ─Eu Unit for Enhanced Electrocatalytic Oxygen Evolution in PEMWE
ABSTRACT The design of a low‐Ir‐loading anode catalyst with high activity and stability is crucial for the proton exchange membrane water electrolysis (PEMWE), y...
Bimetallic Ni <sub>3</sub> Fe/Ni <sub>2</sub> Fe <sub>2</sub> N Catalyst With Optimized <i>d</i> ‐Band Center for High‐Efficiency Lithium–Sulfur Batteries
ABSTRACT Lithium–sulfur batteries (LSBs) face significant challenges for practical application, primarily due to the sluggish reaction kinetics and pronounced sh...
Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes
ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling access to low‐dimensional carbon‐based materials, often unattainable...
Fluorinative Rearrangement of Vinyl Diazo Compounds Enabled by a New Reactivity Mode of Cyclopropanediazonium Ions
ABSTRACT Although selective transformations of aromatic and purely aliphatic diazonium ions are well‐established, the reactivity of the unique cyclopropanediazonium (CPD) ions remain...
Decoding Carbon Dot Purity by Nuclear Magnetic Resonance
ABSTRACT Carbon dots (CDs) have attracted increasing attention in recent years and have been widely explored in many fields. However, several challenges still li...
About the Role of Interfacial Lattice Oxygen in Pd─Pt Alloy for C─C Cleavage in Ethanol Electrooxidation
ABSTRACT The electrocatalytic ethanol oxidation reaction is bottlenecked by inefficient C─C bond cleavage. This challenge is epitomized at metal‐oxide heterointe...
Hexamethoxy Triazocoronene Based Covalent Organic Frameworks: A Family of Tailored Tools for Efficient Gold Recovery
ABSTRACT Covalent organic frameworks (COFs) have recently emerged huge prospects as new adsorption platforms for gold recovery, however, the design and construct...
Accelerated Discovery‐to‐Unveiling of High‐Performance and Affordable Ammonia Electrode Process by Human–Machine Collaboration Framework
ABSTRACT The electrochemical nitrate reduction reaction (eNO 3 RR) to ammonia (NH 3...
Spiro‑Linked Double Tetraphenylethenes: Solid‐State Emission and Circularly Polarized Luminescence Imaging
ABSTRACT Herein, we report the synthesis and structural characterization of two spiro‐linked tetraphenylethenes and investigate their optical properties in solution, as aggregates, a...
Multidentate Chelation Modulates PbI <sub>2</sub> Crystallization and Buried‐Interface Formation in Perovskite Solar Cells
ABSTRACT The buried interface in two‐step processed perovskite solar cells (PSCs) remains a major performance‐limiting factor, primarily due to incomplete PbI...
Catalyst‐Controlled Chemodivergent Carbene Transfer Reactions With Bicyclo[1.1.0]butane‐Derived Acceptor Metallocarbenes
ABSTRACT Transition‐metal‐catalyzed carbene transfer reactions are powerful tools in organic synthesis, yet they traditionally rely on diazo compounds, which rai...
Edge‐Engineered Interfacial Carrier Dynamics for Efficient Photocatalytic Gold Recovery
ABSTRACT Developing highly efficient and sustainable precious metal recovery technologies is critical for meeting escalating global demand and mitigating the sev...
Herbert Walter Roesky (6.11.1935–5.12.2025): One Who Set Out to Learn Chemistry
<i>β</i> ‐Ketoenamine Porous Organic Cage Membranes Through Hydrogel‐Induced Shielding for Efficient Ion Sieving
ABSTRACT Porous organic cages (POCs) with intrinsic and extrinsic microporosity offer a promising platform for efficient ion sieving. However, assembling these c...
Electroreductive Radical C–C Acylation Coupling from <i>N</i> , <i>N</i> ‐Dimethylamides and Organic Halides via Inert C(O)−N Bond Cleavage: Facile Access to Aryl Ketones
ABSTRACT The conversion of amides to ketones via C(O)−N bond cleavage has attracted significant attention, with cross‐electrophile coupling (XEC) between amides...