Angewandte Chemie International Edition
Articles in this Issue
Asymmetric Electrolytes Govern Tetrahydroxozincate Dynamics for Stable Alkaline Zinc Batteries
ABSTRACT Green electrochemical energy storage is essential for carbon neutrality, and alkaline zinc batteries offer a compelling solution due to their inherent s...
Tuning Redox Behavior of Pyrene–Benzothiadiazole/TTF–Based Covalent Organic Framework Electrodes in Dual‐Ion Batteries
ABSTRACT Covalent organic frameworks (COFs) have emerged as promising electrode materials for secondary‐ion batteries, where redox‐active building blocks and lin...
Surface‐State–Regulated Product Distribution in Photothermal CO <sub>2</sub> Hydrogenation Over MXene‐Based S‐Scheme Catalyst
ABSTRACT The rational design of heterostructured photocatalysts that simultaneously enable efficient carrier separation, photothermal synergy, and controllable r...
Metal Node Guided Pore Engineering in Carborane‐Based MOFs for Efficient C <sub>2</sub> H <sub>2</sub> /CO <sub>2</sub> and C <sub>2</sub> H <sub>2</sub> /C <sub>2</sub> H <sub>4</sub> Separations
ABSTRACT The efficient separation of C 2 H 2 from C 2...
Harnessing Controlled Dealloying–Support Coupling for Ultrastable PtNi Catalysts in PEMFC Applications
ABSTRACT Platinum–transition metal (PtM) alloys are among the most promising oxygen reduction reaction (ORR) catalysts, yet their practical deployment in proton‐...
The Important Role of Carbonyl in Accelerating Reverse Intersystem Crossing for Selenium‐Based Organoboron Narrowband Blue Emitters
ABSTRACT Narrowband emissive polycyclic aromatic heterocycles (PAHs) featuring multiple resonance thermally‐activated delayed fluorescence (MR‐TADF) are capable...
Efficient Removal of Short‐Chain Perfluoroalkyl Substances by Cavity‐Directed Aggregation in a Molecular Cage Host
ABSTRACT The removal of perfluoroalkyl substances (PFAS) from water is critical to protect human health and the environment. However, removing short‐chain PFAS r...
Remote Positioning of Cations Tunes Catalytic Fe‐Mediated Nitrogen Fixation Selectivity for Hydrazine Instead of Ammonia in Protic Media
ABSTRACT Understanding the basis of product selectivity is a central issue in catalyst design. Catalytic nitrogen reduction (N 2...
Imidazolium Cation‐Stabilized Interfacial Chemistry for Durable Aqueous Cadmium‐Iodine Batteries
ABSTRACT Aqueous metal batteries are attractive candidates for large‐scale energy storage owing to their intrinsic safety and low cost. However, their practical...
<i>p</i> ‐Benzoyl‐ <scp>l</scp> ‐phenylalanine as a Multifunctional Noncanonical Amino Acid in Synthetic Biology: Photoprobing, Photocatalysis, and Structural Programming for Biocontainment
ABSTRACT p ‐Benzoyl‐ l ‐phenylalanine (pBzF) is a widely used noncanonical amino acid (ncAA) that exp...
Quasi‐One‐Dimensional Perovskite Single Crystals Enabling Decoupled Ionic–Electronic Transport for Sensitive and Stable X‐ray Detection
ABSTRACT Metal halide perovskites are promising candidates for low‐cost and sensitive x‐ray detection. However, the existing perovskite materials with diverse co...
Photoswitch Mediated Electron Highway Driving Direct Pollutant‐to‐Oxidant Electron Transfer in Ultrafast Fenton‐Like Reactions
ABSTRACT Traditional heterogeneous photocatalytic systems coupled with oxidant activation hold great promise for environmental remediation but are constrained by...
First Principles Identification of Active Sites in Heterogeneous Catalysis: A Case Study on Zn <sub>x</sub> Cr <sub>y</sub> O <sub>z</sub> for Syngas Conversion
ABSTRACT Discovering next‐generation heterogeneous catalysts calls for embracing the full complexity of active site formation under realistic conditions. Here, w...
Correlating Structure Change With Magnetic Ordering and Spin Fluctuation During Delithiation of Transition Metal Layered Oxide
ABSTRACT Current Li‐ion battery technology relies on Li + insertion/extraction coupled with electron gaining/loss at both...
Supramolecular Nanoconfinement‐Accelerated Synthesis of Two‐Dimensional Styrenic Polymers Boosting Proton Conductivity in Nafion‐doped Membranes
ABSTRACT Two‐dimensional (2D) covalent polymers offer environmental stability, surface area, and mechanical resilience, but preparation of functional, freestandi...
Hydrogen‐Bond Network‐Directed Controllable Assembly of Stable Cyanine J‐Aggregates for Long‐Term and High‐Contrast In Vivo Imaging
ABSTRACT Optical probes based on near‐infrared region (NIR) small‐molecule dyes have emerged as an indispensable tool for contemporary in vivo biomedical researc...
Fluorinated Glycan Frameshifts: Automated Synthesis Expedites the Study of Glycan‐Protein Interactions by <sup>19</sup> F‐BioNMR
ABSTRACT Given the prominence of 19 F‐bioNMR in structural research, fluorinated glycan frameshifts hold enormous potenti...
Terminal Cyanate in Stabilizing Mononuclear Cu(III) Complex: Room Temperature Preparation, Characterization, and Reactivity
ABSTRACT Great efforts have been made to generate new types of late transition metal oxidants by tuning terminal ligands. These metal oxidants play a key role to...
Confined Cu <sub>111</sub> Nanolaminates as a Single‐Phase Nanoreactor for Efficient Urea Electrosynthesis
ABSTRACT Modern electrocatalysis typically involves multi‐species cascade systems, imposing stringent requirements on catalysts to exhibit multi‐component and mu...
Dynamic Spin Governing Asymmetric Coordination Fields in Trimetallic Single‐Atom Catalysts for Optimal Oxygen Reduction
Abstract Single‐atom catalysts demonstrate theoretically superior oxygen reduction reaction (ORR) kinetics, the limited dynamic adaptability, however, poses a gi...
Protective Shield for Interfacial Cu <sup>+</sup> /Cu <sup>0</sup> Sites Enhances Multicarbon Production Toward Electrochemical Reduction of Carbon Dioxide
ABSTRACT The interface of Cu + /Cu 0 is a promising active site for multi‐carbon...
Distance‐Dependent Energy Transfer Between Organic Fluorophores and Single‐Walled Carbon Nanotubes
ABSTRACT Single‐walled carbon nanotubes (SWCNTs) are promising optical biosensing platforms due to their intrinsic near‐infrared fluorescence and environmental s...
Expeditious Synthesis of 2‐Deoxy‐2‐perfluoroalkyl Glycosides
ABSTRACT In carbohydrate‐based drug discovery, fluorine‐containing substituents are widely used to enhance pharmacodynamic and pharmacokinetic profiles. However,...
Near‐Infrared Photothermal Polymerization of Thioctic Acid Triggered by Polyoxometalate Crosslinker
ABSTRACT The monomer conversion rate of thioctic acid (TA) and the cross‐linking degree of polymer chains significantly influence the performance of materials, making them important...
Spatial Mapping of Membrane Protein Interactions Using a DNA Origami Rubbing
Abstract Revealing the protein–protein interactions (PPIs) of membrane proteins is as challenging as their structural reconstruction, primarily because the molecular structures and r...