Angewandte Chemie International Edition
Articles in this Issue
Logic‐Responsive Superspherical Nucleic Acid Enables Tumor‐Specific Multiplexed Gene Silencing for Efficient Cancer Therapy
ABSTRACT Gene‐targeted therapies are of considerable interest for targeting multiple “undruggable” oncogenes. However, their therapeutic efficacy is largely hamp...
Dual Thermal Stabilization Toward Highly Safe and Durable All‐Solid‐State Lithium Metal Batteries Based on Sulfide Electrolytes
ABSTRACT The practical deployment of all‐solid‐state lithium (Li) metal batteries (ASSLMBs) based on sulfide electrolytes is constrained by the thermal–electroch...
Catalytic Sulfur‐Atom Transfer Enabled by a Bis(disulfide) Titanium Complex
ABSTRACT Multi‐electron processes are key steps in the activation and valorization of small molecules. Due to titanium's electropositivity and the limited access...
Remapping the Synthetic Landscape of α‐Tertiary Alkylamines via Dual‐Functional Catechol
ABSTRACT α‐Tertiary alkylamines are privileged motifs with a strong propensity to be bioactive, rendering their efficient synthesis fundamentally important acros...
Bioinspired Total Synthesis of Myltayloriones A‐B and Mylnudones A–D
ABSTRACT Herein, we report the first asymmetric synthesis of the dimeric sesquiterpenoid myltayloriones A and B. The synthesis features a stereodivergent Echavar...
Engineering Pt/Ionomer Interface via Strengthening Hydrogen‐Bond Network for High‐Performance Low‐Pt Fuel Cells
ABSTRACT A critical challenge in proton‐exchange membrane fuel cells (PEMFCs) is the severely limited catalyst utilization at conventional Pt/perfluorosulfonic a...
Porous Organic Cage Liquid Stabilizes Pd Nanoclusters for Ambient H <sub>2</sub> Capture and Alkyne Semihydrogenation
ABSTRACT The design and synthesis of novel supports for stabilizing highly active ultrafine metal nanoparticles (MNPs) is critically important across diverse sci...
Design of Isomeric Covalent Organic Frameworks for Realizing Low‐Temperature Sodium Storage
ABSTRACT High‐performance low‐temperature sodium‐ion batteries (SIBs) are essential for energy storage in extreme environments, which, however, is severely hinde...
Desulfurative Deuteration of (Hetero)Aryl Sulfides With D <sub>2</sub> O by Nickel Catalysis
ABSTRACT Selective deuteration of (hetero)aryl rings is of great significance and interest, yet it has remained a challenge, especially when employing D...
Jahn–Teller Effect Dominates the Left‐Hand Rule: Magneto‐Optics in Metal Halide Lattice
ABSTRACT Symmetry operation during molecular packing in the crystalline phase determines diverse unique features. Inducing asymmetry in hybrid inorganic–organic...
Correction to “Activate 1‐TM Channel of Disordered Rock Salts via Electrostatic Repulsion Regulation for Enhanced Lithium Storage”
Selective Oxidation From Toluene to Benzaldehyde via 4 <i>f‐</i> Orbital Involvement
ABSTRACT Selective oxidation has been greatly challenging for the benzylic C─H bond from toluene to benzaldehyde. In this study, Sm 3+...
Crystal‐Field‐Weakening Engineering Unlocks Ultra‐Efficient Eu <sup>2+</sup> Near‐Infrared Emission for Emerging Spectroscopic Applications
ABSTRACT Eu 2+ ion has emerged as a promising blue‐light‐excitable near‐infrared (NIR) emitter owing to its parity‐allowe...
Well‐Defined RhO <sub>4</sub> Species Confined in Self‐Pillared Pentasil Zeolite as Efficient Nano Reactors for Hydroformylation of Higher Olefins
ABSTRACT Heterogeneous catalytic hydroformylation of higher olefins often suffers from substrate diffusion limitations and unclear active species. We overcame bo...
Recyclable Pt‐Catalyzed Biphase Hydrosilylation on Water: From Functionalized Monomers to Polymer Materials
ABSTRACT Ways to resolve the main challenges of the important industrial hydrosilylation process are proposed. Recyclable biphasic...
Deep Eutectic Solvent Matrix for Hybrid Indium Chloride Glasses With Tunable Luminescence
ABSTRACT Hybrid metal halide (HMH) glasses are emerging as superior photonic candidates, yet their development is fundamentally hindered by the high crystallizat...
Speciation‐Controlled C–F Bond Functionalization Enabled by Zwitterionic Pnictinidenes
ABSTRACT Low‐valent pnictogen systems have recently emerged as redox catalysts for C–F activation. However, catalytic turnover has remained largely restricted to hydrodefluorination...
Homonuclear Dual‐Atom Cobalt Sites for Enhanced Selective Hydrogenation
ABSTRACT Single‐atom catalysts based on non‐noble metals have demonstrated remarkable selectivity in selective hydrogenation. However, their electron‐deficient m...
Supramolecular Cage‐Based Heterojunction: Chloroplast Mimicked Artificial Photosynthesis for Efficient Ethanol Production
ABSTRACT Photosynthesis of C 2+ products like ethanol through artificial photosynthetic overall reaction is much desired...
Activation of Allylic Primary Alcohols With Biaryl Oxazepine Reagent for Chiral Phosphoric Acid‐Catalyzed Asymmetric S <sub>N</sub> 1 Reaction
ABSTRACT Carbocations have long been important reactive intermediates in organic synthesis. Nevertheless, their inherent instability and high reactivity present...
Thermally Activated “Cold” Holes Overcome Recombination Limits in Single‐Component Organic Solar Cells With 15.6% Efficiency
ABSTRACT Single‐component organic solar cells (SCOSCs) based on double‐cable conjugated polymers offer unparalleled morphological stability compared to bulk‐heterojunction systems, b...
Bio‐Inspired Zymogen‐Activation Strategy for On‐Demand and Bilateral Interphase Formation in Aqueous Zinc‐Ion Batteries
ABSTRACT Aqueous zinc‐ion batteries (AZIBs) possess distinct benefits in cost and safety, but bilateral interfacial failures on Zn anodes and MnO...
Beyond Self‐Assembled Molecules: Hydrogen‐Bonding‐Regulated Crystallization of Wide‐Bandgap Perovskite for High‐Performance Perovskite‐Silicon Tandem Photovoltaics
ABSTRACT Wide‐bandgap (WBG) perovskites crystallization is essential for high‐efficiency perovskite–silicon tandem solar cells (TSCs), yet their fabrication on s...
Machine‐Learning‐Guided Discovery of Boron‐Free Narrowband Blue Thermally Activated Delayed Fluorescence Emitters
ABSTRACT Thermally activated delayed fluorescence (TADF) emitters enable color‐pure, energy‐efficient organic light‐emitting diodes (OLEDs), yet many ultra‐narro...
Nickel‐Catalyzed Asymmetric Hydrophosphinamidation of Alkynes
ABSTRACT P ‐stereogenic phosphinamidates are highly pivotal structural motifs in drug discovery and the design of chiral ligands. Despite the...