Angewandte Chemie International Edition
Articles in this Issue
Biocatalytic Access to Natural Mosquito Repellent <i>p</i> ‐Menthane‐3,8‐diol via Direct Asymmetric Prins Cyclohydration
ABSTRACT Vector‐borne diseases pose a rising global health challenge, necessitating the development of safe and effective pest protection agents. Here, we report...
Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals
ABSTRACT Glycals are unsaturated sugar derivatives constituting a large family of polyhydroxylated synthons which are widely exploited as synthetic intermediates...
Correction to “Toward Ultra‐High‐Quality‐Factor Wireless Masing Magnetic Resonance Sensing”
BNB/NBN‐Phenalenyl‐2'‐deoxyuridines as a Fluorophore–Quencher Pair in DNA
ABSTRACT Deoxyribonucleic acid (DNA) enables the precise arrangement and positioning of chromophores in order to study their interactions, leading, for example, to through‐space ener...
Chemical Metabolomics: Chemical Biology Tools for Advanced Metabolism Investigations
ABSTRACT Human metabolism has been investigated to understand disease onset for the discovery of new selective pharmaceuticals and the development of diagnostics for early disease de...
Conformational Landscapes in the Ground and Excited States Dictate Circularly Polarized Excimer Emission: A Thermodynamic–Kinetic Interplay in Carbazole Dimer Systems
ABSTRACT We demonstrate that in chiral carbazole dimers, the tt conformer generates intense excimer CPL, while...
The Power of Pnictogen Bond: As─As Linkages Drive Wide Bandgap, Strong NLO Response and Large Birefringence in SrGa <sub>3</sub> Si <sub>4</sub> As <sub>11</sub>
ABSTRACT Arsenides represent an advantageous platform for designing long‐wavelength infrared (IR) nonlinear optical (NLO) materials; however, the intrinsic narro...
Enantioselective Synthesis of Inherently Chiral Tetraphenylene Analogues Enabled by NHC‐Catalyzed Benzoin Condensation
ABSTRACT Herein, we report an enantioselective N‐heterocyclic carbene (NHC)‐catalyzed intramolecular benzoin reaction of bisaldehydes featuring a 1,1′:2′,1′′‐terphenyl linkage to aff...
Light‐Induced Dispersion of Pd Single Atoms Provides Steady‐State‐Stabilized Activity for Photocatalytic H <sub>2</sub> Generation
ABSTRACT In recent years, the use of single atoms (SAs) has become increasingly significant in photocatalysis. Particularly, SA noble metals of Pt and Pd can act...
Integrated CO <sub>2</sub> Capture and Conversion Induced by Amines for Effective Electrocatalytic N‐Methylation
ABSTRACT N‐Methylation of amines is a crucial transformation for synthesizing valuable compounds. However, conventional N‐methylation methods often rely on hazar...
Reductive Photocatalysis Unlocks the Hydrodeoxygenation of Polycarbonate Plastic Into Fuel‐Range Hydrocarbons
ABSTRACT Polycarbonate (PC) is among the most challenging plastics to recycle because its robust aromatic C─O linkages resist conventional depolymerization strat...
Homoleptic and Heteroleptic Borylones L1‐B(Ph)‐L2
ABSTRACT Quantum chemical calculation using density functional theory at the BP86‐D3(BJ)/def2‐TZVPP level and ab initio theory at the CCSD(T)/def2‐TZVPP level ha...
A Trade‐Off Between Thermodynamics and Kinetics of O <sub>2</sub> Binding for Highly Active and Selective Electrocatalytic Oxygen Reduction Reaction
ABSTRACT O 2 binding to metal ions is an essential step in the oxygen reduction reaction (ORR). Tailoring O...
Interfused Graphene Fiber Membranes Enable Volumetric Electron‐Transfer Advanced Oxidation via Interlayer Site Activation
ABSTRACT Electron‐transfer‐involved persulfate‐based advanced oxidation processes (ET‐AOPs) are attractive for wastewater treatment because of their high selectivity and environmenta...
Enhancing Superlubricity and Wear Resistance in Mechanically Robust Hydrogel via Microliter‐Scale Subsurface‐Initiated Polymer Brush Grafting
ABSTRACT Hydrogels represent an ideal for articular cartilage replacement, with hydrogel‐polymer brush layered composites emerging as a promising strategy to simultaneously achieve u...
Bio‐Propelled Stomatocyte Nanomotors with Glutathione‐Responsiveness for Osteoarthritis Treatment
ABSTRACT Pharmacological intervention is a primary therapeutic strategy for Osteoarthritis (OA), however, improving the bioavailability of therapeutic agents rem...
Tailoring Hybrid Copper Iodide Cluster Glasses via Ligand Design for Stable Multifunctional X‐Ray Imaging
ABSTRACT The development of glassy organic–inorganic hybrid material has attracted great interest, yet remains significantly challenging due to issues such as un...
Oxygen Vacancy‐Driven Dual‐Site Pd‐TiO <sub>2</sub> Sonocatalyst for Amplified Reactive Oxygen Species Generation and Sonocatalytic Therapy
ABSTRACT Ultrasound (US)‐triggered reactive oxygen species (ROS) generation by nano‐sonocatalysts is vital for sonocatalytic therapy. However, the therapeutic ef...
A High‐Metal‐Content 2D Conjugated Metal‐Organic Framework With a Bis‐Salphen Architecture for Dendrite‐Free Sodium Metal Anodes
ABSTRACT Two‐dimensional conjugated metal‐organic frameworks (2D c ‐MOFs) are promising candidates for electrochemical ap...
Radical Cascade Combining Cross‐Olefin Coupling with the Smiles‐Truce Rearrangement
ABSTRACT Radical cascade reactions enable the swift and efficient assembly of complex molecular architectures. These transformations are especially valuable when...
A Bifunctional Descriptor Inspired by Electron‐Donating Ability for Regulating Dendrite Growth and Parasitic Reactions in Zinc‐Ion Batteries
ABSTRACT Aqueous zinc‐ion batteries (AZIBs) are promising alternatives to lithium‐based systems but are limited by dendritic growth and parasitic reactions at th...
Concerted Proton and Electron Transfer in Heterogeneous Electrocatalytic CO <sub>2</sub> Reduction
ABSTRACT Understanding how protons influence heterogeneous electrocatalytic CO 2 reduction on electrode surfaces is criti...
Flexible Organic Radical Cocrystal With 94% Photothermal Conversion Efficiency
ABSTRACT Flexible photothermal materials made of particulate carbon, metal, polymer, or semiconductors often suffer from interfacial incompatibility, leading to...
Interfacial Charge‐Regulated Microenvironments Enabled by Ionic Organic Cages for Boosting Electrocatalytic Nitrate Reduction to Ammonia
ABSTRACT Ammonia (NH 3 ) is essential for agriculture and industry, yet the Haber–Bosch process is energy‐intensive and c...
Harnessing Antiaromatic Perturbation in Multiple‑Resonance TADF Emitter for Simultaneous Bathochromic Shift and Spectral Narrowing
ABSTRACT Narrowband multiple‐resonance thermally activated delayed fluorescence (MR‐TADF) emitters are pivotal for wide‐color‐gamut displays, yet they often enco...