Angewandte Chemie International Edition
Articles in this Issue
Outside Front Cover: Molecular Engineering of a Rigid Tetradentate Pt(II) Emitter for High‐Performance OLEDs Realizing the BT.2020 Blue Gamut (Angew. Chem. Int. Ed. 44/2025)
Best‐Practice Reporting for Porous Materials Adsorption Data
Abstract Recent decades have seen an enormous evolution of novel porous materials for catalysis, energy efficient processes, and sustainable technologies to improve life quality. Ads...
Tailor‐Made Host–Guest Organic–Inorganic Hybrid Antimony Halide Enables Efficient Light‐Emitting Diodes
Abstract Organic–inorganic antimony (Sb) halides are garnering increasing interest for lead‐free perovskite light‐emitting diodes (LEDs), but the non‐radiative r...
KF·[SO <sub>2</sub> (NH <sub>2</sub> ) <sub>2</sub> ]: the First Deep‐Ultraviolet Transparent Sulfonamide Fluoride Nonlinear Optical Crystal with Novel Cairo Pentagonal Structure
Abstract The sulfonamide group (SO 2 (NH 2 ) 2...
Dynamic Gas‐Bridged Chemistry: Breaking Down the Barriers in Building Functional Materials with Gas Molecules
Abstract Greenhouse gases like carbon dioxide (CO 2 ), alongside other pollutant gases, pose a significant ecological thr...
Acyclic Tripodal Receptors as Ultrahigh Superprotonic Conductors
Abstract Solid‐state proton‐conductors (SSPCs) with high conductivity and excellent chemical stability are the key requirements for proton exchange membrane fuel...
A Highly Selective Nucleophilic and Radical Relay Difluorination of Cyclopropanes and Alkenes
Abstract Fluoro‐containing organic compounds have been found wide application in pharmaceutical and agrochemical industries and in medical diagnostics. In this f...
Predicting Reaction Feasibility and Selectivity of Aromatic C─H Thianthrenation with a QM–ML Hybrid Approach
Abstract The direct thianthrenation of aromatic C─H bonds is a valuable late‐stage functionalization strategy that can assist, for example, the development of ne...
Chirality‐Induced Split Personality in Polymer with Intrinsic Microporosity‐Based Artificial Ion Channels
Abstract The construction of artificial transmembrane ion channels using polymers has emerged as a promising research avenue in membrane transport. In this study...
Enhanced Bifunctional Catalysis of Iridium Nanoparticles on Nitrogen‐Doped Holey Carbon via Strong Metal–Support Interaction for Rechargeable Zinc–Air Batteries
Abstract Developing efficient and durable catalysts is crucial for the practical application of energy storage and conversion technologies. This work reports the...
Breaking the Linear Scaling Relations for the Oxygen Reduction Reaction with a Dual‐Atom Catalyst Composed of a MnFe‐Porphyrrole Aerogel
Abstract Bimetallic catalysts offer enhanced catalytic performance through synergistic interactions between the two metals, allowing them to break the linear sca...
Atomically Dispersed Rare Earth‐Confined High‐Entropy Alloy Nanocrystals for Efficient Ammonia Electrosynthesis
Abstract Rare earth (RE) elements with unique lanthanide contraction and electron configuration are promising for many important studies. Alloying RE with typical 3d/5d transition me...
Na <sub>2</sub> Fe <sub>3</sub> (SO <sub>4</sub> ) <sub>4</sub> : A Zero‐Strain Sustainable Positive Electrode Material for Na‐Ion Batteries
Abstract One of the challenges in the energy transition is minimization of the battery cost for energy grid storage. Na‐ion batteries are a promising alternative...
Multidentate Macrocyclic Salphen‐Based 2D Conjugated Metal–Organic Framework
Abstract Two‐dimensional conjugated metal–organic frameworks (2D c ‐MOFs) represent an emerging class of crystalline poro...
Impact of Glycoclustering on Stiffening of MUC5AC Peptides Revealed by High‐Efficiency Synthesis
Abstract Clustered O‐glycosylation of long tandem repeat regions is the hallmark of secreted mucins such as MUC5AC. Glycosylation is thought to play a key role in rigidifying the pep...
Molecular Weight Control in Frontal Ring‐Opening Metathesis Polymerization
Abstract In this study, we push the limits of bulk frontal ring‐opening metathesis polymerization (FROMP) to control polymer molecular weight and dispersity with...
Tunable Copolymerization of Oxetane and Anhydrides via a Nonsymmetric Three‐Center Four‐Electron Iodine Activation Mode
Abstract The copolymerization of low‐strain cyclic ethers, such as oxetane and anhydrides, still presents opportunities for improving compositional control in po...
Can Charge Transfer Across C─H⋅⋅⋅O Hydrogen Bonds Stabilize Oil Droplets in Water?
Abstract Oil–water emulsions resist aggregation due to the presence of negative charges at their surface that leads to mutual repulsion between droplets, but the molecular origin of...
Polymeric Diaminophenazine with Spiral Architecture as Cathode Materials for Ultra‐Stable Aqueous Zinc‐Organic Batteries
Abstract Pyrazine‐based organic electrode materials hold great promise for applications in aqueous zinc‐ion batteries (AZIBs), while developing cost‐effective or...
Reversible Mechanical Interlocking via Stimuli‐Triggered Nonhomeomorphic Topology Transformation Enables Highly Efficient Rotaxane Synthesis
Abstract Rotaxanes, as one of the most fundamental mechanically interlocked molecules (MIMs) , have attracted considerabl...
Self‐Assembled Nanoconjugates with Aggregation‐Induced Emission for Near‐Infrared II Imaging and Transcytosis‐Driven Cancer Therapy
Abstract Nanomedicine holds immense potential to revolutionize cancer therapy, yet its clinical translation remains hampered by insufficient tumor accumulation a...
Ultrasmall Chemogenetic Tags with Group‐Transfer Ligands
Abstract Chemogenetic tags facilitate exploration of activities of a protein‐of‐interest (POI) that lacks small‐molecule ligands; however, most tags are too larg...
Persistent Membrane‐Anchored Oligomeric Peptides with Nanopore Formation for Targeted Immune Modulation
Abstract In the field of targeted diagnosis and therapy, one of the key challenges is the off‐target effect of these recognition molecules. Herein, a new class of oligomeric helical...
Stereoselective Synthesis of Cyclic P(V) Compounds via Stereoconvergent Nucleophilic Substitution
Abstract We report a simple, scalable, and stereoselective synthesis of chiral oxazaphosphoramides using phosphoryl chloride, an L‐serine derivative, and various primary and secondar...
Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes
Abstract We present a study of the ability of our recently reported well‐defined crown ether‐coordinated alkali metal phosphides...