Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

Abstract

ABSTRACT The reversible molecular motions of mechanically interlocked molecules (MIMs) have played a crucial role in realizing stimuli‐responsive functions. While the reversible switching of circularly polarized luminescence (CPL) properties has been achieved using MIMs through pH change and/or addition of chemicals, the mechanically controlled CPL utilizing the interlocked architecture has not yet been demonstrated. Here, we introduce a rotaxane‐based mechanophore designed for force‐induced CPL on/off switching. The mechanophore consists of a ring featuring a CPL‐active helicene luminophore and an axle with a matching quencher. The rotaxane mechanophores covalently introduced at the cross‐linking points of a double‐network (DN) gel are reversibly activated and deactivated in response to changes in applied force transduced through the polymer chains during the macroscopic swelling and shrinking of the DN gel. The isotropic swelling of the DN gel effectively suppresses artifacts arising from macroscopic sample orientation, enabling accurate detection of reciprocal CPL derived from a single chiral emitter. This work establishes the first example of mechanical control of CPL at the single‐molecule level and provides a robust measurement methodology for force‐induced CPL switching in soft materials.