Angewandte Chemie International Edition
Articles in this Issue
Catalytic Enantioselective Reductive Arylation and Alkenylation of Sulfinylamines to Access Sulfinamides Enabled by Cobalt Catalysis
Abstract This study reports a cobalt‐catalyzed method for the enantioselective reductive arylation and alkenylation of sulfinylamines, facilitating the efficient synthesis of enantio...
Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste
Abstract Developing highly efficient and selective catalysts for chemical recycling and upcycling of plastic waste is essential for establishing a sustainable pl...
Cooperative Iron–Aluminium Reactivity for Dinitrogen Activation
Abstract We report a novel bimetallic approach utilizing cooperative Fe─Al reactivity for N 2 activation on the Cp*Fe(1,2...
Correction to “Iridium(III) Blue Phosphors with Heteroleptic Carbene Cyclometalates: Isomerization, Emission Tuning, and OLED Fabrications”
Bio‐Sourced 4‐Aryl‐1,2‐Dithiolanes for Recyclable Poly(disulfide)s with High Performance
Abstract The development of recyclable polymers presents a solution to the urgent issues of circular plastics economy. To this end, there is an increasing interest in expanding the u...
Bismuth Meets Olefins: Ethylene Activation and Reversible Alkene Insertion into Bi─N Bonds
Abstract Owing to its fundamental properties as the parent olefin, its outstanding industrial relevance, and the challenges associated with its activation, ethylene remains a benchma...
A Single‐Molecule Liposome Assay for Membrane Permeabilization
Abstract Cell membrane disruption is associated with numerous diseases and underlies the activity of various antimicrobial agents. The rapid screening of compounds capable of disrupt...
Front Cover: Decoding Double Layer Dynamics for CO <sub>2</sub> Electroreduction over Cu (Angew. Chem. Int. Ed. 26/2025)
Functional SELEX and Biomedical Applications of Aptamers: Beyond Molecular Recognition
Abstract Aptamers, developed through SELEX (systematic evolution of ligands by exponential enrichment), are generally short oligonucleotide molecules with remarkable specificity and...
Unveiling an In Situ H <sub>2</sub> O <sub>2</sub> Production: Rechargeable Zinc‐H <sub>2</sub> O <sub>2</sub> Battery Powering 26 LEDs
Abstract Looking toward ever‐growing energy demand, the advancement in energy storage devices and carrying out electrocatalytic reactions in an efficient way is...
Ruthenium Catalyzed <i>Ortho</i> ‐Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts
Abstract Arylthianthrenium salts have become key intermediates for late‐stage functionalizations of drug‐like molecules. Ruthenium‐phosphine catalysts are now sh...
Structures of Polyhydroxyalkanoate Synthase PhaC from <i>Aeromonas caviae</i> , Producing Biodegradable Plastics
Abstract Polyhydroxyalkanoate (PHA) is a biodegradable polyester that can serve as a promising alternative to petrochemical plastics, which present a serious sou...
Influence of Ligand Design and Non‐Covalent Interactions on the Isoselective Ring‐Opening Polymerization of <i>rac</i> ‐β‐Butyrolactone Using Salan and Salalen Rare‐Earth Metal Catalysts
Abstract We herein report the influence of the ligand framework on the isoselective ring‐opening polymerization (ROP) of rac...
The Mechanism of Ruthenium‐Catalyzed Directed C─H Arylation of Arenes: The Key Role of Bis‐Cyclometalated Intermediates
Abstract The mechanism of Ru‐catalyzed N ‐directed C‐H ortho ‐arylation with halo...
Concise Enantioselective Total Syntheses of Rearranged <i>ent</i> ‐Trachylobane Diterpenoids (–)‐Wallichanols A and B
Abstract Herein, we report the first enantioselective total syntheses of three rearranged ent ‐trachylobane diterpenoids,...
Efficient Ammonia Electrosynthesis from Pure Nitrate Reduction via Tuning Bimetallic Sites in Redox‐Active Covalent Organic Frameworks
Abstract Electrocatalytic nitrate reduction reaction (NITRR) represents a promising approach for ammonia synthesis, but existing application has been constrained...
Frontispiece: A Sustainable and Scalable Approach for In Situ Induction of Gradient Nucleation Sites in Biomass‐Derived Interface Layers for Ultra‐Stable Aqueous Zinc Metal Batteries
Cyclization Polymerization of Elemental Sulfur and Diisocyanate: New Polymerization Toward High‐Performance Polymer
Abstract The development of polymer materials heavily relies on new polymerization reactions. Herein, we report the discovery of cyclization polymerization of el...
Frontispiece: Surface Chemistry of WC Powder Electrocatalysts Probed In Situ with NAP‐XPS
To Make a Painstaking Investigation: Revealing the Electrochemical Reactions in Aqueous Zn─Mn Batteries
Abstract The rechargeable aqueous Zn||MnO 2 batteries have been extensively explored, but the electrochemical reaction me...
Fused Dual‐Donor Design for Accelerating Reverse Intersystem Crossing Rates of Spatially Folded Through‐Space Charge Transfer Emitters
Abstract The development of through‐space charge transfer (TSCT)‐thermally activated delayed fluorescence (TADF) material is defective in relatively low reverse...
Supramolecular Recognition of a DNA Four‐Way Junction by an M <sub>2</sub> L <sub>4</sub> Metallo‐Cage, Inspired by a Simulation‐Guided Design Approach
Abstract DNA four‐way junctions (4WJs) play an important biological role in DNA repair and recombination, and viral regulation, and are attractive therapeutic ta...
In Situ Cation Exchange Enables Air‐Processed Inverted Perovskite Solar Cells with over 25% Efficiency and Enhanced Stability
Abstract The scalable fabrication of inverted perovskite solar cells (IPSCs) in humid air with an antisolvent‐free process is essential for future industrial app...
Tuning Multi‐Active Sites in Cu Catalyst via Ag/Ni Doping for Enhanced CO <sub>2</sub> Electroreduction to C <sub>2+</sub> Products
Abstract Electrochemical CO 2 reduction (ECR) to C 2+ products is a promising sus...
Photocatalytic Nitrogen Reduction for Ammonia Synthesis Accelerated by Overcoming Photo‐Dember Effect
Abstract During photocatalytic nitrogen fixation for ammonia synthesis, the photo‐Dember effect causes direct transmission of photogenerated electrons from the i...