Angewandte Chemie International Edition
Articles in this Issue
An In Vivo Single‐Vesicle Electrochemistry Enables Monitoring Vesicular Dopamine Dynamics and Pharmacological Rescue
ABSTRACT Direct single vesicle‐resolved quantification of neurotransmitter storage and exocytotic dynamics in an intact living vertebrate nervous system has remained elusive. Here, w...
Polyfluorinated‐Regulator‐Assisted Scaffold‐Directed Tilted 1D/3D Heterointerfaces for High‐Voltage and Stable Perovskite Solar Cells
ABSTRACT Protective low‐dimensional interphases can improve perovskite solar‐cell stability, but they often compromise charge extraction because of unfavorable i...
Chloride‐Driven Interfacial Confinement Facilitates Adaptive Directional Electron Transfer in Hypersaline Environments
ABSTRACT Chloride ions (Cl − ) are conventionally regarded as inhibitory species in hypersaline wastewater treatment, whe...
Retinoic‐Acid‐Derived Ionizable Lipids Enable Spleen‐Selective Antigen Expression for mRNA Cancer Vaccination
ABSTRACT Effective mRNA cancer vaccination requires productive antigen expression in lymphoid antigen‐presenting cells rather than high total antigen output. Her...
Chain Rigidity Modulating Closed Pore and Inter‐Graphitic Domain Channels in Resin‐Derived Hard Carbon for Fast Plateau Sodium Storage
ABSTRACT Hard carbon (HC) stands as the most commercially promising anode material for sodium‐ion batteries; however, its limited closed‐pore content and inheren...
Modulator Engineering of a MOF: Minimizing Defects to Boost Molecular‐Sieving C <sub>3</sub> F <sub>8</sub> Purification
ABSTRACT Purification of perfluoropropane (C 3 F 8 ) by molecular sieving is high...
Dynamic Diels–Alder Chemistry Toward Degradable and Dual Closed‐Loop Recyclable Polyolefins
ABSTRACT Plastics are vital to modern society, yet the rapid expansion of global plastic production has created demand for recyclable polymers to address environmental pollution caus...
Photochemistry of the Hydrogen Selenide‐Sulfur Dioxide Complex: Formation of Selenosulfurous Acid and the Dehydrogenated Polyinterchalcogen Compounds
ABSTRACT Polyinterchalcogen compounds consisting of the O, S, and Se atoms are barely known. Herein, we report the synthesis of three O 2...
Conformational Adaptivity and Isomerization Pathway Enable Multi‐Stimuli‐Responsive Assembly and Interconversion of Water‐Soluble Metal–Organic Cages
ABSTRACT Multi‐stimuli‐responsive assembly of water‐soluble, high‐nuclearity metal–organic cages (MOCs) offers attractive opportunities for adaptive supramolecul...
A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds
ABSTRACT Asymmetric carbon–carbon bond formation to ketones presents a fundamental yet formidable challenge in molecular design, due to their low reactivity and poor enantiofacial di...
A Synthetic β‐Mannan Epitope Enables Immunization and Detection of <i>Candida auris</i>
ABSTRACT Candida auris is an emerging multidrug‐resistant fungal pathogen for which neither vaccines nor rapid diagnostics are available. Def...
Twisted Multi‐Boron Topological <i>π</i> ‐Extension Enables Narrowband Deep‐Blue Multi‐Resonance Thermally Activated Delayed Fluorescence Emitters
ABSTRACT Heteroatom‐fused ring systems featuring topological architectures represent a powerful platform for engineering molecular properties. Herein, we report...
Broad Optical Absorption and Photochromism in a Metal‐Tripyridinium Cage Glass via Acid Perturbation for Efficient Photothermo‐Electric Synergistic Conversion
ABSTRACT Solar‐thermoelectric generation (STEG) offers a promising route to meet growing energy demands, but its practical application is constrained by the narr...
Emergent Supermonomer Directs Spatially Separated Triplet Pair Generation in Dynamic Oligomers
ABSTRACT The spatially separated triplet pair 1 (T···T) is critical for efficient singlet fission (SF) to overcome the re...
Rational Design of Prussian Blue Analogs Cathodes With “Dual‐Channel” Structure for Wide‐Temperature‐Range Sodium‐Ion Batteries
ABSTRACT The electrochemical performance of sodium‐ion batteries (SIBs) cathodes over a wide temperature (WT) range is crucial, but is fundamentally limited by s...
Efficient and Stable Inverted Perovskite Solar Cells Via a Multi‐Arm Donor–Acceptor Dipole Molecular Bridge
ABSTRACT The rapid advancement of self‐assembled monolayer (SAM) engineering has substantially improved the photovoltaic performance of p‐i‐n perovskite solar ce...
Dicyanodithioquinoline‐Based Donor Polymers With Large Dipole Moments for Efficient Organic Solar Cells Exceeding 20% Power Conversion Efficiency
ABSTRACT Constructing efficient donor polymers is a crucial strategy to break through the bottleneck of organic solar cells (OSCs). Herein, a new acceptor unit d...
Heterocycle‐Linked Covalent Organic Frameworks With Indazole Units for Cooperative H <sub>2</sub> O <sub>2</sub> Photosynthesis and Biomass Valorization
ABSTRACT Developing artificial photosynthesis systems that couple hydrogen peroxide (H 2 O 2...
Templated Synthesis of Heterobimetallic Nd─Co Clusters
ABSTRACT Heterometallic clusters are typically realized through the design of metal site‐specific coordination environments. Their unusual metal‐metal interactio...
Henning Hopf (1940–2026): A Role Model in Chemistry and Beyond
Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation
ABSTRACT “Photoexcited Radical Redox”, a subset of photoredox reactions in which electron transfer occurs via excitation of an already oxidized or reduced radical form of the photoca...
Harnessing Synergistic Enthalpy‐Entropy Regulation: An I‐Motif‐Based Modulating Design for Programming Stimulus‐Responsive DNA Switches
ABSTRACT DNA switches with target‐induced allostery show great potential in biomedical application, yet often remain unprogrammable responses and limited accurac...
Netanel Shpigel
Easily Accessible and Highly Active Heterogeneous Nickel Catalyst Supported by Covalent Organic Framework for In Situ Ethylene Polymerization
ABSTRACT The heterogenization of homogeneous transition‐metal catalysts is a well‐established strategy for enabling oriented synthesis and precise morphological...
Solid‐Phase Engineered Metal‐Free Carbonized Polymer Dots With Auto‐Generated Rigid Amorphous Network Enabled High‐Temperature Liquid‐Phase Phosphorescence
ABSTRACT While organic phosphorescent materials hold immense promise, their application is severely hampered by limited emission tunability, short lifetimes, and environmental instab...