Angewandte Chemie International Edition
Articles in this Issue
Extending Chain Length of PNP Pincer Ligands Triggers Catalytic Activity of Gold–Copper Nanoclusters in Aerobic Oxidations
ABSTRACT Structural isomerism of organic ligand‐protected atomically precise metal nanoclusters constitutes an ideal model for revealing the structure–activity r...
Downsizing the Histone H3–H4 Quaternary Structure Into Foldamer Mimetics Yields High‐Affinity and Cell‐Permeable Ligands of ASF1
ABSTRACT Mimicking complex protein–protein interfaces with small, well‐defined molecular scaffolds remains a major challenge in chemical biology. Here, we report a foldamer‐based dow...
Step‐Associated Cu‐Ceria Interfaces Enhance Catalytic Activity and Selectivity
ABSTRACT Precise control of metal–support interactions is essential for understanding and steering catalytic processes. Here, we demonstrate that the surface loc...
Gold Clusters With Open‐Shell Ligands: Superatom Mediated Magnetic Interaction
ABSTRACT Understanding the magnetic interactions within gold clusters that involve superatomic orbitals is critically important in advancing the development of n...
Oxophilic Gallium Single‐Atom Regulating Micropore‐Confined Os Atomic Clusters Enables Efficient Alkaline Hydrogen Electrocatalysis
ABSTRACT Rational design of cost‐effective atomic cluster (AC) catalysts with high mass activity and robust durability remains a formidable challenge for alkalin...
A Two‐Dimensional Organic–Inorganic Hybrid Perovskite Ferroelectric for High‐Performance Composite Magnetoelectric and Dual‐Source Energy Harvesting
ABSTRACT Magneto‐mechano‐electric (MME) generators capable of simultaneously harvesting ubiquitous vibrational and magnetic‐field energy are attractive candidate...
Chlorination‐Induced Symmetry Breaking in Cu Single‐Atom Sites for Boosting Electrocatalytic Nitrate Reduction to Ammonia
ABSTRACT Electrochemical nitrate reduction to ammonia is attractive for green fertilizer synthesis and pollution remediation, yet its performance is normally hin...
Pressure‐Treated Luminescent and Structural Evolution With Irreversible Control of Emission in Through‐Space Charge Transfer Emitter
ABSTRACT Through‐space charge transfer (TSCT) is gaining prominence for developing solid‐state luminophores, owing to its tunable and dynamically regulable luminescence. In this work...
Hydrophilic RuGd Alloy Redirecting Interfacial Water Adsorption Configuration for Long‐Term and Ampere‐Level Hydrogen Evolution
ABSTRACT Rapid interfacial water dissociation is pivotal to efficient hydrogen evolution reaction (HER) in anion‐exchange‐membrane water electrolysis (AEMWE), wh...
Chirality‐Induced Selective Electrosynthesis Hydrogen Peroxide and Tandem Green Chemical Synthesis
ABSTRACT Two‐electron oxygen reduction reaction (2e − ‐ORR) toward hydrogen peroxide (H 2...
Donor‐Glycolated Quinoidal Polymers Enable Fast N‐Type Organic Electrochemical Transistors
ABSTRACT Fast, stable n‐type organic mixed ionic‐electronic conductors remain scarce. We report a donor glycolated, quinoidal design that facilitates efficient n...
Short Sb···Sb Contacts in Polymorphic Tris( <i>p‐</i> Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid‐State Chemistry?
ABSTRACT Discovery of a polymorph of tris( p‐ tolyl)antimony(III) reveals solid‐state supramolecular dimers connected thr...
Metal Coordination Dynamics Governs Selective Halogenation in α‐KG/Fe‐Dependent Halogenase SyrB2
ABSTRACT α‐Ketoglutarate (α‐KG)‐dependent nonheme iron enzymes catalyze a diverse array of oxidative transformations essential for natural product biosynthesis....
Uncaging Iridium(III) Complexes for Combined Photodynamic and Photoactivated Chemotherapy
ABSTRACT Inorganic photochemotherapy enables precise spatial and temporal control over anticancer drug activation, offering a promising strategy to reduce system...
Carlos M. Cruz
Macrocycle‐Based Charge‐Transfer Cocrystals: From Host–Guest Recognition to Multifunctional Solid‐State Materials
ABSTRACT Macrocycle‐based charge‐transfer (CT) cocrystals have recently emerged as a distinctive class of adaptive supramolecular solids that bridge molecular recognition and solid‐s...
Anisotropy‐Driven Discovery of Rare‐Earth‐Free Magnets in Mo <sub>2</sub> FeB <sub>2</sub> ‐Type Borides
ABSTRACT Multifunctional materials are critically important for modern technologies. Magnets, especially those relevant to spintronic applications, are essential...
Evolutionary, Functional and Mechanistic Characterisation of Microbial Terpene Synthase‐Like Genes From Springtails
ABSTRACT Despite previous doubts about the origin of terpenes in springtails, a deep bioinformatic analysis of the genomes of 26 springtails surprisingly reveale...
Direct Synthesis of Well‐Defined Epoxide‐Terminated Telechelic Polymers via an Alcohol‐Mediated Self‐Switching Strategy
ABSTRACT The one‐step synthesis of well‐defined telechelic polymers represents a highly attractive approach, providing an efficient alternative to conventional s...
Goutam Ghosh
Moisture‐Responsive Ion‐Coupling Networks in Molecularly Engineered MoS <sub>2</sub> Channels for Enhanced Ion Transport
ABSTRACT Classical nanofluidic ion transport predominantly relies on fixed surface charges for selectivity. However, such static‐charge systems are fundamentally...
Intracellular Delivery of Hydrophilic Glycans Using Superchaotropic Clusters
ABSTRACT The intracellular delivery of glycans is a significant challenge. Glycan delivery is typically achieved by per‐acetylation necessitating the use of the...
Decoupling Ion Transport and Desolvation via Spatially Heterogeneous Solvation Structure for Wide‐Temperature Sodium‐Ion Batteries
ABSTRACT Despite competitive room‐temperature performance, sodium‐ion batteries suffer from sluggish kinetics and unstable interphases at ultralow temperatures....
Dopant‐Tailored Matrices: A Crystal Engineering Strategy for Organic Room‐Temperature Phosphorescent Host–Guest Systems and Beyond
ABSTRACT Host–guest doping of molecular crystals is a powerful strategy to tune optoelectronic properties, yet achieving precise host–dopant compatibility and beneficial synergy with...
Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis
ABSTRACT Real exhaust streams rarely contain a single pollutant: NO x coexists with volatile organic compounds (VOCs) in...