Angewandte Chemie International Edition
Articles in this Issue
Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands
Abstract Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes whi...
Front Cover: Development of Organoautocatalyzed Double s‐Bond C(sp <sup>2</sup> )‐N Transamination Metathesis Reaction (Angew. Chem. Int. Ed. 28/2025)
Noncovalent Synthesis of Topological Heterostructures Using a Site‐Selective Electrostatic Co‐Assembly Strategy
Abstract Heterostructured nanomaterials composed of heterogeneous zones with dramatically different chemical and/or physical properties have attracted significan...
Iridium‐Catalyzed Asymmetric β‐Selective Hydroamination of Enamides for the Synthesis of 1,2‐Diamines
Abstract An iridium‐catalyzed highly enantioselective hydroamination of electron‐rich alkenes has been developed. The coordination assistance of the amide group to the metal center e...
Rhodium/Indium Heterobimetallic Alloy as an Effective Catalyst for Reductive C(sp <sup>3</sup> )─O Silylation of Ethers with Chlorosilanes
Abstract C(sp 3 )─O bonds are ubiquitous in natural and synthetic small molecules as well as polymers. The methodology fo...
Multiple and Alternative Sites Make Tau Protein an Adaptable Sticky Surface for the SH3 Domain of Fyn Kinase
Abstract The interaction between the microtubule associated protein Tau and the tyrosine kinase Fyn is believed to play a pivotal role in the early stage of Alzheimer's disease. Prev...
Cost‐Effective and Low‐Carbon Scalable Recycling of Waste Polyethylene Terephthalate Through Bio‐Based Guaiacol‐Enhanced Methanolysis
Abstract The global plastic waste crisis, particularly from polyethylene terephthalate (PET), demands sustainable recycling solutions. PET methanolysis offers a...
Triple‐Phase Boundaries Enable Selective Urea Production From Simulated Flue Gas in a Zero‐Gap Electrolyzer
Abstract Renewable energy‐powered co‐electrolysis of CO 2 and NO 3 −...
Dinitrogen Activation with Low‐Valent Strontium
Abstract DFT calculations on β‐diketiminate (BDI) complexes with the full series of alkaline‐earth (Ae) metals show that (BDI)AeAe(BDI) complexes of the heavier...
Comparative Study of Solvatomorphs of Stryker's Reagent Using MicroED and Quantum Mechanics
Abstract The atomic position of hydrogen atoms in metal hydrides has been a long‐standing structural question in inorganic chemistry given that hydride delivery is integral to divers...
High‐Performance Cu <sub>6</sub> Sn <sub>5</sub> Alloy Electrocatalysts for Formaldehyde Oxidative Dehydrogenation and Bipolar Hydrogen Production
Abstract Aldehyde‐assisted water electrolysis offers an attractive pathway for energy‐saving bipolar hydrogen production with combined faradaic efficiency (FE) o...
Data‐Driven Review on Aerogels and Polymeric Aerogels
Abstract A thoroughly data‐driven review on the chemistry, properties, and applications of aerogels is provided. Aerogel is a category of solid materials having homogeneous, highly p...
Preparation of Cyclic Olefin Polymers via Group Transfer Radical Cyclopolymerization for High Performance in Anode‐Free Batteries
Abstract Cyclic olefin polymers (COPs) are of high importance in optical and medical materials. These materials are typically synthesized via ring‐opening metathesis polymerization o...
A Simple Quinoid Building Block for Polymer Semiconductors with Tunable Polarity and High n‐Type Thermoelectric Performance
Abstract π‐Conjugated polymers with deep‐positioned lowest unoccupied molecular orbital (LUMO) level and large electron mobility are highly pursued as n‐type org...
Electronic Structure Origins of Distinct Hydrogenation Activities Observed for Linear and Bent Bimetallic <i>μ</i> ‐Nitrides
Abstract Hydrogenation of metal nitrides is of particular interest due to the direct relevance to Haber–Bosch ammonia synthesis. Notably, for all bi‐ and multi‐n...
Nucleophilic Covalent Ligands Enable Simultaneous Surface Reconstruction and Passivation of Colloidal InSb Quantum Dots for Stable Short‐Wave Infrared Photodetectors
Abstract Indium antimonide (InSb) colloidal quantum dots (CQDs) are promising candidates for short‐wave infrared (SWIR) photodetectors due to their large Bohr exciton radius and tuna...
Beyond Second Coordination Shell: Long‐Range π‐Electrons Delocalization Engineering in Single‐Atom Catalysts for CO <sub>2</sub> Electroreduction
Abstract Although long‐range charge delocalization beyond the second coordination shell critically influence the geometric and electronic properties of single‐at...
Antiparallel <i>β</i> ‐Sheet as a Key Motif of Amyloid‐ <i>β</i> Inhibitor Designed via Topological Peptide Reprogramming
Abstract Peptide inhibitor design targeting self‐assembly of amyloid‐ β (A β ) re...
Bromide as Noninnocent Ligand to Iron Tames Fenton Chemistry for Chemoselective Nondegrading Oxidation
Abstract It has long been the chemistry dogma that the nitrogen‐based ligand of iron complexes determines the redox reactivity; tetra‐ and/or pentadentate nitrog...
Multiple‐Asymmetric Molecular Engineering Enables Regioregular Selenium‐Substituted Acceptor with High Efficiency and Ultra‐low Energy Loss in Binary Organic Solar Cells
Abstract Asymmetric molecular engineering is utilized for developing efficient small molecular acceptors (SMAs), whereas adopting multiple asymmetric strategies...
Covalent Organic Framework Nanosheets for the Assembly of Efficient Membrane Bioreactors
Abstract Immobilizing fragile enzymes in porous materials holds significant potential for biocatalysis but encounters challenges such as mismatched enzyme size and pore structure of...
Nucleophilic Germylation of Stable π Bonds via Ge─Ge Bond Heterolysis
Abstract Organogermanes have recently attracted a great deal of attention as building blocks for the synthesis of bioactive products, drugs, and functional mater...
On‐Surface Synthesis of Nanographenes Through Domino Cyclization Reactions
Abstract On‐surface synthesis has emerged as a powerful method to synthesize nanographenes that are difficult to obtain through the solution chemistry, but the n...
Production of H <sub>2</sub> O <sub>2</sub> via Energy Transfer Photocatalysis by Coupling with Furfuryl Alcohol Conversion over an Amide‐Functionalized Heptazine Framework
Abstract Photocatalytic oxygen reduction provides a sustainable approach for hydrogen peroxide (H 2 O...
Visible Light Excited Time‐Dependent Phosphorescence Color Tuning in Carbon Dots via Charge Transfer
Abstract Achieving high‐efficiency time‐dependent phosphorescence color (TDPC) materials that can be activated under visible light with strong stability remains challenging. In this...