Angewandte Chemie International Edition

Sensitized Disequilibration of Water‐Soluble Azopolymers

Abstract Photo‐responsive systems based on azobenzenes usually require UV light for E → Z...

Regulation of Active Hydrogen and Nitrate Concentration: Pulsed Potential Strategies in Nitrate Electroreduction Microenvironments

Abstract The electrochemical reduction of nitrate (eNO 3 RR) plays a significant role in the nitrogen cycle and environme...

Complementary Multi‐Resonance Thermally Activated Delayed Fluorescence Design for Blue OLEDs Beyond the Concentration Limit

Abstract Advances in boron‐based organic compounds exhibiting multi‐resonance (MR)‐type thermally activated delayed fluorescence (TADF) have been primarily driven by their potential...

Synthesis, Structure, and Reactivity of a Magnesium(0) Complex with a Polarized Mg ^δ− ─Ca ^δ+ Bond

Abstract Despite numerous examples of Mg─Mg bound complexes, complexes with unsupported two‐center‐two‐electron Mg─Ca bonds so far always eluded their isolation....

Inside Front Cover: Direct Synthesis of H ₂ O ₂ by Spatially Separate Hydrogen and Oxygen Activation Sites on Tailored Pt–Au Catalysts (Angew. Chem. Int. Ed. 7/2026)

Electrochemical Controllable Divergent Carboxylation and Hydrocarboxylation of Alkynes with CO ₂

Abstract Carboxylation and hydrocarboxylation of alkynes with CO 2 for the synthesis of value‐added and versatile carboxy...

Direct Synthesis of H ₂ O ₂ by Spatially Separate Hydrogen and Oxygen Activation Sites on Tailored Pt–Au Catalysts

Abstract The direct synthesis of H 2 O 2 is considered an atom‐efficient, environ...

Geometry Controls Confined Water Dynamics in Lipidic Mesophases

Abstract Water under nanoscale confinement is central to biological function, catalysis, and soft materials, yet how geometry dictates its structure and dynamics remains unresolved....

Ionomer‐Driven Reaction Microenvironment Control in Bicarbonate‐Mediated Integrated CO ₂ Capture and Electrolysis

Abstract Bicarbonate electrolysis coupling upstream CO 2 capture with electrochemical conversion of captured CO...

Carbonized Polymer Dots as Versatile Nanocarrier for Bioincompatible Fluorophore Imaging

Abstract Fluorophores with excellent emission often come at the cost of cell permeability, and this long‐standing dilemma has limited their effective application...

Regulation of the <i>D</i> ‐Band Center Through Ligand Engineering in Silver Cluster‐Based MOFs Enhances Acidic CO ₂ Electroreduction

Abstract Acidic electrochemical CO 2 reduction reaction (eCO 2 RR) offers a promi...

Dual‐Induced Confined Synthesis of Metastable γ‐MnO ₂ Nanoclusters in Metal–Organic Frameworks for Highly Efficient Ozone Decomposition

Abstract Ultrafine metal oxide nanoclusters (UMONs) exhibit remarkable catalytic potential due to their high specific surface area; however, achieving precise co...

Anthracene Bisurea as a Supramolecular Chloride Receptor for Additive‐Free, Broad‐Scope Gold(I) Catalysis

Abstract Gold catalysis provides access to a remarkable array of complex carbon scaffolds, but the use of silver salts to activate gold(I) chloride precatalysts can be problematic du...

Realizing Cocktail Effects in Catalytic High‐Entropy Metal–Organic Frameworks (HEMOFs) via Predictive Density of State Calculations

Abstract High‐entropy materials, particularly high‐entropy metal–organic frameworks (HEMOFs), represent a promising class of catalysts amenable to imparting supe...

Decoupling Adsorption of Key Intermediates Enabled by Asymmetric 3d‐5d‐Orbital Hybridization: Durable High‐Performance AEM Water Electrolysis and Zn–Air Batteries

Abstract Decoupling key intermediates’ adsorption via asymmetric 3d‐5d‐orbital hybridization overcomes the intrinsic scaling relation bottleneck, enabling ration...

Design of Adsorption‒Diffusion Dual‐Driven MOF Membranes for Efficient CO ₂ Separation

Abstract Metal–organic frameworks (MOFs) offer exceptional tunability in pore structure and functionality, holding considerable potential for advanced gas separa...

Biomimetic NaK Channel Membrane Enabled by a Crown Ether‐Coordinated Metal–Organic Framework

Abstract Biological NaK channels integrate exquisite ion selectivity with dynamic gating to regulate life processes, yet achieving such multifunctionality in syn...

Overcoming Copper Instability via Nickel Alloying for Efficient Plasmon‐Catalytic CO ₂ Hydrogenation

Abstract The development of efficient, stable, and low‐coat plasmonic catalysts for CO 2 hydrogenation via the reverse wa...

Programmable DNA Nanostructures for hTERT Compartmentalization and Translocation in Living Cells

Abstract Protein translocation is essential for cellular function, and compartmentalizing proteins can regulate their activity. However, constructing artificial intracellular compart...

Alkynyltriazenes in Photochemical Metal‐Free Doyle–Kirmse Rearrangements

Abstract Doyle–Kirmse rearrangement reactions are widely recognized as versatile and powerful synthetic tools, promoting the simultaneous generation of C─C and C─S bonds. While notab...

Synergistic Action of Crystallophore and Imaging‐Crystallophore Enhances the Production and Imaging of Protein Crystals

Abstract The synthesis and photophysical characterization of a new family of terbium(III) complexes called Imaging ‐cryst...

Electrochemical Degradation of Perfluoroalkyl Sulfonates via Sulfonate to Carboxylate Conversion

Abstract Efficient, scalable, and well‐understood methods for degrading per‐ and polyfluoroalkyl substances (PFAS) are essential for limiting their numerous negative human health and...

M–O–C Catalysts: Copper Single Atoms Supported on Oxocarbon Covalent Networks as Electrocatalysts for Glycerol Oxidation to Formic Acid

Abstract N‐doped carbon single‐atom catalysts (M–N–C) have emerged as some of the most efficient electrocatalysts, offering both high activity and selectivity. T...

Benzoyl‐Xanthenoxanthenes: Versatile Chromophores for Light‐Engaging Applications

Abstract In this work, we present a modular donor–acceptor strategy that produces oxidatively stable, benzoyl‐fused peri...

Oxygen‐Bridged Dual Catalytic Sites Enable Asymmetric C─C Coupling for Efficient CO ₂ Electroreduction to Ethanol

Abstract Understanding C─C coupling pathways is essential for achieving selective CO 2 conversion into multi‐carbon produ...