Angewandte Chemie International Edition
Articles in this Issue
Hexavalent Iridium Sites Drive Highly Efficient and Selective Chlorine Evolution via a Two‐Step Chemical‐Electrochemical Cycle Reaction Mechanism
ABSTRACT Chlorine evolution reaction (CER) is pivotal to the chlor‐alkali industry, while its operation still relies on the dimensionally stable anode (DSA) deve...
Chemical Biology Tools for Decoding the Cell Surface GlycoRNA
ABSTRACT The discovery of glycosylated RNAs (glycoRNAs) on the outer surface of mammalian cells, represents a spatial awakening in RNA biology. This identification redefines the spat...
Beyond Excimer: Engineering Pyrene Stacking With Mechanical Bonds for Tunable Emissions
ABSTRACT Aiming to deepen the fundamental understanding of how hierarchical molecular packing governs the overall photophysical properties in multi‐chromophore s...
Extending the Temperature and Time Operating Windows of CsPbI <sub>3</sub> Quantum Dots for Scalable Synthesis for LEDs
ABSTRACT Large‐scale manufacturing of CsPbI 3 quantum dots (QDs) is hindered by narrow thermal and temporal operating win...
Continuous Evolution of Calmodulin for High‐Purity Separation of Rare Earth Elements
ABSTRACT The grand challenge of separating critical rare earth elements (REEs) stems from their similar physicochemical properties, requiring complex process flow‐sheets to achieve h...
Phase Separation of Nucleic Acids: Mechanisms, Properties, and Applications
Abstract Nucleic acids are essential biological macromolecules bearing genetic information and playing important roles in post‐transcriptional regulation. Given their high programmab...
Aggregation‐Induced Upconversion Luminescence of Ultra‐High‐Brightness Lanthanide Organic Cages X‐ray Scintillators
ABSTRACT In this work, aggregation‐induced emission luminogen (AIEgen) were used as ligand to achieve the first aggregation‐enhanced ligand triplet‐mediated coop...
Photochemical N‐dealkylation of Tertiary Amines Coupled With Photocharging of Poly(Heptazine Imides)
ABSTRACT Photocharging in carbon nitride materials is emerging as a promising route for light‐driven energy storage, yet the nature of the storage sites and thei...
Electrocatalytic Nitrate Reduction to Hydroxylamine: Breaking the Activity‐Selectivity Trade‐Off by Designer Bifunctional Metal‐Organic Frameworks
ABSTRACT Electrocatalytic nitrate reduction reaction (NitRR) offers a promising route for hydroxylamine (NH 2 OH) synthes...
Alternately Twisted, Electron‐Rich Rylenes and Their Stable Cations
ABSTRACT Solution‐phase synthesis of long rylenes remains challenging due to their strong tendency to aggregate. Introducing backbone twist can reduce aggregatio...
Surface‐Assisted Wurtz Coupling for the Stereoselective Synthesis of Covalent Organic Frameworks
ABSTRACT Surface‐confined precision synthesis of 2D covalent organic frameworks (COFs) represents a crucial bridge connecting molecular design with macroscopic m...
Steering Ethylene Electrosynthesis by Controlling Interfacial Water Orientation
ABSTRACT Controlling reaction pathway via solvent polarization dynamics remains a grand challenge in catalysis due to elusive interfacial kinetic regulation mech...
Brush‐Like Tetrameric Acceptors Achieving over 20% Efficiency With Exceptional Stability and Mechanical Robustness
ABSTRACT Well‐defined high‐molecular‐weight acceptors have recently emerged as promising materials for organic solar cells (OSCs), offering high power conversion...
Mechanism of the Photodecomposition of Stable Triarylmethyl Radicals
ABSTRACT Luminescent radicals, the vast majority of which are derivatives of tris(trichlorophenyl)methyl (TTM), are of significant recent interest because of the unique photophysical...
Solid Solution In Situ‐Reconstructed Mg‐Cu <sub>2</sub> O/Cu Heterointerface for CO <sub>2</sub> Reduction to C <sub>2+</sub> Alcohols in Neutral and Acidic Media
ABSTRACT Electrochemical CO 2 reduction presents a sustainable route for producing value‐added liquid C...
Catalyst‐Free Ammonia Formation at the Gas‐Liquid Interface Enables Selective Nitrogen‐Saccharide Association Under Abiotic Conditions
ABSTRACT Ammonia (NH 3 ) is one of the quintessential building blocks in the renowned nitrogen cycle, which sustains life...
Sustaining Methanol‐Oxidation and Hydrogen Evolution at Low Voltage by Applying Periodic Polarity Reversal on a Symmetric Pt‐Based Electrode Pair
ABSTRACT It has been established that Pt‐based electrocatalysts can enable the methanol oxidation reaction (MOR) to produce value‐added formate at ultralow poten...
Orbital‐Level Chemical Coding for Exclusive Detection of VOCs Gases in Chemiresistive Sensors
ABSTRACT Cost‐effective chemiresistive gas sensors are widely applicated in the commercial detection of volatile organic compounds (VOCs). However, their poor se...
Highly Efficient Tandem Electrosynthesis of Dimethyl Carbonate From CO <sub>2</sub>
ABSTRACT Current DMC production is energy‐intensive, while generating CO 2 emissions. Electrosynthesis of DMC from CO...
Encapsulated Non‐Exchangeable Na <sup>+</sup> Ions Determining the Upper Limit of Al Inclusion in FAU—A Multiscale Simulation
ABSTRACT Na + ion as charge‐balance agent controlling the distribution of framework aluminum atoms in Y‐zeolite from 1 to...
A General Group Testing Strategy for Discovering Chemical Cooperativity
ABSTRACT The combinatorial explosion inherent to multi‐component systems limits their experimental exploration and ultimately chemical discovery. Here, we introduce a statistics‐base...
Ultra‐Low‐Cost Hydrophobic Organic Coating for Highly Reversible Zinc Anodes
ABSTRACT Electrolyte additive engineering offers a promising pathway for achieving dendrite‐free aqueous zinc‐ion batteries (ZIBs) while facing challenges relate...
Tuning Exciton–Phonon Coupling by Isotope Engineering: Regulated Charge Carrier Evolution in Carbon Nitride Photocatalysts
ABSTRACT Polymeric carbon nitride (C 3 N 4 ) has emerged as a promising photocata...
Harnessing Exciton Flux With a Single‐Stranded DNA‐Programmed Nanodevice
ABSTRACT Natural and artificial nanosystems rely on functional module assembly, yet overcoming thermodynamic incompatibility in atomically precise nanodevice integration remains chal...
Regioselective Electrosynthesis of Substituted (deuterated) Pyridines Through Enamine‐Iminium Cross‐Coupling
ABSTRACT An electrochemical protocol for the regioselective synthesis of multi‐substituted pyridines via a (3+3) annulation is described. The strategy utilizes enamine‐iminium cross‐...