Angewandte Chemie International Edition

Huasong Ai

3D‐Printable Nanoporous Thermosets via Disulfide‐Based Polymerization‐Induced Microphase Separation

ABSTRACT Interconnected nanoporous polymer networks are central to applications that demand rapid mass transport, yet their fabrication by polymerization‐induced microphase separatio...

Sustainable Synthesis of Ammonium Nitrate From Air and Water via Tandem Plasma‐Electrolyzer System

ABSTRACT Ammonium nitrate (NH 4 NO 3 ) is an indispensable high‐nitrogen fertiliz...

Substrate‐Controlled Dearomative Cycloadditions of Perfluoronaphthalenes via Visible‐Light Energy Transfer Catalysis: Switchable Access to [2+2], [4+2], and Diastereoconvergent Cycloadducts

ABSTRACT We report the first substrate‐controlled intermolecular dearomative cycloaddition of polyfluoronapthalenes in which the substitution pattern of the olef...

Correction to “Sono‐Triggered Cascade Lactate Depletion by Semiconducting Polymer Nanoreactors for Cuproptosis‐Immunotherapy of Pancreatic Cancer”

Synergistic Dual <i>d</i> ‐Band Engineering at the Ru‐N ₄ /MXene Interface for High‐Efficiency and Long‐Lived Li–CO ₂ Batteries

ABSTRACT The cyclability of Li–CO 2 batteries is fundamentally limited by the...

Pd Single‐Atom‐Doped Cu ₃ Co Quantum Dots With Optimized Hydrogenation Kinetics for Versatile Aluminum‐Nitrate Primary Battery With Synchronous Energy Harvesting and Waste Valorization

ABSTRACT The rational design of nitrate batteries enabling simultaneous electricity generation and pollutant degradation is highly promising, yet most reported s...

Outside Front Cover: 3D‐Printable Nanoporous Thermosets Via Disulfide‐Based Polymerization‐Induced Microphase Separation (Angew. Chem. Int. Ed. 33/2026)

Copper (II) Chloride Mediated Interfacial Permeation for High‐Efficient and Stable Wide‐Bandgap Perovskite Solar Cells

ABSTRACT Wide‐bandgap (WBG) perovskite solar cells (PSCs) are crucial for high‐efficiency tandem photovoltaics. However, their performance is severely limited by...

A General Platform for <i>S</i> ‐Stereogenic α‐Fluoroalkyl S(IV/VI) Compounds via Enantioselective Radical Fluoroalkylation of Sulfenamides

ABSTRACT α‐Fluoroalkyl‐substituted high‐valent sulfur motifs are important structural elements in fluorinated molecule design and exhibit broad application poten...

Antiaromaticity‐Driven Enhancement of Single‐Molecule Electrical Conductance by <i>s</i> ‐Indacene Molecular Bridges

ABSTRACT High electrical conductance of antiaromatic molecules compared with aromatic counterparts at the single‐molecule level has been a topic of controversy,...

Excited‐State Antiaromaticity in Nonbenzenoid Aromatics: Examining the Dynamics of Intramolecular Proton Transfer With a Small Driving Force

ABSTRACT The relief of excited‐state antiaromaticity (ESAA) is a powerful driving force that underpins the photochemical behavior of photoexcited aromatic molecules. Photo‐induced is...

Catalyst‐Free Upcycling of Polyethylene Waste Into Oxidized Polyethylene Wax

ABSTRACT Polyethylene (PE) accounts for 36% of the total plastic waste by mass. However, its inherent chemical stability poses significant challenges for chemica...

Light‐Driven Epimerization: Diastereoconvergent Synthesis of [ ¹² C, ¹³ C] <i>β</i> ^2,3 ‐Amino Acids

ABSTRACT β ‐Amino acids are crucial building blocks for bioactive peptides and pharmaceuticals, wherein the stereochemistry of C...

“Two‐in‐One” Anion Engineering Strategy for One‐Step Ethylene Purification From a Ternary Mixture

ABSTRACT One‐step purification of C 2 H 4 from a C 2...

Ultrastable Non‐Noble‐Metal Oxygen Evolution Electrocatalyst for Industrial‐Level Water Electrolysis

ABSTRACT The sluggish kinetics of alkaline oxygen evolution reaction (OER), together with the highly polarizing conditions at industrial‐level ampere‐scale curre...

Orbital Stabilization of Anionic Redox via Surface Restructuration for Li‐Rich Mn‐Based Layered Oxides

ABSTRACT Lithium‐rich layered oxides are renowned for their high capacity, originating from both cationic and anionic redox reactions. However, the anionic redox...

Reversible Calcium Metal Anodes Enabled by Asymmetric Solvation Effect in Hybrid Ca‐Na Organoborate Electrolytes

ABSTRACT Calcium metal batteries represent a promising frontier for high‐energy‐density energy storage, yet their practical application is hindered by sluggish k...

CSAKD: Determining Absolute Ligand Affinities From ¹⁹ F NMR Chemical Shift Anisotropy

ABSTRACT Small‐molecule drug discovery typically begins with the screening of compound libraries to identify initial hits, which are subsequently optimized into lead compounds and, u...

Adaptive Cavity‐Enabled Crystalline Chirality in Nanocarbon Cages

ABSTRACT Chiral nanocarbons are attractive because their unique chiroptical properties enable advanced optical applications. In this work, we report the discover...

Control of Circularly Polarized Luminescence in Cholesteric Luminescent Liquid Crystals: From FRET to Exciton Coupling

ABSTRACT Achieving circularly polarized luminescent (CPL) materials with tunable wavelength and high dissymmetry factor ( g...

Overcoming Data Starvation: Automated Virtual Reaction Exploration and Machine Learning Discovery of <i>p</i> ‐Block Metal Catalysts for Borrowing Hydrogen

ABSTRACT (De)Hydrogenation processes, traditionally dominated by d ‐block transition metals, offer a sustainable route fo...

Distinct Oxidoreductases Orchestrate Indolethiophene Skeleton Formation and <i>N</i> ‐Hydroxylation‐Mediated Bioactivation in Thienoxidolin Biosynthesis

ABSTRACT Microbial sulfur‐containing secondary metabolite thienodolin ( 1 ) features a unique tricyclic thieno[2,3‐...

Iron‐Catalyzed Cyclopropanation of Allenes Using Unactivated Alkyl Sulfonium Salts

ABSTRACT The catalytic generation and transfer of non‐stabilized carbenes represent a formidable challenge in synthetic chemistry, historically necessitating the use of hazardous dia...

Localized Accumulation of Tri‐n‐Propylamine Prolongs Electrochemiluminescence for Tumor Model Spheroid Analysis

ABSTRACT Electrochemiluminescence (ECL) is a technique that couples electrochemical control with photon emission, enabling highly sensitive, label‐free imaging w...