Angewandte Chemie International Edition
Articles in this Issue
Boosting Dehydration via Coupling With the Water‐Gas Shift Reaction
ABSTRACT To address the challenge of removing water from dehydration reactions when reaction components share similar physical properties with water, we develope...
Ion‐Exchange and Energy‐Stress Strategies Amplified Dual‐Site Nanozyme‐Mediated Ferroptosis/Pyroptosis Inhibition for Neuroprotection
ABSTRACT Early neuroprotection is crucial for improving the prognosis of secondary injury after intracerebral hemorrhage (ICH). Herein, this work developed an in...
Mechanochemical H‐Bonding Organocatalysis Enabled Controlled Synthesis and Recycling of High‐Molecular‐Weight Poly(ɛ‐Caprolactone)
ABSTRACT The use of organocatalysts for the ring‐opening polymerization (ROP) to achieve high‐molecular‐weight poly(ε‐caprolactone) (PCL) remains challenging. In...
Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal
ABSTRACT Birefringent crystals are key materials for controlling the polarization state of light, and breakthroughs in their performance are crucial for advanced...
Sulfur‐Modulated Fully‐Conjugated Self‐Assembled Monolayers for Synergistic Dual‐Interface Optimization in Inverted Perovskite Solar Cells
ABSTRACT To achieve high efficiency and stability in inverted perovskite solar cells (PSCs), it is essential to ensure uniform self‐assembled monolayers (SAM) coverage on the substra...
Directed Amorphous‐to‐Amorphous Reconstruction Toward Efficient Oxygen Evolution
ABSTRACT To fully unlock catalytic potential in the oxygen evolution reaction (OER), it is essential to guide the reconstruction process, orienting the evolution...
Dynamic Covalent Chemistry in Systematic Construction of Hydrogen‐Bonded Organic Frameworks
ABSTRACT Dynamic covalent chemistry (DCC), which enables error correction during the reversible covalent reaction process, presents an efficient approach for the...
Oxyphilic Ru‐O‐Mn <sup>2+</sup> Interfaces on Ru/MnO Catalysts: Unprecedented Activity for Low‐Temperature CO <sub>2</sub> Methanation
ABSTRACT Catalytic CO 2 methanation using renewable H 2 presents a promising stra...
Triple Matrix Confinement‐Induced Ultrabright Afterglow From Carbon Dots With Multivariate Responsive Afterglow Colors for Advanced Dynamic Information Encryption
ABSTRACT Dynamic afterglow carbon dots (CDs) materials, capable of long‐duration emission and dynamic color changes after excitation, hold promise for widespread...
Engineering Multivalent Copper Catalysts From Cu‐MOF Towards High‐Performance C <sub>2</sub> Electrosynthesis
ABSTRACT Electrocatalytic CO 2 reduction reaction (ECO 2 RR) stands as a crucial...
Selective Conversion NOx Into Isoxazoles via Co–Zn Electrocatalyst Steering the Reaction Pathway
ABSTRACT The electrocatalytic upcycling of NOx species into valuable N ‐heterocycles presents an attractive route, but it...
Unveiling Direct and Indirect Pathways of Electrochemical CO <sub>2</sub> Reduction in Amine‐Based Carbon Capture Electrolytes
ABSTRACT Investigating the origins of carbon sources and mechanistic pathways in the electrochemical conversion of CO 2 f...
α‐Trifluoromethyl Substituted α‐Hydroxyhydrazides as Dianionic Ligands Enable Cu‐Catalyzed Aryl Amination With Higher Turnovers
ABSTRACT The α‐trifluoromethyl‐substituted α‐hydroxy‐hydrazides function as highly efficient ligands for copper‐catalyzed coupling reactions between (hetero)aryl halides (Cl, Br) and...
Suppressing Reductive Deactivation of Fe <sub>2</sub> O <sub>3</sub> via In─O─Fe Motif Formation for CO <sub>2</sub> Hydrogenation
ABSTRACT Transition‐metal oxides are susceptible to over‐reduction under hydrogen‐rich conditions, thereby hindering intermediate turnover and accelerating deact...
Engineering Al‐Pair‐Enriched Hierarchical Zeolites via D‐6R SBU‐Directed Aluminum Reorganization During Desilication
ABSTRACT Alkaline desilication is commonly used to create hierarchical pores in zeolites but is often limited by dealumination and surface passivation, as leache...
Noncovalent Cluster Packing Enables Ultrastable Glasses for Preservation and Delivery of Labile Biomolecules
ABSTRACT The properties of molecular glasses are governed by a thermodynamic‐kinetic coupling described by the Adam–Gibbs theory. This relationship enforces a pe...
Small‐Molecule Activation of mRNA Translation by Click‐to‐Release Reaction in Cells
ABSTRACT mRNA is an emerging medical modality, however, approaches to control its activity lack behind other biologics. Bioorthogonal click‐to‐release reactions...
Surface Segregation‐Assisted Direct Regeneration of Spent Layer Cathodes
ABSTRACT Direct regeneration has emerged as a promising approach, owing to its economic and environmental advantages. However, the efficiency of lithium replenis...
Rational Construction and Modulation of Built‐In Electric Field for High‐Efficiency Alkali Metal‐Based Batteries
ABSTRACT With the large‐scale adoption of electric vehicles and the ongoing integration of renewable energy into the grid, the development of high‐performance alkali metal‐based batt...
Dibenzazepine Bridged Network Polymeric Phthalocyanines as Degradable Heterogeneous Photocatalysts
Abstract Recyclability and energy efficiency are inevitable requirements in today´s synthetic materials, as well as functional efficiency. Network polymeric phth...
Isaac Choi
Atomically Precise Interfacial Engineering on Tin‐Silicon Oxo Clusters for Sub‐8 nm Lithography
ABSTRACT Tin oxo clusters (TOCs) have been recognized as the most promising photoresist candidates for high numerical aperture extreme ultraviolet (High‐NA EUV)...
Photoelectrochemical Heterogeneous Catalysis: From Single Molecule Oxidation Toward C─X Bond Formation
ABSTRACT Photoelectrocatalytic (PEC) organic synthesis has emerged as a promising platform for sustainable chemical manufacturing by synergistically integrating light and electrical...
Low‐Temperature Reverse Water–Gas Shift Enabled by Magnetically Induced Catalysis
ABSTRACT Equilibrium‐limited endothermic reactions play a crucial role in the transition toward a more sustainable chemical industry, but are typically plagued by the need for high o...
Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling
ABSTRACT Given the short half‐life of radionuclides used for positron emission tomography (PET), such as fluorine‐18 ( t...