Angewandte Chemie International Edition
Articles in this Issue
Sebastian Clementson
Stereoselective Synthesis of Aminals Through Enzyme‐Catalyzed Intermolecular C(sp <sup>3</sup> )‐H Amidation of Azacycles
ABSTRACT Stereogenic aminals are widespread in natural products, pharmaceuticals, and biologically active compounds, including important classes of antibiotics....
Reflex Charging for Anion‐Derived Solid Electrolyte Interphase Formation
ABSTRACT Lithium (Li) metal offers exceptional energy density but suffers from unstable interphases that lead to dendrite growth and poor reversibility. Because...
Domino Effect in Epimer Self‐Assembly Induces Diverse Hydrogel Properties for Biomedical Applications
ABSTRACT Precise regulation of small‐molecule self‐assembly remains a formidable challenge, as subtle structural variations can trigger profound reprogramming of supramolecular archi...
Bottlebrush Polyolefin Sulfones as Triggerable and Degradable Pressure‐Sensitive Adhesives
ABSTRACT The molecular architecture (topology) of bottlebrush polymers, featuring densely grafted side chains along a polymeric backbone, leads to unique physica...
Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective
ABSTRACT The increasing applications of electrochemical energy‐storage systems in transportation, aerospace, and grid applications impose stringent requirements on electrolytes capab...
Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons
ABSTRACT Phenonium intermediates are almost universally invoked to account for 1,2‐aryl migration processes in reactions that exploit in situ‐generated hypervale...
Pre‐Crosslinking via MOFs With Coordinatively Unsaturated Metal Sites for Fabricating Macroporous Hydrogels Toward Efficient Atmospheric Water Harvesting
ABSTRACT Freshwater scarcity is a global crisis, and sorbent‐based atmospheric water harvesting (SAWH) offers location‐independent water supply, yet developing f...
Giant Compressed Mo Blue Wheel {Mo <sub>118</sub> }: A Molecular Photothermal Agent for High‐Effective NIR‐II Chemo‐Photothermal Therapy
ABSTRACT The rational construction of well‐defined polyoxometalate (POM)‐based second near‐infrared (NIR‐II) molecular photothermal agents (PTAs) and the elucida...
Unlocking the Distance Effect on CO <sub>2</sub> Electroreduction to Multi‐Carbon Products via Monolayer Model Catalysts
ABSTRACT The interaction between adjacent active sites significantly influences electrocatalytic performance, for example, CO 2...
Structural Water‐Enabled Helicity Emergence From an Asymmetric Achiral Molecule
ABSTRACT Helical supramolecular architectures are ubiquitous in nature yet remain challenging to construct from asymmetric achiral molecules. Here, we demonstrat...
Component Self‐Initiated Photopolymerization for Gel Polymer Electrolytes in Zinc–Air Batteries
ABSTRACT Flexible zinc–air batteries (FZABs) require gel polymer electrolytes (GPEs) to ensure ionic transport, interfacial stability, and mechanical flexibility...
Asymmetric Tellurium‐Bonding Catalysis for Mannich Reaction
ABSTRACT Chalcogen‐bonding catalysis has recently emerged as a powerful tool in organocatalysis. Nevertheless, its application in asymmetric transformations rema...
Allosterically Controlled Capture of Mutually Repulsive Guests With Positive Cooperativity and Ultrahigh Affinity
ABSTRACT A hexacationic cage incorporating three urea units can encapsulate two mutually repulsive anions in close proximity through a combination of hydrogen bo...
Synthesis, Structure, and Photothermal Conversion of a Bowl‐Shaped Nanographene Containing Fused 5‐/7‐Ring Pairs
ABSTRACT Incorporation of non‐hexagonal topologies into bowl‐shaped nanographenes offers opportunities for tailoring their electronic properties and supramolecul...
Degradable Alternating Copolymers With Strained Cyclobutane Backbones via Photocontrolled RAFT Polymerization
ABSTRACT In this study, we report a reversible addition‐fragmentation chain transfer (RAFT) alternating copolymerization of 1,3‐disubstituted bicyclo[1.1.0]butanes (BCBs) with maleim...
Regulating Solvation Chemistry via Strongly Coordinating Anion and Weakly Solvating Cosolvent for Low‐Temperature Sodium Metal Batteries
ABSTRACT Sodium metal batteries (SMBs) hold great promise for next‐generation energy storage systems due to their abundant sodium resources, high theoretical spe...
Cr‐Leaching Induced Vacancy Engineering for High‐Performance Anion Exchange Membrane Water Electrolysis
ABSTRACT Anion exchange membrane water electrolysis (AEMWE) offers a compelling route to large‐scale green hydrogen production. However, developing catalysts tha...
Heterocyclic Nanographenes Doped with Boron and Phosphorus: Post‐Phosphorization Synthesis, Excited‐State Dynamics and Ion‐Responsive Properties
ABSTRACT Incorporating more than one kind of heteroatom into polycyclic aromatic hydrocarbons is a powerful method for achieving diversiform heterocyclic structu...
Polymer Composites of Ultra‐Small Nanoparticles: Coupled Dynamics for Synergistic Processability
ABSTRACT Ultra‐small nanoparticles (USNPs), characterized by fast dynamics, ultra‐small dimensions and dense surface functionalities, offer an underexplored yet...
Field‐Free Spin‐Polarized Charge Transport in Chiral Co <sub>3</sub> O <sub>4</sub> Boosts Supercapacitor Kinetics
ABSTRACT Supercapacitors offer ultrahigh power density but remain fundamentally constrained by limited interfacial charge‐transfer kinetics at high rates. Althou...
Atypical Condensation Domains Guide Discovery and Illuminate Biosynthesis of Myxoglucamides Featuring Vinyl‐Substituted, α‐Oxidized γ‐Amino Acids
ABSTRACT Condensation (C) domains in nonribosomal peptide synthetase (NRPS) pathways exhibit versatile functions that drive biosynthetic and chemical novelty. Th...
Hierarchical Chirality Memory Governs Dual Chiroptical Inversion in Mesoscopic Helical Covalent Organic Frameworks
ABSTRACT Constructing crystalline chiral covalent organic frameworks (CCOFs) with programmable chiroptical properties from a single chiral source remains highly challenging. Herein,...
Molecularly Templated Buried Interfaces for Inverted Perovskite Solar Cells
ABSTRACT The buried interface between self‐assembled monolayers (SAMs) and perovskite absorbers critically governs charge extraction and stability in inverted perovskite solar cells,...