Angewandte Chemie International Edition
Articles in this Issue
Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries
ABSTRACT Aqueous zinc–iodine (Zn–I 2 ) batteries are promising candidates for safe and cost‐effective energy storage, yet...
Chromium‐Catalyzed Stereodivergent Carbonyl Addition Dictated by Non‐Covalent Interactions
ABSTRACT Catalytic stereodivergent synthesis, which accesses the full complement of stereoisomers from a common precursor set, is a paramount objective in drug d...
Generalizable Strategies for the Synthesis of Cereblon‐Recruiting PROTAC Prodrugs
ABSTRACT Cereblon (CRBN)‐recruiting PROTACs (proteolysis‐targeting chimeras) are among the most clinically advanced degraders but remain challenging to chemically modify for translat...
Organic Molecules in Zeolites for Long‐Lifetime Afterglow
ABSTRACT Organic afterglow materials based on host–guest assembly have recently attracted extensive attention for their promising applications in photobiology an...
High‐Efficiency and Carbon‐Lean Electrochemical Desalination Enabled by Nucleophilic Engineering of Organic Molecular Electrode
ABSTRACT The worsening global freshwater crisis positions seawater desalination as a critical solution. However, conventional desalination technologies remain co...
Beyond PXRD Pattern Matching: Toward Rigorous Structure Determination in Covalent Organic Frameworks
ABSTRACT Widespread reliance on qualitative powder x‐ray diffraction (PXRD) pattern matching has led to systematic overinterpretation of covalent organic framework (COF) structures....
Unconventional‐Phase Pd <sub>20</sub> Te <sub>7</sub> Octahedra With High‐Index Facets for Oxygen Reduction
ABSTRACT The high surface energy leads to a significant challenge in the chemical synthesis of high‐index faceted nanomaterials. While the preparation of unconve...
Inside Front Cover: Modular Assembly of Bioconjugates Enabled by a Pyridine‐Based Chemoselective Sequential Conjugation Platform
Correction to “Rabies Virus‐Inspired Metal–Organic Frameworks (MOFs) for Targeted Imaging and Chemotherapy of Glioma”
Au Single‐Atom Interlayer Bridge Promotes Cross‐Layer Charge Transport and Intrinsic Catalytic Dual‐Sites Activation for Efficient CO <sub>2</sub> Photoreduction
ABSTRACT Layered photocatalysts are attractive for artificial photosynthesis, but their performance is often limited by inefficient charge transport across inter...
Outside Back Cover: Cycloazulenylene
High‐Triplet‐Energy Ancillary‐Ligand Regulation of Dual‐Antenna Eu(III) Scintillators: Near‐Unity PLQY for 3D X‐Ray Videography
ABSTRACT Eu(III) complex scintillators, benefiting from efficient triplet‐exciton utilization and strong x‐ray absorption, are promising candidates for advanced...
In Situ Explosion Induced “Stress + Defect” Structure for Enhanced Hydrogen Evolution Reaction
ABSTRACT The rational integration of lattice strain and carrier defect offers strategy to adjust the electronic structure of heterogeneous catalysts, yet remains...
Solvent and Ligand Control of Long‐Lived Charge‐Separated States in Cerium(IV) Photocatalysis
ABSTRACT Cerium(IV) complexes are powerful photooxidants with broad applications in organic synthesis and environmental remediation. We employ broadband transien...
Revisiting Coulombic Efficiency Paradigm: Electrolyte Additive Design for Lithium Metal Batteries
ABSTRACT Small‐dose electrolyte additives are widely used to enhance battery performance, yet rational additive selection for the stabilization of lithium metal...
A Rigid Molecular Triangle as an Ultrafast and Highly Selective Transmembrane Li <sup>+</sup> Channel
ABSTRACT A central challenge in engineering artificial ion channels is the simultaneous achievement of high ion transport efficiency and high selectivity. In thi...
Pairing a Zn <sub>1</sub> O <sub>1</sub> Monomer With Oxide Supports via Dual Interfacial Metal–Oxygen Bonding for Stable Conversion of Syngas to Light Olefins
ABSTRACT Atomically dispersed metal oxides on oxide supports have garnered significant attention for their exceptional catalytic activity and selectivity, yet th...
Light and Acid‐Base Dual‐Regulated Atom Transfer Radical Polymerization With ppb Concentrations of Zwitterionic Photocatalysts
ABSTRACT Here, we introduce highly efficient, and acid/base‐responsive zwitterionic photocatalysts (PC) for photoinduced atom transfer radical polymerization (ph...
Tailoring Photonic Transport in Cluster‐Assembled Crystals via Atomic‐Level Coordination Engineering
ABSTRACT The development of efficient optical waveguides requires precise control over photonic transport properties, yet linking atomic‐level structure to devic...
In Situ Sonoafterglow Supramolecular Hydrogel From Natural Substrate for Post‐Surgical Glioblastoma Treatment
ABSTRACT Fluorescence imaging suffers from substantial background interference and a low signal‑to‑background ratio due to real‑time excitation. In contrast, aft...
Ultrafine Iridium‐Oxide Solid Solutions for Efficient Acidic Water Oxidation
ABSTRACT The high cost and inadequate catalytic performance of IrO 2 are primary factors hindering the development of pro...
Pt Nanoplates Interfaced by Atomic CrO <sub>x</sub> Layer Enable High‐Power‐Density and Durable PEM Fuel Cells
ABSTRACT The dissolution of Pt‐based alloy catalysts remains a formidable challenge for oxygen reduction reaction (ORR) in proton exchange membrane fuel cells. H...
Counterion Dynamics in Chiral Supramolecular Polymerization
ABSTRACT Counterions have been studied in a broad range of chemical and biological systems, and their effects are typically evaluated by comparing different ioni...
A Mechanical Planar Chiral Rotaxane Induces Single‐Handed Helicity in a Twisted Perylene Diimide
ABSTRACT The twisting of chromophores such as perylene diimides (PDIs) into helical structures affords chiroptical properties from discrete molecules, which are of significant value...
Spontaneous Long‐Range Order and Alignment in Phase‐Separated Dynamic Covalent Networks Using Discrete Siloxanes
ABSTRACT For the first time, dynamic covalent networks are prepared that show spontaneous alignment and long‐range hexagonal columnar ordering. This is a consequence of the phase‐sep...