Angewandte Chemie International Edition
Articles in this Issue
Total Synthesis of <i>ent</i> ‐Kaurenoic Acid Diterpenoids Enabled by Distal Conformational Control in Photoredox Radical Polyene Cyclization
ABSTRACT We report a divergent synthesis of ent ‐kaurenoic acid‐derived diterpenoids enabled by a stereoselective photore...
Dynamic Dual‐Site Relay Catalysis Enables Selective Solar‐Driven CO <sub>2</sub> Reduction Toward Ethanol
ABSTRACT Photocatalytic CO 2 reduction to ethanol (C 2 H 5...
MOF‐Derived Hollow CoFe@NC Nanocages for Highly Efficient Degradation of Textile Fibers
ABSTRACT The accelerated accumulation of synthetic textile fibers, particularly 100% polyester (PET), poses a persistent environmental challenge due to their chemical inertness and r...
Sulfur‐Modulated Covalent Organic Framework Superstructures With Highly Dense and Fully Accessible Protophilic Sites for High‐Performance All‐Organic Proton Batteries
ABSTRACT Covalent organic frameworks (COFs) have emerged as competitive battery materials by solving the solubility and/or kinetics limitations of small molecule...
Upcycling Poly(ethylene terephthalate) Into High‐Efficient Epoxy Toughener: Hyperbranched Oligomer Induced Nano‐Structural Heterogeneities
ABSTRACT The post‐consumer recycling efficacy of poly(ethylene terephthalate) (PET) has attracted considerable attention. Current chemical recycling of PET predominantly targets mono...
Decoding Atypical G‐Quadruplexes and Their Interactome in Liquid Biopsies via Integrated Electroanalytical–Proteomic Technologies
ABSTRACT A multipurpose electroanalytical biotechnology to advance the role of atypical G‐quadruplex (G4) structures as emerging, multifunctional DNA biomarkers is reported. The tech...
Separation and Valorization of Chlorine From Tail Gas Streams
ABSTRACT The chemical industry generates chlorine‐containing tail gas streams on a million‐ton scale. Following the established linear approach, these streams ar...
Chemoenzymatic Radiosynthesis of a Gluconate Transporter‐Targeted In Vivo Bacterial Sensor From Clinical [ <sup>18</sup> F]FDG
ABSTRACT Many bacteria, but not mammalian cells, can directly import and metabolize extracellular gluconate via gluconate permease (GntP) and kinase (GntK). We h...
Hierarchical Surface‐to‐Bulk Architecture for High‐Performance O3‐Type Sodium Cathodes
ABSTRACT O3‐type layered oxide cathodes suffer from surface chemical instability and sluggish Na + transport within the O...
Harnessing Secondary Nucleation–Driven Supramolecular Bundled Fibers for Long‐Range One‐Dimensional Assembly of Semiconductor Nanocrystals
ABSTRACT Achieving long‐range 1D organization of semiconductor nanocrystals without altering their inherent optical properties is highly challenging, yet crucial...
Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry
ABSTRACT Thiele's hydrocarbon (TH) derivatives, or p ‐quinodimethanes, are prototypical members of the organic diradicalo...
Thermodynamically Driven Multi‐Site Photoswitching in Tetraoxindole Cavitands Controlled by Hydrogen Bonding and Mechanochemistry
ABSTRACT Integration of multiple photoswitches into a single multi‐responsive system is a promising strategy toward achieving high information density, complex l...
Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect
ABSTRACT Dipolar π‐conjugated groups with large polarizability anisotropy and hyperpolarizability are generally regarded as important nonlinear optical (NLO) act...
Synthesis and Activity‐Based Protein Profiling Identifies Aldo‐Keto Reductase 1C3 as Target Protein of Myxoglucamides
ABSTRACT Myxoglucamides, natural products recently isolated from Cystobacterineae sp., are featured by an unprecedented v...
A Review of Electrochemical–Biological Coupling Systems for CO <sub>2</sub> Valorization: Catalytic Fundamentals, System Integration, and Industrial Outlook
ABSTRACT To support dual‐carbon goals and address the limitations of conventional CO 2 valorization technologies, this re...
Photo‐Generated <sup>1</sup> O <sub>2</sub> Triggers In Situ RNA Crosslinking for High‐Contrast Tumor MRI and Effective Tumor Suppression
ABSTRACT High‐contrast imaging and effective treatment of hepatocellular carcinoma (HCC) remain challenging, largely due to the limited tumor selectivity of exis...
Semiconducting Covalent Organic Frameworks Based on Spin‐Delocalized Trioxotriangulene Neutral Radicals
ABSTRACT Electrically conductive two‐dimensional covalent organic frameworks (2D COFs) have emerged as a versatile class of crystalline porous polymers with prom...
Beyond Simple Mimicry: Next‐Generation Geometric Architectures and Future Paradigms in Small‐Molecule and Macrocyclic Peptidomimetics
ABSTRACT Peptidomimetics have matured from motif‑based inhibitors into a structural engineering discipline that systematically translates peptide recognition surfaces into drug‑like...
Peiran Wei
A Tautomeric Carbon Nitride Structure for Photocatalytic Overall Water Splitting
ABSTRACT Constructing type‐II heterojunctions is a prevalent strategy for enhancing the photocatalytic performance of polymeric carbon nitride (PCN). However, conventional PCN‐based...
Energy Transfer Catalysis Enabled by Multichannel Through‐Space Charge Transfer TADF Photosensitizers: [2 + 2] Photocycloaddition to Cyclobutane‐Fused Phosphindole 3‐Oxides
ABSTRACT Triplet energy transfer (TEnT) photocatalysis has emerged as a powerful tool for enabling mild and selective bond‐forming reactions. However, its genera...
Unlocking the Potential of Sparingly Soluble LiNO <sub>3</sub> in Carbonate Electrolytes With Pyridine as a Carrier Cosolvent for 450 Wh Kg <sup>−1</sup> High‐Voltage Lithium Metal Batteries
ABSTRACT LiNO 3 is a highly effective electrolyte additive for ether‐based lithium metal batteries, but its extremely poo...
Room‐Temperature Rapid Synthesis of Crystalline Ag─C Coordinated MOFs for Highly Efficient Acidic CO <sub>2</sub> Electroreduction
ABSTRACT The acidic CO 2 electroreduction reaction (eCO 2 RR) shows great promise...
A Universal Fenton‐Like Strategy for Selective Generation of <sup>1</sup> O <sub>2</sub> in Mixed Industrial Wastewater Treatment and Green Chemical Synthesis
ABSTRACT Sustained and selective generation of singlet oxygen ( 1 O 2 ) in Fenton...
Ion Bridging Enables Dual‐Interface Engineering for High Capacity and Long Cycling Aqueous Zinc–Sulfur Battery
ABSTRACT Aqueous Zn–S batteries (AZSBs) have garnered significant attention owing to their high energy density and low cost. However, their practical application...