Angewandte Chemie International Edition
Articles in this Issue
Intrinsic Near‐Infrared‐II Fluorescent Nanozymes Support High‐Resolution Imaging and Tumor Catalytic Immunotherapy
ABSTRACT Nanozymes hold considerable promise for in vivo therapy due to their stable and versatile enzyme‐mimicking activities. However, real‐time tracking of their dynamics with hig...
Correction to “Nanoscale Metal–Organic Layers for Deeply Penetrating X‐ray‐Induced Photodynamic Therapy”
Reversible Click Reactions in Water: A Robust and Customizable Synthetic Tool
ABSTRACT Beyond the context of click chemistry, reversible click chemistry refers to a class of coupling reactions that satisfy all the characters of click react...
Charge‐Transfer Assembly of Electrically Conductive Metal–Organic Cages
ABSTRACT We report a strategy for utilizing metal–organic cages (MOCs) as building blocks for assembling porous materials with high electrical conductivity. Real...
Cu <sup>+</sup> ‐Cu <sup>0</sup> Cluster Pairs in Defective MOFs for Highly Synergistic CO <sub>2</sub> Hydrogenation to Methanol
ABSTRACT Precise arrangement of multivalent Cu sites for the synchronized activation of CO 2 and H 2...
Substituent Variation in Tetraaza[14]Annulene‐Based Covalent Organic Frameworks for Modulation of Electronic States
ABSTRACT Introducing metal centers into covalent organic frameworks (COFs) is an effective and attractive strategy, but the pool of building blocks offering tuna...
Carbon‐Encapsulated Gemini Ionic Liquid as Advanced Bromine Hosts for High‐Performance Zn–Br <sub>2</sub> Batteries
ABSTRACT Zinc–bromine (Zn–Br 2 ) batteries represent a promising aqueous energy storage technology, yet their widespread...
Atomic–Level Interfacial Regulation Enables Efficient Chlorine Redox Chemistry in Rechargeable H <sub>2</sub> ─Cl <sub>2</sub> Batteries
ABSTRACT Hydrogen─chlorine (H 2 ─Cl 2 ) batteries are attractive high‐power energ...
Molecular Orientation‐Directed Isomerization in Indolocarbazole‐Embedded Multiple Resonance Emitter Enables High‐Performance Pure‐Green Electroluminescence
ABSTRACT Multiple resonance thermally activated delayed fluorescence (MR‐TADF) emitters are considered ideal candidates for high‐definition displays; however, si...
Correction to “Colossal Anisotropic Thermal Expansion Through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {Fe <sup>III</sup> <sub>4</sub> Fe <sup>II</sup> <sub>2</sub> } Compound”
Spatially Manipulating Polar Centers of Covalent Organic Frameworks for Boosting Hydrogen Peroxide Photosynthesis and Water Purification
ABSTRACT Hydrogen peroxide (H 2 O 2 ) photosynthesis from H 2...
Pd Nanoparticles Versus Single Atoms on CuTi‐LDH: Reversing Photoinduced Charge Transfer to Switch Radical Generation Pathway for Selective Methane Photooxidation
ABSTRACT Photocatalytic methane conversion to liquid products offers a promising route for the efficient utilization of methane while enabling the generation of...
Elucidating the Origin of Intensified Thermal Safety Concerns of Practical Next‐Generation High‐Energy‐Density Li‐Ion Batteries
ABSTRACT High‐specific‐energy battery systems, crucial for powering heavy‐lift unmanned aerial vehicles (UAVs) and electric vertical take‐off and landing (eVTOL)...
A Small Structural Change Makes a Big Difference: Synthesis of a Bowl‐Like Polyoxometalate‐Encapsulated {Ag <sub>7</sub> } <sup>5+</sup> Cluster and Its Structural Derivatives
ABSTRACT Ligand‐induced structural transformation has been developed as an effective strategy to manipulate the geometric/electronic structures, elemental compos...
One Ligand, Three Roles: L‐, X‐, and Z‐Type Coordination at Nitrogen
ABSTRACT Nitrogen‐based ligands are central to coordination chemistry but are limited to L‐ and X‐type donor behavior. Here we report a fundamentally new class o...
Asymmetric Ni–O–Co Active Sites Induce Spin‐State Transitions to Break Performance Trade‐Offs in Urea Electrolysis
ABSTRACT Urea‐assisted water electrolysis represents a sustainable paradigm for concurrent hydrogen production and wastewater remediation; however, its efficienc...
Binding‐Activated <sup>1</sup> O <sub>2</sub> ‐Genic Photosensitizers for Live‐Cell Control and Proteomic Mapping of Cytoskeletal Networks
ABSTRACT Cytoskeletal filaments and their associated organelles/proteins form a system‐level network that organizes cellular architecture and activity, yet chemi...
CO <sub>2</sub> ‐Derived Graphite: A Critical Material for Terrestrial and Martian Sustainability
ABSTRACT CO 2 , one of the major contributors to global climate change, is a promising carbon feedstock for graphite synt...
Strain‐Tunable Phonon Coupling and Polarization Optoelectronics in Supersaturation‐Grown Boron Phosphide Nanowires
ABSTRACT Boron phosphide (BP) nanowires represent a rare 1D semiconductor, combining outstanding chemical stability, ultrahigh hardness, and high thermal conduct...
Steering CO <sub>2</sub> Electroreduction to Methane and Deuterated Methane via Hydrogen‐Bond Engineering on Copper–Phenolic Networks
ABSTRACT Electrochemical CO 2 reduction (eCO 2 R) powered by renewable electricit...
Interfacial Fluorinated Ion Crowding Enables Reversible Zinc Metal Batteries
ABSTRACT Aqueous zinc metal batteries (AZMBs) are promising candidates for large‐scale energy storage owing to their intrinsic safety. However, their lifespan is...
Chelation Drives Surface Substitution in Hybrid‐MXenes
ABSTRACT Hybrid organic–inorganic MXenes ( h ‐MXenes) offer a versatile platform for tailoring the surface chemistry of t...
Flexible, Biocompatible Supercapacitors Weaved From Layered Phyllosilicates and Zwitterions via Ionicity
ABSTRACT Phyllosilicates, for example, bentonite clay, are among the most abundant natural minerals, yet their brittleness and poor conductivity have limited the...
Cyclic P <sub>3</sub> O <sub>9</sub> <sup>3–</sup> Trimer: A Network Former for Amorphous Superionic Conductors in Sodium Solid‐State Batteries
ABSTRACT Achieving solid‐state electrolytes (SSEs) that combine fast Na + conduction, high‐voltage stability, and deforma...
Heteronuclear Rh‐La Dual‐Atom Sites Enable Pathway‐Controlled Hydrogen Production in Ethanol Steam Reforming
ABSTRACT Achieving kinetic matching among elementary steps is critical for optimizing catalytic performance in complex reactions, yet rationally designing active...