Angewandte Chemie International Edition
Articles in this Issue
A Multidentate Coordination Complex‐Based Self‐Assembled Monolayer Stabilizes Perovskite Interface
ABSTRACT Self‐assembled monolayers (SAMs) have emerged as promising hole‐selective contacts for buried‐interface engineering in inverted perovskite photovoltaics...
Probe the Electron Spin Polarization of the Otherwise Unobservable <sup>3</sup> MLCT Triplet State Through Polarization Transfer Accompanying the Intramolecular Triplet–Triplet Energy Transfer in Pt(II)‐Salen Schiff Base Complexes
ABSTRACT The non‐Boltzmann population of the triplet sublevels in Pt(II)‐Schiff base complexes, and other phosphorescent transition metal complexes, exhibits lar...
Cycloazulenylene
ABSTRACT Nonalternant hydrocarbons differ significantly from their alternant analogs due to their nonsymmetric electronic structure, which manifests in distinct...
Controlled Reactive Metal−Support Interactions in NiIn/CeO <sub>2</sub> Catalysts for Enhanced Methanol Synthesis from CO <sub>2</sub>
ABSTRACT Reactive metal‐support interactions (RMSIs) frequently occur under high‐temperature reaction conditions, leading to intricate reconstructions of metal‐o...
Water‐Derived Radical Species Initiate Six‐Electron Oxidation of Cyclic Ketones in Microdroplets
ABSTRACT Direct six‐electron oxidation of cyclohexanone and other cyclic ketones and associated C‐C bond cleavage can be achieved in microdroplets without the ne...
Multirole Integrated Filler Design for Polymer‐in‐Salt Electrolytes Enables Long‐Life, Safe Solid‐State Lithium Batteries
ABSTRACT Although polymer‐in‐salt (PIS) electrolyte strategy is widely employed in solid‐state lithium batteries for interface stabilization through ion transpor...
Dynamic Ion‐Pair Networks Enable Selective Li <sup>+</sup> Transport for Stable and Efficient Solid‐State Lithium‐Sulfur Batteries
ABSTRACT Solid‐state lithium‐sulfur (Li‐S) batteries are intrinsically constrained by persistent Li + ‐anion coordination...
Biosynthesis of the Fully Saturated C <sub>16</sub> Homosesquiterpene Descartane Through Deprotonation With Cyclopropanation
ABSTRACT Non‐canonical terpene biosynthesis expands structural diversity beyond the classical C 5n logic. Here we report...
Azole γ‐Peptides Helix Switching via Heterocycle Substitutions
ABSTRACT Precise control of peptide backbone folding through non‐covalent interactions remains a major challenge in foldamer design. In this work, we demonstrate...
Polymer of Intrinsic Microporosity‐Derived Artificial SEI With Electronegative Sub‐1‐nm Channels for Robust Li‐Metal Anodes
ABSTRACT An unstable Li–electrolyte interface remains a major bottleneck for next‐generation Li‐metal batteries practically operated at high current densities (≥...
Direct Cytosolic Delivery of Amphiphilic Framework Nucleic Acids for RNA Interference
ABSTRACT The efficient cytosolic delivery of nucleic acid molecular machines remains a major challenge due to the dual barriers of the cell membrane and endosomal sequestration. Here...
Site Spacing Reconstruction Toward Perfect Hydrogen‐Bond Network for Fast Proton Transport
ABSTRACT Proton‐conducting materials are essential to electrochemical energy storage, conversion and sensing, yet their performance is restricted by structural l...
Ordering‐Driven Biaxial Strain Engineering in PtNi Intermetallic Nanowires for Oxygen Reduction Catalysis
ABSTRACT Precise regulation of lattice strain in platinum (Pt)‐based intermetallic catalysts is essential for optimizing oxygen reduction reaction (ORR) performa...
Isomeric Dibenzodiindenophenanthrene Diradicaloids: Synthesis, Structures, Properties, and Efficient NIR Photothermal Conversion for Imaging
ABSTRACT Structural isomerism is a powerful strategy to modulate the fundamental properties of organic diradicaloids. Herein, we report the synthesis and charact...
Discovery of a Reversible Sub‐Picomolar Thrombin Inhibitor Using DCC
ABSTRACT Dynamic combinatorial chemistry (DCC) offers a powerful yet underutilized strategy for ligand discovery, largely limited by heterogeneous kinetic constr...
Inside Front Cover: Design Guidelines for Anode Modifications to Eliminate Soft Short Circuits in Anode‐Free Na Batteries Under High Current Density With Large‐Capacity Plating, Demonstrated via Initiated Chemical Vapor Deposition (iCVD)
Precise End‐Group Conjugated‐Site Isomerization of Wing‐Typed Dimeric Acceptors Enables 20.32% Efficiency Organic Solar Cells
ABSTRACT Molecular isomerization has been proven as an effective strategy to optimize the backbone geometry of photovoltaic materials and improve power‐conversion‐efficiency (PCE) of...
Triply N‐Confused Hexaphyrins(1.1.1.1.1.0) Synthesized From N‐Confused Hexaphyrin(2.1.1.1.1.1): Aromaticity Modulation, Metal Coordination, and Photothermal Conversion
ABSTRACT Antiaromatic compounds exhibit intriguing structures, reactivity, and physicochemical properties. To address the challenge in developing stable antiarom...
The Bidentate Adsorption Mode of Re‐Ni Atomic Pairs Inducing the Ultralow Overpotential in CO <sub>2</sub> Electroreduction
ABSTRACT Developing highly efficient, selective, and low‐overpotential electrocatalysts for the electrochemical carbon dioxide reduction reaction (eCO...
Adsorption Energy Difference‐Driven Synthesis of Perovskite Single Crystals With Tailored Exposed Facets
ABSTRACT The precise synthesis of perovskite single crystals with tailored exposed facets is crucial for enhancing the performance of optoelectronic materials. However, the controlle...
Overlayer‐Engineered BiVO <sub>4</sub> Suppresses H <sub>2</sub> O <sub>2</sub> Decomposition to Enable Sustained Photocatalytic Production
ABSTRACT Inorganic semiconductor photocatalysts are highly promising for hydrogen peroxide (H 2 O 2...
A Programmable Luminescent Sensing Platform via Site‐Selective Modular Installation in Metal–Organic Frameworks
ABSTRACT Metal–organic frameworks (MOFs) have emerged as versatile platforms for structural design and engineering for targeting applications, particularly in luminescent sensing. MO...
Redirecting Reaction Pathway in Tandem Catalysis With Isolated Metal–Acid Architecture
ABSTRACT The rational design of metal‐acid bifunctional catalysts is critical for tandem catalysis. However, the precise control of intermediate formation and conversion remains chal...
Tri‐Acceptor Skeleton Balancing Ambipolar Mixed Ionic‐Electronic Transport in Organic Conductors
ABSTRACT Organic mixed ionic‐electronic conductors (OMIECs) are emerging materials for low‐power dissipation, high transconductance, and biocompatible semiconduc...
Interlayer Confinement Steers Peracetic Acid Activation Toward Nearly Exclusive Singlet Oxygen Generation
ABSTRACT Precisely controlling reaction pathway is vital for selective oxidation chemistry but remains challenging due to the complexity of oxidant–catalyst inte...