Angewandte Chemie International Edition
Articles in this Issue
Sustainable Pd‐Catalyzed Aminations “on <i>Dirty</i> Water”
ABSTRACT A new approach to Pd‐catalyzed C─N bond formation is disclosed based on observations from Nature, where its use of an “on water” phenomenon allows for v...
Environmental Identification of Novel Enzymes for Polyurethane and Polyamide Degradation
ABSTRACT Better enzymes are needed to develop sustainable methods to recycle plastics with C‐X heterobonds such as polyurethane (PUR) and nylon, for which no industrial‐scale solutio...
Light‐Controlled Modulation of 15‐Lipoxygenase‐1 Regulates Intestinal Inflammatory Signaling
ABSTRACT Photopharmacology offers powerful opportunities for the spatiotemporal control of biological processes, yet the rational design of photoswitchable enzym...
Modulating Surface Potential and Electron/Hole Overlap of Singlet Excited State in Asymmetry End‐Capped Dimeric Acceptors for Efficient and Stretchable Organic Solar Cells
ABSTRACT Back‐to‐back dimeric acceptors have attracted widespread attention for organic solar cells (OSCs) due to their exceptional stability and unique three‐di...
Kinetic Regulation of Anionic Redox Reaction Voltage by Metastable Over‐Lithiated Surface Shells Formation for High‐Energy‐Density Batteries
ABSTRACT Anionic redox reaction (ARR) has emerged as a pivotal mechanism to support next‐generation of high‐energy‐density batteries. While extensive efforts hav...
Crosslinking of Linear Polyimines Into Aminal‐Linked Porous Organic Polymers for C <sub>2</sub> Hydrocarbon/Methane Separation
ABSTRACT Hypercrosslinked polymers, a class of porous organic polymers (POPs), are constructed by crosslinking linear polymers or knitting small aromatic molecul...
Surface BO <sub>3</sub> Configuration in Li‐Rich Cathode Materials Enabling Highly‐Stable Anionic Redox Reactions
ABSTRACT Li‐rich Mn‐based layered oxides (LRMOs) are considered promising cathode candidates for next‐generation high‐energy‐density lithium batteries, owing to...
Interstitial Copper Doping and Thermally Activated Rattling in La <sub>3‐</sub> <i> <sub>x</sub> </i> Te <sub>4</sub> for Enhanced Thermoelectric Performance
ABSTRACT La 3‐ x Te 4...
Synergistic Anion‐Reinforced Solvation Chemistry and Cationic Electrostatic Shielding for Fast‐Charging Sodium‐Ion Full Batteries Over a Wide Temperature Range
ABSTRACT Sodium‐ion batteries (SIBs) capable of stable operation under fast‐charging conditions across a wide temperature range are of great significance for the...
Flame‐Retardant Quasi‐Solid‐State Electrolytes From Self‐Assembled Azolate Hybrid Frameworks for Highly Safe Lithium Batteries
ABSTRACT Achieving quasi‐solid‐state electrolytes (QSSEs) that simultaneously deliver fast ion transport and intrinsic thermal safety remains a central challenge...
Water‐Mediated SEI in Fluorinated Alkoxylborate Electrolytes for Long‐Cycling Calcium Metal Anodes
ABSTRACT The practical implementation of calcium metal anodes in rechargeable batteries is persistently hindered by surface passivation, which impedes Ca...
Tuning the Mechanical Properties of Crosslinked Copolymers via Sequence and Solvent‐Selective Swelling for Vat Photopolymerization
ABSTRACT Block copolymers (BCPs) offer distinct advantages for vat photopolymerization by enabling mechanically programmable network structures through microphas...
Electrochemically Triggered Supramolecular Polymerization Under Kinetic Control
ABSTRACT Stimuli‐responsive supramolecular polymerization with high precision is essential for developing adaptive materials with programmable kinetics and funct...
Force‐Locking DNA Hairpin Probes for High‐Throughput and Cumulative Detection of Intercellular Molecular Tensions
ABSTRACT Mechanical forces at cell‐cell junctions play essential roles in tissue organization, morphogenesis, and disease progression, yet their transient and low‐intensity nature ma...
Transition Metal‐Free Borata‐Alkene/Alkyne Metathesis Enables Access to Cyclopentenes
ABSTRACT Metathesis reactions are fundamental transformations in organic synthesis, enabling efficient reorganization of unsaturated bonds and underpinning broad applications in phar...
Bifluorinated Motif‐Tailored Hybrid Membranes for Ultra‐Permeable CO <sub>2</sub> Separation From Air Under High Humidity
ABSTRACT Membrane‐based direct air capture (m‐DAC) offers an energy‐ efficient route to mitigate rising atmospheric CO 2...
High‐Performance, Activation‐Free Magnesium‐Ion Batteries Enabled by Ionic Liquid Electrolyte Additive
ABSTRACT Magnesium‐ion batteries (MIBs), as a highly promising next‐generation energy storage technology, benefit from the high theoretical volumetric capacity (...
A Superhydrophobic Nanotrap Porous Organic Cage for Efficient Capture of SF <sub>6</sub> Under Dry and Humid Conditions
ABSTRACT Effective SF 6 capture and recovery are essential for reducing greenhouse gas emissions and promoting resource r...
Chemical Synthesis and Immunological Evaluation of <i>Escherichia coli</i> O29, <i>Shigella dysenteriae</i> Serotype 11, and <i>Proteus vulgaris</i> O12 O‐Antigen Oligosaccharides
ABSTRACT Escherichia coli ( E. coli ), Shigella dysenteriae (...
Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables <i>Remote</i> ‐Markovnikov Hydroamination of Alkenes
ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet regioselective remote C─N bond formation from simple alken...
Cooperative Redox Catalysis of N <sub>2</sub> O Decomposition by Short‐Range RhO <i> <sub>x</sub> </i> and CeO <i> <sub>x</sub> </i> Anchored to Co <sub>3</sub> O <sub>4</sub>
ABSTRACT Hybrid materials based upon mixed metal oxides provide an effective strategy to boost catalytic performance through redox‐induced interfacial engineerin...
A Platinum(IV) Metallo‐Stapling Approach to Tumor‐Specific Prodrugs for Targeted Chemo‐Immunometabolic Cancer Therapy
ABSTRACT The clinical utility of classical metallodrugs is limited by insufficient tumor selectivity and systemic toxicity. Platinum‐based chemotherapeutics, while foundational in on...
Photo‐Triggered, Fast, and Fluorogenic Thiophene‐Based Cycloalkynes for the Bioorthogonal Fluorescent Labeling of 1,3‐Dipole‐Tagged Molecules in No‐Wash Conditions
ABSTRACT Bioorthogonal reactions have revolutionized our way of performing chemistry in a highly complex biological environment. In particular, strain‐promoted 1...
Transient Boryl Assistance Enables Stereoselective Alkylation of Acyclic Tetrasubstituted Enolates
ABSTRACT The enantioselective construction of acyclic quaternary carbon stereocenters and vicinal quaternary/tertiary stereocenters represents two persistent cha...
Regulating the Adsorption Configuration of Intermediates to Construct C─N Bonds From CO <sub>2</sub> for High‐Efficiency <i>N</i> , <i>N</i> ‐Dimethylformamide Electrosynthesis
ABSTRACT N, N‐Dimethylformamide (DMF) is a widely used chemical reagent often described as a “universal solvent” due to its exceptional solvating capabilities. A...