Angewandte Chemie International Edition
Articles in this Issue
Targeted Near‐Infrared Photoacoustic Probes for Dual‐Channel Cartilage and Bone Imaging
ABSTRACT Simultaneous imaging of cartilage and bone with molecular specificity remains a significant unmet need in orthopedic research and intraoperative guidance. Here, we report th...
Janus Electronic State Ni Enable High‐Level CO‐Tolerance in Fuel Cells Toward Crude‐Hydrogen Feeds
ABSTRACT Maximizing the utilization efficiency of surface‐active atoms is essential for improving carbon monoxide (CO) tolerance of hydrogen oxidation reaction (...
π‐Bridge Modulation in Three‐Motif Covalent Organic Framework for Efficient H <sub>2</sub> O <sub>2</sub> Photosynthesis From Water and Air
ABSTRACT Rational integration of strong photosensitive moieties and multiple active sites into high performance photocatalysts is challenging due to uncontrollab...
Programming Dimensional Transitions in DNA Brick Crystals via Interfacial Connectivity
ABSTRACT The precise control of assembly dimensionality and macroscopic structural parameters remains a fundamental challenge in molecular self‐assembly. Here, w...
Pulsed Charging‐Induced Interfacial Stabilization Enables Highly Stable Iron Phosphate Electrode for Ultrafast Electrochemical Lithium Extraction
ABSTRACT Amid the soaring global demand for lithium, electrochemical lithium extraction using iron phosphate (FePO 4 ) el...
Interfacial Ru–C Coupling Harnesses Photoexcited Hot Electrons to Sustain Oxygen Cycling in Photothermal Methane Dry Reforming
ABSTRACT Methane dry reforming (DRM) remains challenged by the difficulty of simultaneously achieving high activity and long‐term stability under moderate‐temper...
Cation–Anion Redox Co‐Modulation: Unlocking the Potential of All‐Electrochem‐Active Sulfur‐Based Solid‐State Batteries
ABSTRACT The capacity utilization of all‐solid‐state sulfur cathodes reveals a significant disparity between material and electrode levels due to the high propor...
Chemo‐, Diastereo‐, and Enantioselective Radical Cyclization of Enals to Access Cyclopentanols Bearing an α‐Quaternary Center
ABSTRACT Controlling both chemo‐ and stereoselectivity in reactions of sterically demanding radicals remains a fundamental challenge in the construction of vicin...
Tailoring the Cu Local Microenvironment to Create Formate Conversion‐Desorption Equilibrium for Industrial Level Formaldehyde Electrooxidation
ABSTRACT Copper‐based electrocatalysts exhibit high initial activity for formaldehyde oxidation but suffer rapid deactivation under industrially relevant current...
Carrier‐Dynamics‐Regulated BiOI/Au/TiO <sub>2</sub> Z‐Scheme Photoanode for Selective Glycerol Photoelectrooxidation and Mass‐Transfer‐Enhanced Continuous‐Flow Operation
ABSTRACT Selective conversion of biomass‐derived glycerol into high‐value chemicals is challenged by poor selectivity and mass‐transfer limitations. Here, a BiOI...
Metal‐Dependent Kinetic Control in Cationic‐Anionic Synchronous Ring‐Opening Polymerization
ABSTRACT Synchronous polymerization that combines mechanistically orthogonal pathways within a single catalytic system offers an attractive route to well‐defined...
Stabilizing Dual‐Band Redox Process via Bidirectional Regulation Term in High‐Voltage Sodium Layered Oxide Cathodes
ABSTRACT Manganese‐based layered oxides represent a promising cathode candidate for sodium‐ion batteries due to their natural abundance and high theoretical capa...
Strong Modulation of Electronic States in IrO <sub>2</sub> by Interstitial Carbon for Highly Active Acidic Water Oxidation
ABSTRACT IrO 2 as the most stable electrocatalyst for acidic oxygen evolution reaction (OER) suffers from its low activit...
Secondary Site Ligand for Integrin <i>α</i> V <i>β</i> 3 Enables Targeted mRNA Delivery
ABSTRACT Poor perfusion and abnormal vasculature constrain direct drug delivery to solid tumors. Hence, targeting neighboring tumor endothelial cells via the upr...
Strain Engineering via W–O–Ru Interfacial Coupling to Suppress Lattice Oxygen Activation for Stable Acidic Water Electrolysis
ABSTRACT Developing highly active and durable acidic oxygen evolution reaction (OER) electrocatalysts remains a central challenge for proton‐exchange membrane wa...
Bromide‐Mediated Low‐Energy Ru <sup>IV</sup> ═O Pathway of Stable Water Oxidation
ABSTRACT Mimicking natural photosynthesis to split water into oxygen and hydrogen represents a promising pathway for transitioning from fossil fuels to a sustain...
Bisphosphane‐Stabilized Borylenes: Unlocking Borylene Transfer Reactivities
ABSTRACT The development of borylene‐transfer reactions—a powerful yet underdeveloped strategy for the efficient construction of boron‐containing compounds—has b...
Reprogramming the Fate of Stored Excitation Energy in Persistent Phosphors for Dark Photocatalysis
ABSTRACT Solar‐driven CO 2 reduction is fundamentally constrained by the intermittency of sunlight, resulting in a tempor...
Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media
ABSTRACT Electrocatalytic glycerol oxidation represents a sustainable route for glycerol valorization, yet high selectivity toward glyceric acid (GLA) remains ch...
Formation of Gallium Monofluoride in the Coordination Sphere of Nickel
ABSTRACT Monovalent gallium halides are intrinsically unstable compounds at room temperature and can only be generated in the gas phase at temperatures of about...
Novel Carborane Based Metal Organic Framework for Record Electronic Specialty Gas C <sub>2</sub> F <sub>6</sub> Purification via Molecular Sieving
ABSTRACT The production of high‐purity perfluoroethane (C 2 F 6 ), an essential e...
Multi‐Stimuli‐Responsive Mechanoluminescent Manganese Halide Toward External‐Light‐Free Photochemistry
ABSTRACT Solvent‐free mechanochemical photosynthesis offers significant advantages in enhancing reaction efficiency and minimizing environmental impact. However,...
Building Crosslinking Network via Catalytic Furan‐to‐Pyrrole Conversion
ABSTRACT To address the limitations of conventional furan resins, which rely on furfural derivatives for synthesis and exhibit constrained performance, this work...
Defining Rational Photoelectron Routing for Targeted Intracellular Energy Transfer
ABSTRACT Microbial artificial photosynthesis offers a promising strategy for light‐driven biomanufacturing, yet its efficiency remains limited by the non‐selecti...
Dual Regulation of Molecular Orbital and Interfacial Water on Nickel Phthalocyanine for Highly Selective H <sub>2</sub> O <sub>2</sub> Synthesis
ABSTRACT Hydrogen peroxide (H 2 O 2 ) electrosynthesis via the two‐electron oxyge...