Angewandte Chemie International Edition
Articles in this Issue
Recent Advances in Two‐Photon‐Activatable Metal Complexes for Photodynamic Therapy
ABSTRACT Photodynamic therapy (PDT) is a non‐invasive modality for cancer treatment, but its broader application remains constrained by two central limitations, that is, insufficient...
In Situ Quantification of Hydrogen Radicals Disentangles Direct and Hydrogen‐Radical‐Mediated Pathways in Green Ammonia Electrosynthesis From Nitrate
ABSTRACT The electrochemical reduction of nitrate (ERN) to ammonia (NH 3 ) has attracted increasing attention as a sustai...
Asymmetric Zn─N <sub>2</sub> O‐Coordinated Hydrogen‐Bonded Organic Frameworks for Electrochemical Hydrogen Peroxide Production and Wastewater Purification
ABSTRACT Hydrogen‐bonded organic frameworks (HOF) demonstrate significant potential in the electrocatalytic synthesis of hydrogen peroxide. However, their practi...
Photocatalytic Cascade Nitrogen Fixation for Selective Purification of Methane‐Rich Coal‐Bed Gas Over a Bimetallic MOF
ABSTRACT CH 4 ‐rich coal‐bed methane (CBM) is often contaminated with N 2 , but t...
Cobalt Nanoparticles Confined in Defective Carbon Matrices for Robust Intermittent CO <sub>2</sub> Methanation
ABSTRACT The development of robust catalysts for CO 2 methanation under intermittent operating conditions is key to harne...
Covalent Confinement of AuCu Nanoclusters in Metal‐Organic Frameworks for Photocatalytic CO <sub>2</sub> Reduction to C <sub>2</sub> Hydrocarbons
ABSTRACT Bimetallic alloy nanoclusters provide an ideal platform for photocatalytic CO 2 reduction owing to their synergi...
Fundamentals, Measurement and Regulation of the Conductance of Single Molecule Junctions
ABSTRACT The miniaturization of conventional silicon‐based devices is one of the pinnacles of achievement of the 20 th ce...
Supramolecular Chloride Reservoirs Enable Homogeneous Halide Distribution and Near‐Unity Blue Luminescence in Cs <sub>4</sub> PbBr <sub>6</sub> ‐CsPbBr <sub>3</sub> Heterostructured Perovskites
ABSTRACT Blue‐emitting metal halide perovskites remain difficult to stabilize because mixed‐halide compositions suffer from halide heterogeneity, defect formatio...
Layered Copper‐Anthraquinone Coordination Polymer Cathode Leveraging Dual‐Redox Sites and Facilitated Ion Diffusion for High‐Performance Lithium‐Ion Batteries
ABSTRACT Organic electrode materials often face challenges of low electronic conductivity and high solubility in electrolytes. To address this, we synthesized Cu...
Generation of the Camptothecin Scaffold by a Flavin‐Catalyzed Photooxidative Skeletal Reorganization
ABSTRACT The plant alkaloid camptothecin is a high‐value precursor for the semi‐synthesis of multiple anticancer drugs. The key transformation during its biosynt...
Hydrophobic Promoter‐Enhanced Tandem Catalysis for Alkene Epoxidation With H <sub>2</sub> and O <sub>2</sub>
ABSTRACT The efficiency of tandem catalysis is fundamentally limited by the transport of transient intermediates. In the direct epoxidation of alkenes with H...
Asymmetric Ionic Liquid Modulated Anion‐Reinforced Electric Double Layer for Advanced Durable Lithium Batteries
ABSTRACT The electric double layer (EDL) governs local electrolyte enrichment and reduction pathways, thereby directing the nucleation and evolution of solid ele...
A Fixed‐Charge Interphase Synchronizes Ion Transport to Suppress Space‐Charge‐Driven Inefficiency Under Nanoliter Confinement
ABSTRACT Ion transport at electrified interfaces is conventionally described by the redistribution of mobile ions to preserve local electroneutrality. Under extreme electrolyte confi...
Tandem Catalysis Overcomes the Rate‐Determining Sulfur Conversion Cascade in Na─S Batteries
ABSTRACT Room‐temperature sodium–sulfur (RT Na─S) batteries offer high theoretical energy density and low cost, yet their practical performance is fundamentally...
Transient Activation Windows Program Adaptive Photochemical Responses
ABSTRACT Biological systems regulate photochemical functions through transient activation states that determine when a stimulus can produce a response. Inspired by this principle, we...
Pulsed‐Laser Ablation for the Synthesis of High‐Entropy Alloy Aerogels Toward H <sub>2</sub> O <sub>2</sub> Production and Water Decolorization
ABSTRACT Electrosynthesis of H 2 O 2 is attractive for its environmental sustaina...
Efficient Syngas Photoproduction Enabled by Electronic Engineering of Co‐Immobilized Imine COFs
ABSTRACT Heterogeneous photocatalytic CO 2 reduction provides a promising route for syngas production. However, high reac...
One‐Pot CO <sub>2</sub> Hydrogenation Coupled With In Situ Esterification for Polyester Monomers Production Over Single‐Atom Cu <sup>δ+</sup> ‐Doped 1.8 Nm T‐ZrO <sub>2</sub>
ABSTRACT Here, we report a one‐pot tandem catalytic system that integrates CO 2 hydrogenation to CH 3...
Attractive Ni <sup>…</sup> O Interactions Enable Non‐Alternating Ethylene‐Carbon Monoxide Copolymerization
ABSTRACT In‐chain functional groups can reduce the environmental impact of polyethylene waste and enhance its recyclability. A significant advance was the realiz...
Multiple Strong Ion–Dipole Interactions in Hierarchical Porous Polymer/Covalent Organic Framework Electrolytes Accelerating Stable and Efficient Ion Transport
ABSTRACT The development of solid‐state lithium metal batteries (SSLMBs) is severely restricted by the inherent drawbacks of conventional solid electrolytes, inc...
Unbiased Structure Prediction of Sophisticated Cage Structures
ABSTRACT Cage structure prediction has made significant strides by generating structures based on what the community has seen before. However, to computationally...
Electronic‐Structure‐Directed Pore Engineering in Metal–Organic Frameworks for Molecular Sieving of C <sub>3</sub> F <sub>6</sub> /C <sub>3</sub> F <sub>8</sub>
ABSTRACT Trace removal of hexafluoropropylene (C 3 F 6 ) from octafluoropropane (...
Cross‐Interface Quasi‐Tandem Catalysis Over Amorphous Oxide‐Metal Junctions Steers CO <sub>2</sub> Electroreduction Toward C <sub>3</sub> Products
ABSTRACT The selective electroreduction of CO 2 to n ‐propanol is fundamentally c...
The Role of Zn–Hf Site Proximity and Oxygen Vacancies for Methanol Formation Over ZnHfO <i> <sub>x</sub> </i> Catalysts Under CO <sub>2</sub> Hydrogenation Conditions
ABSTRACT Mixed metal oxides, such as ZnZrO x , have attracted considerable in...
A Novel Class of “Super‐Strained” Spiro Heterocycles: Gateway to 1‐Azaspiro[3.3]heptane Derivatives, and Biological Validation
ABSTRACT Strained spiro heterocycles have gained popularity in medicinal chemistry due to their potential to act as conformationally rigid non‐classical three‐dimensional bioisostere...