Angewandte Chemie International Edition
Articles in this Issue
Adsorption‐Mediated Sodium Compensation for Hard Carbon Anodes Enabled by Soft‐Contact Presodiation
ABSTRACT Hard carbon (HC) anode in sodium‐ion batteries suffer from low initial Coulombic efficiency and irreversible capacity loss, limiting practical energy de...
An Adaptive Ionic Sieve: Flexible Hydrogen‐Bonded Organic Frameworks Decouple the Trade‐Off Between Zn Ions Desolvation and Mass Transfer
ABSTRACT Efficient ion desolvation and rapid mass transport are crucial yet often competing requirements for stabilizing Zn anodes in aqueous Zn‐ion batteries. T...
Sustainable Electrochemical Valorization of Sulfite in Industrial Wastewater Into Sulfonate‐Based Molecules
ABSTRACT Sulfite (SO 3 2− ), abundant in industrial wastewater, poses environmental challenges due to...
Metal–Organic Framework‐Gated Biocatalysis Enables Triggered Depolymerization of Melt‐Processed Polyesters
ABSTRACT Controlling biocatalytic activity in melt‐processed polymers is a central challenge for triggered depolymerization, because enzymes deactivate at melt‐e...
Nickel‐Catalyzed 1,2‐Arylalkenylation of Unactivated Alkenes Enabled by a Native Hydroxy Group
ABSTRACT Transition‐metal‐catalyzed dicarbofunctionalization of alkenes represents a powerful strategy for building molecular complexity in a single step. Here we report an unprecede...
Precision Switching and Coupled Motion in a [3]Rotaxane Molecular Machine
ABSTRACT We report the synthesis and the characterization of a multicomponent molecular machine based on a [3]rotaxane architecture. The system is composed by tw...
Covalent Borane‐Thiourea Organocatalyst for Stereoselective Ring‐Opening Polymerization
ABSTRACT While the chemistry of ring‐opening polymerization has advanced significantly to alleviate the escalating plastic waste crisis, highly selective and eff...
Pathway Controlled Phase Separation of Minimal Building Blocks Utilizing a Dissociative Chemical Transformation
ABSTRACT Metastable states are utilized by biology to power the construction of large and motile macromolecules and also to realize out‐of‐equilibrium phase separation. Energy transd...
Mechanically Interlocked Indigo Photoswitches
ABSTRACT Photoswitches provide the opportunity to remotely and precisely control matter on the nanoscopic scale. For many materials and biological applications, photoswitches with lo...
Enabling Moisture and Interfacial Stability in Sulfide Solid Electrolytes via a Processable Organic Coating Strategy for High‐Voltage All‐Solid‐State Batteries
ABSTRACT Sulfide solid electrolytes (SEs) are excellent candidates for solid‐state batteries (SSBs), but their extreme sensitivity to moisture and lack of oxidat...
Self‐Cleaning Solar Evaporation Facilitating Water Electrolysis for Hydrogen Generation From Seawater
ABSTRACT Clean energy demands and zero‐carbon commitments have stimulated the desire for stable seawater electrolysis, yet device corrosion and catalyst deactiva...
Chiral Spiro‐Scaffolded C(sp <sup>3</sup> ),P‐Chelated Iridacycles: Direct Asymmetric Hydrogenation of β,β‐Disubstituted Acrylate Salts
ABSTRACT Rational design of chiral ligands with precisely tailored steric and electronic properties is pivotal to advancing asymmetric transition‐metal catalysis...
Oxygen Bridge‐Induced Spin‐State Engineering Enables Solvation‐Barrier‐Free Sulfur Redox Kinetics in Lithium‐Sulfur Batteries
ABSTRACT Lithium‐sulfur (Li‐S) batteries are attractive for next‐generation energy storage, yet practical deployment is impeded by the lithium polysulfides (LiPS...
Breaking the Linear Scaling Relationship: Bioinspired Electronic Coupling in S‐Bridged Fe−Fe Dual Sites for Efficient Oxygen Reduction
ABSTRACT Dual‐atom catalysts (DACs) provide a promising approach to overcome the linear scaling relationship that limits the activity of single‐atom catalysts fo...
A Deep‐Red Emissive Cage‐in‐Rings Complex for Lysosome Imaging
ABSTRACT Bioimaging technology is a fundamental platform for visualizing biological processes and guiding clinical interventions. Consequently, developing effect...
Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles
ABSTRACT We report the synthesis and characterization of a series: UOS, UOSe and β‐US 2 , the first examples of uranium‐c...
Confined Cationic Covalent Organic Cages Enable Oxidant‐Free Hofmann−Löffler−Freytag/Cyclization Sequences
ABSTRACT Developing confined supramolecular environments capable of regulating radical cascade processes with high site selectivity remains a longstanding challe...
Electrochemical Switch‐On of Nonlinear Optical Response in a Nitro‐Functionalized Arylimido‐Polyoxometalate
ABSTRACT Electrochemical switch‐on of second‐order non‐linear optical (NLO) responses ( β ) has been demonstrated in a po...
Pd/C‐Catalyzed Hydrogenation of CF <sub>3</sub> ‐, CF <sub>2</sub> H‐, and CF <sub>2</sub> CO <sub>2</sub> Et‐containing Pyridines: A Robust Method for Highly Functionalized containing Piperidines
ABSTRACT A robust method for the hydrogenation of various pyridines substituted by CF 3 , CF 2...
Engineering Orbital Hybridization via Coordination and Charging Modulation Toward Efficient and Stable Fe Single‐Atom Catalysts for Superior Oxygen Reduction
ABSTRACT Strategic microenvironment engineering of single‐atom catalysts offers a method for simultaneously enhancing oxygen reduction reaction (ORR) activity an...
Functional and Network PHAs via Stereoselective Polymerization and Tailored Post‐Transformation
ABSTRACT Incorporation of functional groups into poly(3‐hydroxyalkanoate)s (PHAs) is an important strategy to tailor their properties for specific applications,...
Ion‐Driving Polymer Entanglement for Dynamic Organic Phosphorescence
ABSTRACT The development of dynamic organic phosphorescent polymers is often limited by the challenge of exerting precise and reversible control over their conde...
Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using <i>Operando</i> Luminescence Thermometry
ABSTRACT Oxidative coupling of methane (OCM) into ethylene is a very promising process for the valorization of methane. However, the high operating temperatures,...
Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals
ABSTRACT Solid‐state phase transitions provide a powerful platform for translating subtle molecular‐level interactions into macroscopic functional responses; how...
Sulfur Vacancy‐Enriched Cu <sub>4</sub> SnS <sub>4−x</sub> Nanosheets Enable Synergistic Cuproptosis, Photothermoelectric Catalytic and Immunotherapy
ABSTRACT Photothermoelectric catalytic therapy (PTECT) faces challenges like restricted thermoelectric activity and tumor recurrence. In this study, we introduce...