Angewandte Chemie International Edition
Articles in this Issue
Charge‐Transfer Exciton Flows: Red Luminescent Zn <sub>8</sub> D <sub>14</sub> A <sub>4</sub> Nanotubes
ABSTRACT Precise arrangement of multi‐electron‐donor (D) and acceptor (A) molecules can drive directional flows of photo‐generated molecular excitons and charge‐...
Isolation and Reactivity of a Stannabismuthene
ABSTRACT Multiple‐bonded compounds involving heavy group 14 elements (Si, Ge, Sn, Pb) and bismuth (Bi), as heavier analogs of imines, have not previously been is...
Planar Chiral Carbazole‐Naphthalene Bisimide Hetero‐Cyclophane for Circularly Polarized Delayed Fluorescence
ABSTRACT Chiral organic chromophores with circularly polarized thermally activated delayed fluorescence (CP–TADF) provide great prospects as circularly polarized...
Precatalyst Engineering Directs Reconstruction Into Coupled Defective Sites for Selective CO <sub>2</sub> ‑to‑Formate Electroreduction
ABSTRACT Bismuth‐based materials are promising for formate production from CO 2 electroreduction, yet their rational desi...
Mechanism‐Guided, Data‐Driven Discovery of a Dinuclear Gold Catalyst for Promoting Oxidative Addition
ABSTRACT Gold catalysis is frequently constrained by the limited accessibility of Au(I)/Au(III) redox pathways, particularly for the direct oxidative addition (OA) of aryl halides. H...
Discovery of a Robust Single‐Atom Ruthenium Emission Control Catalyst
ABSTRACT Herein, we discover a robust emission control catalyst featuring Ru single‐atom sites even undergoing thermal oxidative aging at 850°C in a 10%H...
Anthraquinone‐Engineered Thiophene‐Based Nanotube‐Like Porous Aromatic Framework as a Robust and Efficient Bifunctional Photocatalyst for C─H Cyanation of Tertiary Amines and Hydrogen Peroxide Generation
ABSTRACT The development of stable organic semiconductor photocatalysts—those capable of withstanding harsh conditions while maintaining high activity—remains a...
A Self‐Monitoring Single‐Atom Copper Nanocapsule for Cascade‐Responsive Tumor Cuproptosis Therapy
ABSTRACT Cuproptosis represents a potent anticancer mechanism, yet its translation is hampered by the scarcity of tumor‐selective and efficient copper ion modulators. Herein, we deve...
Incorporation of Engineered Cu <sup>0</sup> /Cu <sup>+</sup> Interfaces in Metal‐Organic Frameworks for Boosting CO <sub>2</sub> Hydrogenation to Methanol
ABSTRACT The Cu‐based materials are an important category of catalysts for CO 2 hydrogenation to methanol, in which Cu...
An in Situ Deposited Covalent Triazine Framework Photocathode for Electric Bias‐Free Solar‐to‐Hydrogen Peroxide Conversion in a Photoelectrochemical Cell
ABSTRACT Innovative technology for sustainable hydrogen peroxide (H 2 O 2 ) produ...
A General and Scalable Chiral Surrogate Rotaxane Strategy for Highly Enantioenriched Mechanically Planar Chiral Rotaxanes
ABSTRACT We report a general and modular chiral surrogate rotaxane (CSR) strategy for the synthesis of mechanically planar chiral rotaxanes (MPCRs) of high optic...
Regioisomer‐Dependent Supramolecular Assembly of Coumarin Derivatives for Wavelength‐Dependent Blue and Near‐Infrared Circularly Polarized Luminescence
ABSTRACT Supramolecular assemblies exhibiting circularly polarized luminescence (CPL) are attractive candidates for advanced photonic and optoelectronic materials. However, precise r...
Synthesis and One‐Electron Reduction of Donor‐Acceptor‐Stabilized Si <sup>II</sup> –E <sup>II</sup> –Si <sup>II</sup> Trimetallylenes (E = Ge, Sn, Pb)
ABSTRACT Herein, we report isolable donor–acceptor‐stabilized Si II –E II –Si...
A Domino‐Synthesized Dicoordinate Copper(I) Bis‐imidazopyridine Complex Triggering Cuproptosis/Ferroptosis for Enhanced Cancer Immunotherapy
ABSTRACT Novel synthetic methods offer significant potential to accelerate drug development, yet there remains a largely unexplored area for efficiently synthesi...
Reprogramming Photosensitization Mechanisms for Hypoxic Tumor Therapy via Organic Photovoltaic‐Inspired Heterojunctions
ABSTRACT Conventional Type II photodynamic therapy (PDT) is severely compromised by tumor hypoxia. Drawing inspiration from the charge‐separation principles of o...
Green Synthesis of Ultrathin MWW Zeolites With Tunable Al‐T Sites Using Nitrogen‐Free Secondary OSDAs for Catalytic Cracking
ABSTRACT The direct synthesis of ultrathin MWW zeolites with precisely controllable aluminum location represents a significant challenge. Herein, we report a sus...
Stabilizing Ru Atomic Clusters and Activating Interfacial Water Structure via Bridged <i>p</i> ‐Block In‐N <sub>3</sub> O <sub>1</sub> Single Sites for High‐Performance Alkaline Fuel Cells
ABSTRACT Ru atomic clusters (AC) are promising cost‐effective platinum‐group‐metal anode catalysts for the alkaline hydrogen oxidation reaction (HOR) in anion‐ex...
Enantioselective Radical Cascade Cyclization to Axially Chiral Medium‐Sized Lactones
ABSTRACT We report a synergistic photoredox/copper‐catalyzed radical cascade cyclization for the enantioselective synthesis of axially chiral medium‐sized lactones. Compared with con...
Mirror‐Symmetric Organic Two‐Dimensional Crystals for Alternative Photon Transport Pathways
ABSTRACT Two‐dimensional (2D) organic crystals have attracted significant attention due to their highly ordered structures and exceptional optoelectronic properties. However, the con...
Intramolecularly Synergic Catalysis Enables Efficient Closed‐Loop Recycling of Polyesters and Polycarbonates
ABSTRACT Efficient and selective chemical recycling of commercial plastics back to monomers is a pivotal strategy for achieving a circular plastics economy. Howe...
Covalently PD‐L1 Anchoring Drives Bispecific Nanostructure Assembly for Spatial Control of T Cell Recruitment and Activation
ABSTRACT Immune checkpoint blockades have shown great potential in cancer therapy. However, achieving efficient recruitment and activation of T cells while blocking immune suppressio...
HBr‐Regulated Smart 2D Copper‐Organic Framework for Highly Efficient and Selective Photocatalytic Oxidation
ABSTRACT Smart covalent organic frameworks capable of modulating photocatalytic properties responsive to external stimuli represent next generation of emerging c...
High‐Redox‐Potential p‐Type Covalent Organic Frameworks With Abundant Active Sites for High‐Voltage and Long‐Life Lithium‐Ion Battery Cathodes
ABSTRACT Covalent organic frameworks (COFs) hold great promise for advancing lithium‐ion battery (LIB) cathode performance and overcoming resource bottlenecks du...
Facile Synthesis of α,ω‐Dihydroxy Telechelic Macromonomers From Ethylene and α‐Olefins for Recyclable Alternating Block Copolymers
ABSTRACT AA‐type α,ω‐dihydroxy telechelic polyolefins ( t POs) are key macromonomers for the step‐growth construction of...
Chemical Design Principles for Managing the Capacity–Stability Trade‐Off in High‐Voltage Sodium Layered Cathodes
ABSTRACT High‐voltage layered transition‐metal (TM) oxides are attractive for sustainable sodium‐ion battery (SIB) cathodes, yet their development is constrained...