Angewandte Chemie International Edition
Articles in this Issue
Metabolic Labeling and Visualization of Isoprenoids Using Alkyne‐Modified DMAPP Analogs in <i>Bacillus subtilis</i>
ABSTRACT Isoprenoids are a chemically and functionally diverse class of metabolites that underlie essential bacterial physiology including respiration and cell e...
Interstellar Ice Chemistry Yields Elusive Sulfinothioic Acid (HS(O)SH)
ABSTRACT Low‐oxidation‐state sulfur oxyacids are key yet experimentally elusive intermediates in interstellar sulfur chemistry; even the simplest member, sulfino...
An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene
ABSTRACT Despite great advances in the chemistry of low‐valent silicon species, a silicon/sulfur analogue of an acyl carbene, namely a silathioacyl silylene, has...
Nitrogen‐Mediated Orbital‐Compatible π‐Extension: Balancing Excited‐State Components and Suppressing Vibrational Broadening Toward Redshifted Narrowband MR‐TADF Emitters
ABSTRACT BN‐based multi‐resonance thermally activated delayed fluorescence (MR‐TADF) emitters face a critical bottleneck in achieving redshifted narrowband emiss...
Reprogramming Ion‐Transport Dimensionality via Crystal‐Channel Engineering to Stabilize Zinc Anodes
ABSTRACT Unstable zinc (Zn) deposition in aqueous zinc‐ion batteries is intrinsically linked to the interfacial confinement of Zn 2+...
Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation
ABSTRACT We report a unified method for the synthesis of α‐polyhalomethyl amines from alkenes and alkynes, enabled by readily available hemiaminal reagents. This...
Engineering an Electrode–Electrolyte Interphase for Ultrastable Aqueous Aluminium–Air Battery
ABSTRACT Aluminium–air battery (Al–air battery) stands at forefront of next‐generation energy storage technologies; however, their practical implementation is cr...
Selective Photocatalytic CO <sub>2</sub> Reduction via Enhanced CO <sub>2</sub> Adsorption and Activation Over Co‐Salen Functionalized Zr‐MOF Catalyst
ABSTRACT Achieving highly selective production from photocatalytic CO 2 reduction in aqueous systems remains a major chal...
Direct Regioselective <i>para</i> ‐Fluorination via I(I)/I(III) Catalysis
ABSTRACT Fluorine scanning is an expansive strategy to refine the physicochemical profile of clinically important small molecule drugs. Of the possible regioisom...
Coupled Fe <sub>3</sub> O <sub>4</sub> ‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation
ABSTRACT Fe–N–C single‐atom catalysts (SACs) can deliver high activity for catalyzing the oxygen reduction reaction (ORR) in alkaline conditions. However, the sl...
Molecular‐Extrusion‐Driven Halogen Homogenization for Efficient Perovskite‐Silicon Tandem Solar Cells
ABSTRACT Phase segregation is an inevitable phenomenon in wide‐bandgap perovskites, triggering nonradiative recombination and degrading device performance. Herei...
Genetically Encoded Lysine‐Selective Photocyclization Enables Phage Display Selection of Cyclic Peptide Binders
ABSTRACT Genetically encoded macrocyclization strategies have expanded the cyclic peptide chemical space accessible to phage display but remain constrained by re...
A Multi‐Stimuli Transformational Network of Benzil‐Based Pd(II) Assemblies
ABSTRACT Achieving precise control over supramolecular topology and nuclearity in coordination‐driven self‐assemblies through integration of multiple stimuli rem...
In Silicon Deciphering Atomic‐Scale Structural Units in Peptide Glass
ABSTRACT Peptide glasses are an emerging class of biofunctional amorphous materials, but their atomic‐level structure has remained elusive. Here, we resolve the three‐dimensional (3D...
First Evidence for Ozonido‐TMC Complexes of Iron and Cobalt
ABSTRACT We present compelling evidence for the first Fe‐ and Co‐ozonido complexes: [(D 12 ‐TMC)Fe II...
Manipulating Interfacial Water Molecules via Eutectic‐Polymer Dual‐Network for Stable Electrochromic Devices
ABSTRACT Aqueous Zn‐WO 3 electrochromic devices (ZWEDs) represent a promising frontier in energy‐efficient electrochromic...
Subcellular Tandem‐Activated Signal Amplification for Spatially Precise Molecular Imaging in Mitochondria
ABSTRACT Despite significant advances in DNA‐based signal amplification strategies for sensitive molecular imaging in live cells, achieving subcellular resolution remains challenging...
Iminodiacetate Chelated Zinc Complex Electrolyte Enables High‐Voltage and Long‐Life Zinc‐Based Flow Batteries
ABSTRACT Conventionally, lowering the Zn plating/stripping potential relies on strongly alkaline electrolytes that convert Zn 2+...
A Quantitative Electrostatic Potential Descriptor Enables Deep Learning‐Accelerated Discovery of High‐Performance Lithium‐Ion Battery Electrolytes
ABSTRACT Rational electrolyte design for high‐energy‐density lithium‐ion batteries (LIBs) urgently demands precise and quantitative molecular descriptors of solv...
Electropolymerized Donor–Acceptor Cathodes for Photoresponsive Li‐Dual‐Ion Batteries
ABSTRACT As a novel energy storage method, photo‐assisted rechargeable batteries offer an effective solution to numerous issues currently plaguing organic lithiu...
Kai S. Exner
A Cellulose‐Derived Polymer Additive for Stabilizing Thick Cathodes in All‐Solid‐State Batteries
ABSTRACT All‐solid‐state batteries (ASSBs) offer enhanced safety and energy density over conventional lithium‐ion batteries. However, achieving high active mater...
Tetraborylated Multiple Resonance Emitter Incorporating B─O Bond‐Embedded π‐Extension for Ultra‐Narrowband and High‐Efficiency Blue Devices
ABSTRACT Ultra‐narrowband multiple resonance (MR) thermally activated delayed fluorescence (MR‐TADF) emitters are crucial for next‐generation ultra‐high‐definiti...
Toward the Synthesis of Pestalustaine A: Structural Revision and Formation of Original Strained Tricyclic Architectures
ABSTRACT We report our quest toward the total synthesis of the reported structure of the sesquiterpene pestalustaine A and its unprecedented tricyclic skeleton....
Light‐Driven Charge Redistribution of Pt Cluster/CeO <sub>2</sub> Realizing Dual‐Path Synergistic Catalysis for Low‐Temperature Reverse Water‐Gas Shift
ABSTRACT Solar‐driven low‐temperature reverse water‐gas shift offers a sustainable route for CO 2 conversion yet suffers...