Angewandte Chemie International Edition
Articles in this Issue
Spatially Coupled Cl <sub>2</sub> Confinement and Activation at Curved Ni Single‐Atom Sites for Highly Reversible Li–Cl <sub>2</sub> Batteries
ABSTRACT Leveraging the high‐potential Cl 2 /LiCl redox couple (∼3.6 V), rechargeable Li‐Cl 2...
Na–Fe–P Stoichiometry‐Driven Heterostructure Design With a P <sub>2</sub> O <sub>7</sub> ‐Rich Buffering Phase for Stable NASICON‐Type Sodium‐Ion Cathodes
ABSTRACT Na 4 Fe 3 (PO 4 )...
Anion‐Managing Biomimetic Electrolyte Based on Fluorinated COF Recognition and Hyperbranched Polyamidoamine Capture for Practical Lithium–Metal Batteries
ABSTRACT Solid polymer electrolytes (SPEs) hold great promise for next‐generation high‐safety lithium batteries, yet their development is fundamentally constrain...
Enthalpy‐Entropy Modulation in Electrolyte Stabilizes 4.8 V‐Class Li‐Rich Mn‐Based Cathodes
ABSTRACT Lithium‐rich manganese‐based (LRM) cathode materials are promising for high‐energy‐density batteries due to their high specific capacity. However, their...
Low‐Energy Photons in Radical Chemistry: From Deep‐Red to Near‐Infrared Radical Generation for Organic Synthesis
ABSTRACT Highly reactive radical intermediates enable bond formations that are often inaccessible through conventional ionic processes. Visible‐light irradiation has emerged as a mil...
Neutral Borate Buffer Activates Diazo for Rapid Protein Labeling
ABSTRACT Diazo, a carbene precursor, offers an effective chemistry for bioorthogonal labeling upon activation by acids, metals, and/or photo‐illumination. Here, we report neutral bor...
The Jekyll and Hyde Nature of Tetrazoles in Polymer Science: From Intrinsic Electronic Duality to Programmable Macromolecular Function
ABSTRACT Nature encodes stability and responsiveness within single‐molecule frameworks, creating systems that remain structurally persistent while retaining access to activated funct...
Flipped Spin‐State Resists Cobalt Poisoning for the Durable Electrocatalytic Deuteration of <i>N</i> ‐Heterocyclic Compounds
ABSTRACT Electrocatalytic deuteration represents a sustainable method for synthesizing deuterated N ‐heterocycles, which...
Orchestrating Excited‐State Energy Flow in Benzobisthiazole Covalent Organic Frameworks for Solar Water Evaporation and H <sub>2</sub> O <sub>2</sub> Production
ABSTRACT The competing pathways of photothermal conversion and photocatalytic H 2 O 2...
Molecular Tailoring of Self‐Assembled Monolayers Derived From Asymmetric Benzothienoindole for Efficient and Stable Inverted Perovskite Solar Cells and Modules
ABSTRACT Self‐assembled monolayers (SAMs) have emerged as efficient hole‐transporting materials for inverted perovskite solar cells (PSCs). However, the synergis...
Boron Cluster‐Based X‐Ray Scintillators for Highly Efficient Radioluminescence
ABSTRACT Organic scintillators represent a promising alternative to conventional inorganic scintillators; however, their practical applications are severely hamp...
In Silico to In Cerebro—Development of the Orexin Receptor Antagonist “Photorexant” for Photomodulation In Vitro and in Mouse Brains
ABSTRACT In this study, we report the first photoswitchable small molecule dual ligands for the orexin receptor subtypes 1 (OX1R) and 2 (OX2R) as molecular tools...
Sulfone Activation Triggered by Iodide Anion for Photoinduced Fluoroalkylations
ABSTRACT Radical fluoroalkylation via electron donor–acceptor (EDA) complex photochemistry stands out as a particularly attractive approach, owing to its mild conditions and the abse...
Silicon‐Bridged Homocyclopentadienides: Metal‐Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes
ABSTRACT In this study, we report the aromatic C─C bond cleavage of cyclopentadienide by transient imino(metallophosphino)silylenes through the reaction of silyl...
Mechanistically Guided Combinatorial Coding Based on Strand Displacement Probes for Multiplex Pathogen Variant Discrimination
ABSTRACT Accurate and scalable discrimination of closely related genetic variants at single‐nucleotide resolution remains challenge in molecular diagnostics, par...
Multi‐Macrocyclic Nanohoops Bearing Carbazole‐Embedded Cycloparaphenylenes as Geometry‐Adaptive Hosts Toward Fullerenes
ABSTRACT Curved conjugated molecules with strained non‐planar geometries show unique properties valuable for supramolecular chemistry and optoelectronics, but th...
Direct Cl─Cl Coupling Over Atomically Dispersed Ir <sub>2</sub> Pairs for Efficient Chlorine Electrosynthesis
ABSTRACT Chlorine evolution reaction underpins the chlor‐alkali industry, yet its conventional dimensionally stable anodes (DSAs) suffer from low noble‐metal uti...
Applying Glycerol Triacetate as a Multi‐Hydrogen‐Bond Acceptor Co‐solvent to Realize Ultra‐Wide Temperature Zn Metal Batteries
ABSTRACT Although aqueous Zn metal batteries (ZMBs) possess high‐safety and low‐cost, their practical application is hindered by inferior performances at extreme...
Selective CO <sub>2</sub> ‐to‐CH <sub>4</sub> Photocatalytic Reduction via Spin‐Modulation in a Metal─Carbon‐Bonded MOF
ABSTRACT The spin modulation of the electronic structure of photocatalysts offers a promising strategy to address selectivity challenges in photocatalysis. Herei...
A Dual‐Color Two‐Photon‐Active Cavitand for Guest‐Responsive Sensing of Benzene and Pyridine Vapors
ABSTRACT Integrating precise molecular recognition with nonlinear optical functionality represents an attractive yet rarely realized strategy for supramolecular...
Flexible Amorphous Metal–Organic Framework Membranes With Local Order for Gas Separations
ABSTRACT Metal–organic framework (MOF) membranes show immense promise for energy‐efficient gas separations, yet their intrinsic brittleness has precluded their p...
Highly Enantio‐ and Diastereoselective Synthesis of Tetrahydrofuran Frameworks via Chiral Lewis Acid‐Catalyzed Formal [3+2] Cycloaddition of Allylsilanes
ABSTRACT A formal [3+2] cycloaddition via cyclization/1,2‐hydride shift initiated by nucleophilic attack of allylsilanes has been developed for the enantioselect...
Stabilizing Indeno[1,2‐ <i>a</i> ]Fluorene: The Only Ferromagnetic Diradical of Indenofluorene Isomers
ABSTRACT Among five indenofluorene regioisomers, only indeno[1,2‐ a ]fluorene is predicted to be a triplet diradical but...
An Axial Chlorine Spin‐Collar on Atomic Mn Centers for Oxygen Reduction
ABSTRACT Targeted spin‐state programming remains a key yet challenging route to boost transition‐metal oxygen reduction reaction (ORR) catalysis. Here, we report...
Reshaping Chiral Self‐Assemblies Through Alkyne‐Involved Click Chemistry
ABSTRACT Highly efficient click reactions in the solid state or space‐confined condition potentially induce in situ compositional and structural evolution, offering opportunities for...