Angewandte Chemie International Edition
Articles in this Issue
Asymmetric Coordination in Cobalt Single‐Atom Catalysts Enables Fast Charge Dynamics and Hierarchical Active Sites for Two‐Stage Kinetics in Photodegradation of Organic Pollutants
Abstract Single‐atom catalysts (SACs) have attracted growing interest in solar‐driven catalysis, though challenges persist due to symmetrical metal coordination,...
Synthesis and Modification of Formate Zr‐MOF (ZrFA) Toward Scalable and Cost‐Cutting Gas Separation
Abstract The mass production of metal‐organic frameworks (MOFs) with affordable cost is highly demanding yet limited for commercial applications, e.g., purificat...
On the Mechanism of Soft Self‐Assembly from Melt: The Ubiquitous Heat Capacity Hump and Spontaneous Melt Chirality
Abstract We investigate two unusual phenomena in self‐assembly of anisotropic molecules from isotropic (Iso) melt: a heat‐capacity ( C...
Inside Back Cover: A Simple Quinoid Building Block for Polymer Semiconductors with Tunable Polarity and High n‐Type Thermoelectric Performance (Angew. Chem. Int. Ed. 28/2025)
Machine Learning Reveals In‐Cavity Versus Surface Activity for Selective C─H Borylation by Metal‐Organic Framework Catalysts
Abstract Metal‐organic frameworks (MOFs) provide an expansive and tunable platform for heterogeneous catalysis, yet distinguishing between catalytic reactions oc...
High‐Entropy Sulfides Catalyze Rate‐Determining Redox in Fast‐Charging Aqueous Zinc–Sulfur Batteries
Abstract The sluggish kinetics of the solid–solid Zn–S redox process significantly hinders the practical energy density and lifespan of fast‐charging aqueous Zn–...
From Binary to Higher‐Order Organic Cocrystals: Design Principles and Performance Optimization
Abstract Organic cocrystals, particularly the evolution from binary to higher‐order structures, have garnered considerable attention due to their tunable intermolecular interactions...
High‐Performance Perovskite Solar Cells via 3D Covalent Organic Frameworks: Enhanced Efficiency Through Precision Interface Engineering
Abstract Covalent organic frameworks (COFs), a class of porous polymers with tunable 2D or 3D structures, have drawn significant attention for their exceptional versatility across va...
Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry
Abstract Organoboronic acids impact numerous fields of application from organic synthesis to drug discovery and materials science. However, their highly polar nature makes them chall...
Regulating Ion Transport Through Direct Coordination in Composite Gel Polymer Electrolytes Toward High‐Voltage and High‐Loading Quasi‐Solid‐State Lithium Metal Batteries
Abstract Poly(ethylene oxide)‐based composite gel polymer electrolyte is widely used in lithium metal batteries to address dendrite growth and side reactions. Ho...
Chiral Spirobipyridine Synthesis by Cobalt‐Catalyzed Enantioselective Double [2 + 2 + 2] Cycloaddition
Abstract Chiral spirobiindanes are recognized as the privileged structures in the field of asymmetric catalysis. However, the structurally similar chiral spirobi...
Energy‐Efficient Hydrogen Generation via Peroxide‐Mediated Electrocatalytic Pathways
Abstract Hydrogen (H 2 ) production through water electrolysis is a promising route for sustainable energy storage. Howev...
Constructing Ionic Transport Network via Supramolecular Composite Binder in Cathode for All‐Solid‐State Lithium Batteries
Abstract Binders play a pivotal role in maintaining the structural integrity and stability of electrodes. However, conventional polyvinylidene fluoride binder wi...
Supramolecular Charge‐Transfer Approach for Tunable and Efficient Circularly Polarized Delayed Fluorescence and Phosphorescence
Abstract Achieving efficient circularly polarized luminescence (CPL) with a high luminescence dissymmetry factor (|g lum...
Mechanistic Insights into Cation Effects in Electrolytes for Electrocatalysis
Abstract Traditional understanding of electrocatalytic reactions has primarily focused on the covalent interactions between adsorbates and catalyst surfaces, oft...
On‐Demand Ligate and Release Strategy Based on Photoclick Reaction in Tandem with Pd‐Mediated Deallylation
Abstract The development of chemoselective tools that can conjugate, modify, and decouple chemical groups from biomacromolecules has enabled the study of biological processes at incr...
Design of Intrinsically Stable Hole‐Selective Self‐Assembled Monolayers by Introducing Fused‐Ring Intramolecular Donor–Acceptor Interactions
Abstract Hole‐selective self‐assembled monolayers (SAMs) incorporating electron‐donating conjugated units as head groups have witnessed remarkable success in helping achieve high‐per...
Hierarchically Self‐Assembled Anion‐Coordination‐Driven Gels for Guest Segregation and Electrical Sensing
Abstract The search for macroscopic materials with differentially addressable spaces based on molecular containers has long been driven by their great potential...
Development of an Organoautocatalyzed Double σ‐Bond C(sp <sup>2</sup> )‐N Transamination Metathesis Reaction
Abstract The transamination reaction, which involves the conversion of one amine to another, traditionally relies on biological enzyme catalysts. Although chemis...
Red and Near‐Infrared Emissive Organic Crystals: Molecular Design and Optoelectronic Applications
Abstract Red‐emissive organic materials play a pivotal role in optoelectronics, including displays, optical communications, organic lasers, and biomedicine, owing to their high penet...
Valence Tautomerism and Alkaline Properties of Global Aromatic Imine‐ and Methine‐Bridged all‐Benzenoid Macrocyclic Superpyrazine and Supertriazine
Abstract The comprehensive understanding of the ground‐state electronic structures of all‐benzenoid macrocycles and their charged species, particularly those exh...
Mechanosensitive Conjugated Oligoelectrolytes for Visualizing Temporal Changes in Live Cells
Abstract Membrane‐intercalating conjugated oligoelectrolytes (COEs) are lipid‐bilayer‐spanning molecules that serve as fluorescent dyes for bioimaging. However,...
Intrinsically Luminescent Nematic Liquid Crystals Enabling High‐Brightness Full‐Color and White Circularly Polarized Luminescence via Chiral Coassembly
Abstract Circularly polarized luminescence (CPL) materials with simultaneous high dissymmetry factor ( g lum...
Hydrogen‐Bonded Organic Framework with Desolventization and Lithium‐Rich Sites for High‐Performance Lithium Metal Anodes
Abstract Effectively managing Li + migration behaviors and addressing the issues of side reactions at the electrolyte–ele...
Lysine‐Targeting, Covalent Inhibitors of Bromodomain BD1 of BET Proteins in Live Cells and Animals
Abstract The bromodomain extra‐terminal (BET) family of proteins are valuable therapeutic targets for cancer and other diseases. The adverse events of current pa...