Angewandte Chemie International Edition
Articles in this Issue
Metal‐Free Divergent Hydroboration/Multiboration of Terminal Alkynes via Markovnikov Pathway
Abstract Hydroboration/multiboration of alkynes has been considered a straightforward route for the construction of high‐value alkenylboronates and multiborylalk...
Polyphosphorus Ligand Complexes of Coinage Metals for Multiple Capturing of Intact P <sub>4</sub> Tetrahedra
Abstract Two‐ and three‐component self‐assembly reactions of [Cp R Fe(η 5 ‐P...
Supramolecular TADF Materials from Calix[3]Acridan and Guest‐Linked Polymers for Rapid and Visual Detection of Trace Benzene
Abstract In this work, a new strategy for rapid and visual detection of trace benzene vapor was reported by utilizing supramolecular thermally activated delayed...
Silylchromium‐Catalyzed Selective Semihydrogenation of Undirected Allenes by Sila‐Metalation and β‐Silyl Elimination
Abstract The semihydrogenation of simple allenes remains an issue because of the difficulty in controlling of selectivity without coordination assistance from di...
Boosting Initial Coulombic Efficiency in Li‐Rich Mn‐based Cathodes by Tuning Orbital Hybridization
Abstract Li‐rich manganese‐based oxides (LRMO) are promising cathode materials for next‐generation lithium‐ion batteries due to their high‐capacity and low‐cost...
Inside Front Cover: Hierarchically Self‐Assembled Anion‐Coordination‐Driven Gels for Guest Segregation and Electrical Sensing (Angew. Chem. Int. Ed. 28/2025)
Unexpected Redox Role of WO <sub>3</sub> in V <sub>2</sub> O <sub>5</sub> ‐WO <sub>3</sub> /TiO <sub>2</sub> Catalysts for Selective Reduction of NO by Forming V–W Dinuclear Sites
Abstract Promoters can greatly improve the activity of catalysts; however, the mechanism by which they interact with the primary catalyst to enhance catalytic ac...
Thioamides Adjacent to the Ionizable Amine Headgroup in Ionizable Lipids Reduce the p <i>K</i> <sub>a</sub> of Lipid Nanoparticles and Enhance mRNA Transfection Efficiency in Vitro and in Vivo
Abstract Lipid nanoparticles (LNPs) are currently the most clinically advanced mRNA delivery vectors. However, optimizing LNPs for in vivo applications remains l...
Light‐Triggered CRISPR/Cas12a for Genomic Editing and Tumor Regression
Abstract A photo‐triggered CRISPR/Cas12a machinery for in vitro and in vivo gene editing is introduced. The system consists of a caged, inactive...
Frontispiece: Whole‐Cell Lysosome SMLM Imaging as Indicators for Functional Diagnostics with a Low‐Phototoxic Spontaneously Blinking Probe
Local Atomic Off‐Centering Mediated Efficient Self‐Trapped Excitonic Emission in Cs <sub>5</sub> Cu <sub>3</sub> Cl <sub>6</sub> I <sub>2</sub> Nanoplates
Abstract Cu(I)‐based low‐dimensional metal halides have received significant recognition attributable to their intriguing optoelectronic properties, which instig...
Unveiling Zinc Stripping and Molecular Engineering for High‐Performance Zinc Anode
Abstract The unstable zinc anode is a key challenge limiting the cycle life of rechargeable zinc‐ion batteries. The current research primarily focuses on the zin...
Frontispiece: Cost‐Effective and Low‐Carbon Scalable Recycling of Waste Polyethylene Terephthalate Through Bio‐Based Guaiacol‐Enhanced Methanolysis
Jas S. Ward
Selective CO Electroreduction to Multicarbon Oxygenates Over Atomically Dispersed Cu–Ag Sites in Alkaline Membrane Electrode Assembly Electrolyzer
Abstract Electrochemical carbon monoxide reduction reaction (CORR) to produce multicarbon (C 2+ ) oxygenates using renewa...
Enantioselective Decarboxylative Acylation of α‐Hydroxy Acids with Carboxylic Acids via Photoredox/Nickel Dual Catalysis
Abstract Light‐driven decarboxylative cross‐coupling has emerged as a pivotal platform for constructing C(sp 3 )–C(sp...
Modulation of Photoluminescence of BODIHY Dye Using Water‐Soluble Coordination Cages With Different Shapes
Abstract The confinement of guest molecules within supramolecular hosts can alter their photophysical properties. However, the shapes of the hosts in regulating...
Harnessing Negative Photochromism in Styryl Cyanines for Light‐Modulated Proton Transport
Abstract Efficient photoswitches capable of complete conversion to their metastable isomer are not so common, yet highly desirable for applications in smart materials and devices. He...
Enantioselective Divergent Cyclization of Amide‐Type 1,6‐Enynes Enabled by H–[Pd]–CN Catalysis
Abstract Enantioselective cyclization of 1,6‐enynes has been extensively developed as it offers an effective way to obtain chiral cyclic compounds. Herein, we re...
Correction to “Carbodicarbene‐Stibenium Ion‐Mediated Functionalization of C(sp <sup>3</sup> )−H and C(sp)−H Bonds”
Tuning Local Proton Concentration and *OOH Intermediate Generation for Efficient Acidic H <sub>2</sub> O <sub>2</sub> Electrosynthesis at Ampere‐Level Current Density
Abstract Electrocatalytic oxygen reduction is a sustainable method for on‐site H 2 O 2...
Interweaving Covalent Organic Polymer Chains Into Two‐Dimensional Networks: Synthesis, Single Crystal Structure, and Application for Stabilizing Lithium Metal Anode
Abstract Macroscopic weaving has been proven to be the most enduring and effective method for manufacturing fabrics to meet the practical needs of humanity for t...
Programming One‐Dimensional Open‐Channel Superlattices with Edge‐Bonding of Meta‐DNA
Abstract The physicochemical properties of one‐dimensional (1D) porous nanomaterials are fundamentally influenced by their channel geometrical and topological characteristics. Howeve...
Phenacetin[3]Arenes: Mannich‐Type Macrocyclization, Unique Structure, Versatile Functionalization, and Strong Allosteric Binding
Abstract This work introduces a novel N Am –CH₂–C Ar macrocyclization pathway, di...
Theodor Förster: Life and FRET from 1933 to 1951. A Viewpoint from the Archives
Abstract FRET stands for Förster resonance energy transfer. While much is known about resonance energy transfer, much less is known about Förster–apart from the...