Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands
R
Ryan M. Kirk
(Research School of Chemistry Australian National University Canberra ACT 2601 Australia)
A
Anthony F. Hill
(Research School of Chemistry Australian National University Canberra ACT 2601 Australia)
Abstract
Abstract Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P ‐heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.
Article Details
Volume / Issue
Vol. 64, Issue 28
Published
July 07, 2025
ISSN
1433-7851
Publisher
Wiley
Authors (2)
R
Ryan M. Kirk
Research School of Chemistry Australian National University Canberra ACT 2601 Australia
A
Anthony F. Hill
Research School of Chemistry Australian National University Canberra ACT 2601 Australia
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