Angewandte Chemie International Edition
Articles in this Issue
Enzyme‐Assisted Confined Synthesis of Metal Nanoparticles in Covalent Organic Frameworks for Efficient Enzyme‐Metal Cascade Catalysis
Abstract The integration of enzymatic and metal catalysis in cascade reactions offers a highly efficient approach for producing high‐value chemicals, such as chiral pharmaceuticals....
Frontispiece: Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition
Dual‐Function Tetrabenzylphosphonium Groups as Mitochondria‐Targeting Artificial Anion Channels
Abstract Artificial ion channels with specific organelle‐targeting capabilities have been scarcely investigated. Here, we report the first‐in‐class mitochondria‐...
Sub‐Ångstrom Pore Engineering in Carbon Molecular Sieves Realizes Diffusion‐Gated Kinetic Sieving of Alkenes from Alkanes
Abstract Sub‐Ångstrom pore engineering offers a new paradigm for molecular separations. Here, we report sucrose‐derived carbon molecular sieves (CMSs) with preci...
Nitrogen Adsorption Sites with Low Polarizability for Benchmark N <sub>2</sub> /CH <sub>4</sub> Separation
Abstract Selective adsorption of N 2 from CH 4 is an industrially promising but c...
Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition
Abstract Flexible covalent organic pillars ( flex ‐COP‐ n...
Structural Basis for a Scaffolding Role of the COM Domain in Nonribosomal Peptide Synthetases
Abstract Nonribosomal peptide synthetases (NRPSs) are multi‐domain enzymes that catalyze the biosynthesis of therapeutically relevant natural products. Efficient...
Near‐Infrared Emissive Molecular Carbons Based on Quadruple [n]Helicenes
Abstract We present a molecular design strategy that combines structural multiplicity and π‐extension on a quaterrylene diimide scaffold to construct efficient n...
Frontispiece: Alkali Metal Cations Impact the Selectivity of Radical‐Mediated Electrochemical C─H Chlorination
Polymorphic α‐Glucans as Structural Scaffolds in <i>Cryptococcus</i> Cell Walls for Chitin, Capsule, and Melanin: Insights From <sup>13</sup> C and <sup>1</sup> H Solid‐State NMR
Abstract Cryptococcus species are major fungal pathogens responsible for life‐threatening infections in approximately a million individuals g...
A Genetically Encoded Homocysteine Precursor to Probe Protein Active Sites and to Addict <i>Escherichia coli</i> to a Noncanonical Amino Acid Directly Involved in Catalysis
Abstract Noncanonical amino acids (ncAAs) incorporated into proteins by stop codon suppression are powerful tools to probe and expand protein structure and funct...
Ag⁺‐Mediated Structural Reconstruction of a Metastable Cu <sub>35</sub> Cluster Toward Cu–Ag Heterometallic Architectures for Superior Electrocatalytic CO <sub>2</sub> ‐to‐Ethanol Conversion
Abstract Controlled structural transformations of metal nanoclusters (NCs) via dynamic bond reorganization provide fundamental insights into cluster reactivity a...
High H <sub>2</sub> Recovery Properties of Carbon Molecular Sieve Membranes with Sub‐Nanometer Precision Derived from Dual Cross‐Linked Polyimide Precursor
Abstract Energy‐efficient purification technologies are essential for advancing a sustainable hydrogen economy. Carbon molecular sieve membranes (CMSMs) have eme...
Integrating Hydrophobic and Hydrophilic Building Blocks for High‐Performance Organic Electrochemical Transistors and Biosensing
Abstract Organic electrochemical transistors (OECTs) with mixed ionic‒electronic transport features have demonstrated significant potential in biosensing applica...
Dual‐Mode Strain Relief via Zinc Acetate Enables High‐Efficiency InP Quantum Dot Light‐Emitting Diodes
Abstract Heteroepitaxial shell growth on quantum dots (QDs) is essential for tailoring carrier dynamics but is often hampered by core–shell interface strain, whi...
Advancing Solid‐State Calcium Batteries: Achieving Fast Ionic Conductivity at Near Ambient Conditions in Calcium Hydridoborates
Abstract All‐solid‐state batteries based on abundant elements, such as calcium, offer a promising route to safer, cheaper, and more sustainable energy storage. H...
Realizing Unconventional Tandem Nitrate Reduction for Efficient Ammonia Electrosynthesis Enabled by Co, Fe Dual‐Site Conjugated Metal Organic Frameworks
Abstract The electrochemical nitrate‐to‐ammonia reduction reaction (NO 3 RR) offers a sustainable route for carbon‐neutra...
Polycation Engineering in Polymeric Metal Halides Enables Tunable and Multicolor Emission from Single Transition‐Metals
Abstract Zero‐dimensional metal halides have emerged as a versatile platform for the development of light‐emitting materials, but achieving tunable or even multicolor emission from a...
Digital‐Twin‐Assisted Insights Into Irreversible Capacity and Activation Strategy Power High‐Loading Solid‐State Batteries
Abstract In solid‐state lithium‐ion batteries, the fraction of active materials involved in electrode electrochemistry reduces with the increase of electrode thickness. Conventional...
Assessing Fluorosulfonyl Pentafluorooxosulfate (FSO <sub>2</sub> –OSF <sub>5</sub> ) Reservoir Capacity: Selective SOF <sub>4</sub> , SO <sub>2</sub> F <sub>2</sub> , and [OSF <sub>5</sub> ] <sup>–</sup> Anion Release
Abstract Herein, the investigation of inorganic reagents containing the pentafluorooxosulfate (OSF 5 ) moiety is presente...
Stretch‐Induced Structural Ordering and Orientation for Tensile Yield Behavior and Anisotropic Optical Property of Molecular Granular Materials
Abstract The densely packed sub‐nm particles, molecular granular materials (MGMs), represent a new class of functional materials that deliver distinct mechanical properties from poly...