Angewandte Chemie International Edition
Articles in this Issue
Access to Chiral Cyclic β‐Enaminones via Enantioselective Imine Condensation
Abstract We report herein an unprecedented catalytic enantioselective synthesis of cyclic β‐enaminones from simple meso‐1,3‐diketones via chiral phosphoric acid‐catalyzed desymmetriz...
Synthesis and Reactivity of a Mono‐Coordinated Triplet Bismuthinidene
Abstract The triplet bismuthinidene Ar*Bi ( 4 ) stabilized by a very bulky septiphenyl ligand (Ar* = 3,5‐...
Versatile Halide‐Pair‐Driven Multicomponent Polymerization for Library Synthesis of Sequence‐Controlled Semiconducting Dendronized Polymers
Abstract Sequence‐controlled semiconducting polymers represent a new frontier in organic electronics, where precise molecular sequence directly dictates device performance. However,...
Molecular Engineering of Plant Polyphenols Into Amorphous Room‐Temperature Phosphorescent Materials
Abstract Room‐temperature phosphorescent (RTP) materials have potential applications in optoelectronics and bioimaging but encounter significant challenges. Traditional heavy‐metal‐b...
A Robust Nickel‐Interlocked π‐Conjugated Covalent Organic Framework Catalyst for Photocatalytic Aromatic Finkelstein and Retro‐Finkelstein Reactions
Abstract Covalent organic frameworks (COFs) are emerging as a versatile class of hosts for heterogeneous photocatalysis. Herein, we present a nickel‐decorated py...
Sub‐1 nm CuO‐Phosphomolybdic Acid Nanosheets for Ultrasound‐Controlled Pyroptosis Activation and Tumor Immunotherapy
Abstract Inducing pyroptosis effectively transforms immunosuppressive “cold tumors” into immunogenic “hot tumors” to enhance tumor immunotherapy. However, uncont...
Spinel‐Layered Heterostructure Enables Reversible Oxygen Redox in Lithium Manganese Oxide
Abstract Lithium‐rich manganese‐based layered oxides (LRMOs) have emerged as promising cathode materials for next‐generation lithium‐ion batteries (LIBs), primar...
Molecular Rotors as Reactivity Probes: Predicting Electrophilicity from the Speed of Rotation
Abstract A new empirical electrophilicity reactivity parameter, E RB...
A Multistate Adaptive System of Topologically Distinct Chiral Assemblies
Abstract Biological systems exemplify the extraordinary adaptability of living organisms to their surroundings, demonstrating the capacity to reconfigure their structure, properties,...
Gang‐Wei Wang
Highly Structure‐Selective On‐Surface Synthesis of Isokekulene Versus Kekulene
Abstract The role of different facets of metal nanoparticles in steering reaction pathways is crucial for the design of heterogeneous catalysts with superior selectivity. As a promin...
Enhanced Nonlinear Optical Response and Self‐Powered CPL Detection in Unique Triangular–Tetrahedral Chiral Copper(I) Halides
Abstract The low‐coordination polyhedral architecture of Cu(I)‐based chiral metal halides induces significant structural distortions, endowing these materials wi...
Engineered Nanofluidics for Molecular Recognition and Physical Perception
Abstract Nanofluidics has garnered significant attention as the ultra‐sensitive method for molecular recognition and physical perception that are not easily accessible through the tr...
Hybrid Active Sites in Coordination Polymers Enable Ampere‐Level Acetylene Semihydrogenation in Membrane Electrode Assembly Systems
Abstract Electrocatalytic acetylene semihydrogenation in membrane electrode assembly systems promises a sustainable pathway for ethylene production, yet faces ch...
Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains
Abstract Partial fluorination of oxides has positioned oxyfluorides as a promising class of nonlinear optical (NLO) materials owing to their balanced optical pro...
On‐Demand Photodegradable and Thermo‐Reversible, Soft, Transparent Dithioacetal Hydrogels
Abstract Stimuli–reversible, chemically cross‐linked polymers capable of altering their physicochemical and mechanical properties on demand, upon application of...
Universal Chemical Presodiation Under Air Condition for Highly Stable Na‐deficient Oxide Cathodes
Abstract Layered transition‐metal oxides have attracted growing attention for sodium‐ion batteries (SIBs); however, their application is hindered by low initial...
Designing New Natural‐Mimetic Phosphatidic Acid: A Versatile and Innovative Synthetic Strategy for Glycerophospholipid Research
Abstract Glycerophospholipids (GPLs) play important roles in cellular compartmentalization and signaling. Among them, phosphatidic acids (PA) exist as many distinct species depending...
Iron‐Catalyzed Carbonylation Reactions with Carbon Monoxide
Abstract The utilization of carbon monoxide (CO) as an inexpensive and indispensable C 1 feedstock for the efficient cons...
Transfer Learning‐Assisted SERS: Predicting Molecular Identity and Concentration in Mixtures Using Pure Compound Spectra
Abstract Identifying and quantifying compounds in unknown mixtures represents the ultimate goal of surface‐enhanced Raman scattering (SERS) spectroscopy but remains a significant cha...
Photocontrolled Release of Urea Enables the Detection of Urea–Urease Intermediates by Cryo‐FTIR
Abstract Caged compounds are a valuable tool to photocontrol the release of enzymatic substrates in a reaction. For example, caged urea molecules were proposed to control urea delive...
Correction to “Development of an Automated Workflow for Screening the Assembly and Host–Guest Behavior of Metal‐Organic Cages Towards Accelerated Discovery”
Engineering PdAu/CeO <sub>2</sub> Alloy/Oxide Interfaces for Selective Methane‐to‐Methanol Conversion with Water
Abstract The direct conversion of methane‐to‐methanol remains a critical challenge in methane valorization. In this study, we unveil the crucial role of PdAu/CeO...
Qian Zhao
Reversible Structural Oscillation Mediates Stable Oxygen Evolution Reaction
Abstract The dynamic dissolution of active species of electrocatalysts suffers severe durability issues, thus limiting practical sustainable electrochemical appl...