Angewandte Chemie International Edition
Articles in this Issue
<i>tert</i>‐Butyl Functionalized Ultra‐Microporous Three‐Dimensional Covalent Organic Framework for Efficient SF<sub>6</sub>/N<sub>2</sub> Separation
AbstractEfficient capture and recovery of sulfur hexafluoride (SF6) from SF6/N2 mixtures is critical for mitigating greenhouse effects and promoting gas recycling in the electronics industry. Herein,...
Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa‐Cationic Organic Cages
Abstract Most metal organic cages are assembled through metal–ligand coordination, resulting in cages where the metal ions are part of the cage architecture, and thus have limited re...
X‐ray‐Irradiated Polarized Emission in Mn(II) Bromide Hybrids with Chain‐Like Alignment of Halopyridine and Polar MnBr<sub>4</sub><sup>2−</sup> Units
AbstractMn(II) halide hybrid crystals possess exceptional emission properties and pronounced anisotropic optoelectronic characteristics, making them highly promising for diverse applications. In this...
Confining the Node Accessibility of Zr‐MOFs Along One‐Dimensional Channels Toward High Water‐Vapor Cycle‐Stability
AbstractZirconium‐based MOFs (Zr‐MOFs) with high hydrolytic stability are promising materials for water‐adsorption‐related applications. However, besides hydrolytic stability, cycling stability is als...
Identification of a Selective YTHDF1 Inhibitor Targeting the m<sup>6</sup>A Recognition Domain for Breast Cancer
AbstractAs a key N6‐methyladenosine (m6A) reader, YTH domain‐containing family protein 1 (YTHDF1) promotes protein synthesis by recognizing m6A‐modified mRNA, and its abnormal expression is closely re...
Solvent Polarity Triggered Rapidly Reversible Quadruple‐Mode Luminescence Adjustment in 0D Hybrid Antimony Halides
AbstractZero‐dimension (0D) organic‐inorganic hybrid metal halides are highly attractive as smart responsive luminescent materials, but the multiple‐mode luminescence switch is rarely achieved and int...
Angstrom‐Scale Triangular Pore in Single‐Layer Hexagonal Boron Nitride Membrane for Molecular Sieving
AbstractSingle‐layer crystalline films are ideal separation membrane materials because their atomic thickness could yield the highest possible molecular flux once nanopores are generated. However, the...
Tibor Szilvási
Lewis–Brønsted Dual Acid Sites in WO<sub>3‐</sub><i><sub>x</sub></i> Catalysts Facilitate Direct Photocatalytic Hydrodeoxygenation of Hydroxy Groups in Alcohols
AbstractEfficient hydrodeoxygenation (HDO) of the hydroxy groups (C─OH) in alcohol molecules has attracted substantial attention due to its importance in many research fields such as organic synthesis...
Ambient Processing of High‐Efficiency Organic Solar Modules Enabled by Radical Scavengers
AbstractThe pronounced efficiency disparity between ambient‐air‐fabricated organic solar cells (OSCs) and nitrogen‐glovebox‐processed devices poses a major obstacle to industrial‐scale manufacturing....
Convenient Production of Photothermal Recycling Phosphorescent Materials from Cellulose and Lignin
AbstractDeveloping recyclable room‐temperature phosphorescent (RTP) films using ultrafast fabrication techniques remains a critical yet challenging objective. With this research, we developed an RTP f...
Self‐Assembled Homogeneous Heterobimetallic‐Oxide Interfaces Enable Synergistic Hydrogen Evolution Passivation for Durable Acidic Zn–Mn Batteries
AbstractAcidic Zn–Mn batteries hold promising prospects in large‐scale energy storage owing to their higher discharge voltage and capacity. However, the challenge of developing long‐term acidic Zn–Mn...
Modeling Midbrain and Brainstem Neuromelanins to Characterize Metal Binding and Associated MRI Contrast in Parkinson's and Alzheimer's Diseases
AbstractNeuromelanin (NM) is a dark pigment that binds potentially toxic metal ions and is crucial for neuronal vulnerability. Magnetic resonance imaging (MRI) was proposed to measure neuromelanin in...
Balancing Solvation Ability of Polymer and Solvent in Gel Polymer Electrolytes for Efficient Lithium Metal Batteries
AbstractGel polymer electrolytes (GPEs) show practical potential in lithium metal batteries (LMBs), but their development is hindered by insufficient understanding of Li+ solvation chemistry and its i...
Electric Field‐Insensitive Solvation Chemistry Stabilizes High‐Voltage Lithium Metal Batteries
AbstractEther based electrolytes are promising for the realization of lithium (Li) metal batteries (LMBs). However, the oxidation chemistry of these electrolytes stemming from the disruption to solven...
Covalent Organic Framework Nanohydrogel‐Based Oxidase‐Mimicking Nanozyme for Photocatalytic Antibacterial Therapy
AbstractWater‐soluble nanozymes have the potential to overcome the limitations of low catalytic efficiency of most heterogeneous nanozymes in aqueous solutions and further expand their applications in...
Fulcrum Occupancy–Leverage Perturbation Strategy Enables Rapid Discovery of Potent CDK2–Cyclin A2 Interaction Inhibitors
AbstractTraditional strategies for developing small‐molecule inhibitors of protein–protein interactions (PPIs) are time‐consuming and often yield low success rates due to the flat and dynamic interfac...
Thermodynamic Feedback Mechanisms for Mitigating Polarization in Lithium‐Ion Batteries
AbstractThe performance of lithium‐ion batteries (LIBs) is intrinsically determined by the interplay between the kinetic and thermodynamic processes, which jointly govern the polarization dynamics acr...
Photocatalytic Co‐Reduction of CO<sub>2</sub> and Nitrate over Porphyrin Metal–Organic Frameworks: Dual Atomic Active Site and Nanostructure Synergy Enhances C–N Coupling for Urea Production
AbstractThe photocatalytic co‐reduction of NO3− and CO2 (NitRR&CRR) offers a sustainable approach for urea synthesis and environment remediation. However, there is a lack of high‐performance photo...
A Facile and Scalable α‐Diimine Platform for Nickel‐Catalyzed Ethylene Polymerization
AbstractThe structural design and facile synthesis of ligands are crucial for the development of innovative catalysts. Advances have enabled the iterative design of benchmark α‐diimine nickel catalyst...
Freely‐Rotatable Multidentate Molecular Anchor Enables Self‐Adaptive Aqueous Binders for Lithium‐Ion Batteries
AbstractThe rational design and synthesis of reliable binders is a big challenge to efficiently mitigate the severe volume change of silicon‐based anodes for lithium ion batteries. Herein, we report a...
Manipulating the Spin State of Fe Atom to Boost Surface Reaction Kinetics Toward Robust Photocatalytic Hydrogen Evolution
AbstractThe photocatalytic hydrogen evolution (PHE) performance over transition metal catalysts is limited by the unsatisfactory surface catalytic reaction kinetics, which involves the transformation...
Kirkendall Effect‐Driven Interface Engineering Facilitates Water Dissociation for Dual‐Site H<sub>2</sub>O<sub>2</sub> Electrosynthesis Simultaneously at the Anode and Cathode
AbstractThe direct integration of renewable energy into H2O2 electrosynthesis systems offers a promising strategy to minimize energy losses and costs. Due to the intermittency of renewable energy, the...
Visible‐Light‐Driven Iron‐Catalyzed Atom Transfer Radical Addition of CH<sub>2</sub>Br<sub>2</sub> to Alkenes: Facile Access to 1,3‐Dibromo Compounds
AbstractAn efficient visible‐light‐mediated iron‐catalyzed atom transfer radical addition (ATRA) reaction between CH2Br2 and various alkenes has been developed. This transformation provides direct acc...