Angewandte Chemie International Edition
Articles in this Issue
Dienoic‐Acid Coupling Effect Induced Hierarchical Interface for High‐Performance Zinc Metal Batteries
AbstractRational pre‐design of self‐decomposed electrolyte additives to construct solid electrolyte interphase (SEI) for suppressing hydrogen evolution reaction (HER) and dendrite growth of zinc (Zn)...
Accessing Metal‐Containing Species in Tin–Lead Perovskite Precursor Solutions via Molecular Strategies Guided by the Hard–Soft Acid–Base Principle
AbstractThe properties of metal‐centred species in metal halide perovskite precursor solutions substantially influence the formation and evolution of colloidal particles, which in turn dictate the cry...
Time‐Resolved Spectroelectrochemical Observation of Overlayer‐Induced Charge Carrier Dynamics in Water Photooxidation
AbstractSurface and interface engineering is essential for constructing efficient and stable photoelectrodes for photoelectrochemical (PEC) solar fuel production. Despite the recent advances in photoe...
Frontispiece: Abnormal Anti‐Kasha Emission and TADF in Anionic Cycloarylenes
Synergistic Regulation of Electrolyte and Electrode Structures Enhance Ammonium Vanadate Mg‐storage Performance for 100 mAh‐Level Mg‐ion Pouch Cells
AbstractAqueous Mg‐ion batteries (AMIBs) have attracted increasing interest due to their safety, fast kinetics, and sustainability. However, the development of AMIBs is hindered by the narrow electroc...
A General Strategy to Develop Highly Sensitive FAPα Fluorescent Probes for Invasive Cancer Detection
AbstractFibroblast activation protein α (FAPα) has been reported to be expressed in many carcinoma cells and associated with tumor growth, invasive, and metastasis. However, due to the lack of appropr...
Super‐Resolution Axial Imaging for Quantifying Piconewton Traction Forces in Live Cells
AbstractCell mechanics play a pivotal role in regulating numerous biological processes. Although super‐resolution microscopy enables the imaging of cellular forces in the lateral dimension with sub‐10...
Abnormal Anti‐Kasha Emission and TADF in Anionic Cycloarylenes
AbstractIncorporation of non‐benzoid rings into cycloarylenes significantly alters their molecular geometry and optical behavior. Recently, we synthesized two ferrocene‐doped cycloarylenes, (CpFe)3‐1...
Design and Preparation of Self‐Adaptive and Robust Solid‐State Elastomeric Electrolyte for Lithium Metal Battery Inspired by Rubber Tire
AbstractThe development of safe, high‐performance solid‐state electrolytes remains a central challenge for advancing lithium metal batteries (LMBs) toward practical deployment. Inspired by the durable...
Three‐in‐One π‐Conjugated Chiral Macrocycles: Photoswitching, Amplified Chirality, and Photo‐Tailored Chiroptics
AbstractChiral macrocycles have attracted considerable attention because of their fascinating circular chiral topologies, circularly distributed electronic structures, and excellent chiroptical featur...
Design and Synthesis of Box[6]arenes for 3D Charge‐Transfer Co‐Crystal Engineering via Macrocyclic Self‐Complementary and Exo‐Wall Interactions
AbstractThe construction of well‐defined 3D charge‐transfer (CT) co‐crystals using new macrocyclic hosts to enable programmable functionality remains challenging due to the dimensional constraints imp...
Pd‐Catalyzed Stereospecific and Ligand‐Controlled Regiodivergent Suzuki–Miyaura Cross‐Coupling for the Synthesis of 3‐<i>C</i>‐Glycals and 2,3‐Unsaturated <i>C</i>‐Glycosides
AbstractThe selective modification of carbohydrates to achieve structural complexity has emerged as a crucial strategy in carbohydrate‐based drug development. However, the intricate stereochemistry an...
Stereoselective Self‐Assembly of a Topologically Chiral [6]Catenane with 18 Crossings
AbstractMechanically interlocked molecules (MIMs) exhibit unique properties and functions arising from their structural entanglement, features of which are absent in their individual components. Howev...
Tailoring Low‐Miller‐Index Crystal Facets Realizes Perovskite Solar Cells with Flat Grain‐boundary Grooves
AbstractCharge transport and nonradiative recombination loss at the buried interface are important factors, which limit the efficiency and stability of perovskite solar cells (PSCs). Herein, we screen...
Bidirectional Electron Relay at TiN‐TiO<sub>2</sub> Interfaces Enables Oxidation‐Resistant Ru for High‐Potential Hydrogen Oxidation Catalysis
AbstractRuthenium‐based catalysts are pivotal as cost‐effective alternatives to Pt for alkaline hydrogen oxidation reaction (HOR). However, they typically face irreversible deactivation above 0.2 V vs...
Perfluoroalkyl Hybrid Ethylene Glycol Side Chains: A Solution to Water Related Challenges in n‐Type Organic Mixed Ionic‐Electronic Conductors
AbstractThe water molecule is regarded as a double‐edged sword in organic mixed ionic‐electronic conductors (OMIECs), particularly for n‐type semiconductors. On the one hand, hydration facilitates ion...
White Circularly Polarized OLEDs Enabled by Orthogonal Engineering of Achiral Thermally Activated Delayed Fluorescence Emitters and Chiral Assemblies
AbstractThe development of white circularly polarized organic light‐emitting diodes (CP‐OLEDs) faces a critical challenge in simultaneously achieving high external quantum efficiency (EQE) and large d...