Angewandte Chemie International Edition
Articles in this Issue
Mechanical Constraints Promote Noncanonical Base‐Pairing Interactions
Abstract Mechanical perturbations profoundly influence nucleobase interactions in cells, serving as key modulators of fundamental cellular processes such as transcriptional regulatio...
Machine Learning‐Driven Automated Synthesis of Polysubstituted Gentisaldehydes
Abstract Gentisaldehyde is a fundamental motif with broad applications in pharmaceuticals. However, the construction of such molecules is time‐ and cost‐intensive with low step effic...
Self‐Adaptive Interface Reconstruction over Black Phosphorus Complex for Wide‐Temperature and Fast‐Charging Potassium Ion Storage
Abstract Black phosphorus (BP), exhibiting a large spatial layer and high theoretical capacity, has been heralded as a promising candidate for K...
Hyperbranched Oxime‐Ester Covalent Adaptive Network for Recyclable Ultralow‐Dielectric Epoxy
Abstract Epoxy thermosets are indispensable in high‐frequency (5G/6G) electronics, but their permanent crosslinks hinder recyclability and worsen e‐waste. Althou...
Functionalization of Polyolefins via Catalytic Nitrene Addition
Abstract The post‐polymerization functionalization of polyolefins has emerged as a key tool for obtaining new materials with enhanced properties. With an array o...
An Atomically Precise Ru <sub>1</sub> Au <sub>6</sub> (TBBT) <sub>6</sub> (PPh <sub>3</sub> ) <sub>6</sub> Cluster Catalyst for Ammonia Production
Abstract Only one active site in a catalyst is not able to handle a deal of multitasking at once to facilitate distinct elementary steps in a catalytic cycle. To...
Proton Alloying in an Organic‐Inorganic Hybrid Material Enables Unusual Dynamic Birefringence and Martensitic Actuation
Abstract Alloying is widely recognized as an effective strategy for enhancing or unlocking material properties by combining different elements. Organic‐inorganic...
Mechanically Robust Bilayer Solid Electrolyte Interphase Enabled by Sequential Decomposition Mechanism for High‐Performance Micron‐Sized SiO <sub>x</sub> Anodes
Abstract Micron‐sized Si‐based materials are promising anodes due to their high capacity, low cost, and ease of production, yet in application they suffer from s...
Artificial Decision Tree Guided Screening of Ultralong Room‐Temperature Phosphorescent Cocrystals with Locally Excited States
Abstract High‐throughput screening of ultralong room‐temperature phosphorescence (RTP) systems is essential for advancing photofunctional materials. Among molecu...
A Universal pH Regulation Principle for HER Suppression in Aqueous Metal Batteries
Abstract Hydrogen evolution reactions (HERs) pose a formidable challenge to rechargeable aqueous metal batteries (AMBs), causing flammable gas accumulation and i...
Biosynthesis of the Biphenomycin Family of Potent Antibiotics
Abstract Peptide natural products are important molecules for the development of efficient drugs for human health applications. The biphenomycins are bacterial m...
Cooperative Brønsted Acid and Photo‐Promoted Stereoselective Synthesis of Substituted Piperidones
Abstract Saturated nitrogen heterocycles are highly prevalent in medicinal chemistry, agrochemistry, and material science. Despite extensive research to access s...
Unconventional Inverse Size‐Effects Enable Efficient C–N Coupling on Copper Electrocatalysts
Abstract Exposed coordinatively unsaturated sites (CUS) with the reducing geometrical sizes of catalysts commonly offers significant advantages in heterogeneous...
Optimizing *CO/CO Supply by Atomically Dispersed Fe Sites for High‐rate CO <sub>2</sub> ‐to‐C <sub>2</sub> H <sub>4</sub> Conversion Under Visible Light
Abstract Visible light driven carbon dioxide (CO 2 ) reduction to ethylene (C 2 H...
Pentagonal/Heptagonal‐Lock Strategy Enables Narrowband Red Multiple Resonance Emitters Through Temperature‐Controlled Scholl Reaction
Abstract Although π‐extension has shown considerable success in achieving red‐shifted emission in multiple resonance (MR) emitters, it often induces substantial spectral broadening,...
Electrocatalytic Alcohol Oxidation to Aldehyde Through Direct Dehydrogenation Mechanism Using a High‐Performance Pt/Co <sub>3</sub> O <sub>4</sub> Catalyst
Abstract The electrocatalytic upgrading of low‐value carbon sources has been widely regarded as a green approach for synthesizing diverse chemicals and promising...
Chiral Plasmonic Sensors: Fundamentals and Emerging Applications
Abstract Chiral plasmonic sensors have emerged as powerful tools for the enantioselective detection of biomolecules, addressing key limitations of conventional techniques such as cir...
Hemi‐Indigiosin: A pH and Red‐Light Responsive Transmembrane HCl Transporter
Abstract Synthetic anion transporters have emerged as promising therapeutic agents. However, their targeting ability is still low. Herein, we present hemi‐indigi...
Crystallographic Study of DNA T‐Junction via Crystal Engineering
Abstract Engineering DNA crystals is the primary motivation for structural DNA nanotechnology. Among many potential applications, such crystals promise as a platform to precisely (in...
Achieving Charge‐Transfer from the Boron‐Vertices of <i>o</i> ‐Carborane: Dual‐Emission with a Shift of 505 nm (2.1 eV)
Abstract The boron‐vertices of o ‐carborane have long been considered to be inert in conjugation with π‐substituents. Her...
Molecular Design and Redox Chemistries for Aqueous Organic Redox Flow Batteries (AORFBs)
Abstract Aqueous organic redox flow batteries (AORFBs), utilizing redox‐active organic materials as energy storage materials, represent a promising frontier for sustainable long‐dura...
Microemulsion Engineering Reconciles Propylene Carbonate Electrolytes and Graphite Anodes for All‐Climate Lithium‐Ion Batteries
Abstract Propylene carbonate (PC)‐based electrolytes are promising for all‐climate lithium‐ion batteries due to their wide liquid range. However, detrimental Li...
Asymmetric Carbenoid Allylic C─H Alkylation of α‐Olefins Using Tailored Chiral Indenyl‐Rhodium Catalysts
Abstract Alpha (α)‐olefins represent cornerstone feedstocks in the chemical industry, offering a versatile platform for enhancing molecular complexity from readily available precurso...
Ultralow Thermal Conductivity in Layered CuGe <sub>2</sub> Se <sub>3</sub>
Abstract Unraveling the relationship between thermodynamic factors, interatomic interactions, and electronic structure remains a crucial yet elusive challenge in...