Angewandte Chemie International Edition
Articles in this Issue
Dual Electric Fields in Cyclooctatetrathiophene‐Based COF/ ZnIn <sub>2</sub> S <sub>4</sub> Z‐Scheme Heterojunction Boost Photocatalytic Seawater Hydrogen Evolution
Abstract The development of efficient photocatalysts for seawater‐based photocatalytic hydrogen evolution (PHE) represents a crucial step toward sustainable gree...
Environment‐Responsive Self‐Assembly and Coupled‐Network Effect in Dynamic Replicating Nucleopeptide Networks
Abstract The development of complex, adaptive behaviors in chemical systems hinges on the intricate coupling between reaction networks and self‐organizing processes. Self‐assembling...
Enantiodivergent Rh‐Catalyzed Reductive Hydroformylation of Alkenyl Boronic Esters
Abstract We herein report the first enantioselective Rh‐catalyzed reductive hydroformylation of alkenyl boronic esters. By employing either “camouflage” or “dire...
On the Nature of Improper Hydrogen Bonding in RCH <sub>2</sub> F and RCHF <sub>2</sub> Motifs
Abstract The RCH 2 F and RCHF 2 groups are substituents of interest in medicinal...
Ethanol Synthesis by CO <sub>2</sub> Photoreduction Catalyzed by Self‐Optimized Ti <sup>δ+</sup> ‐Based Heterojunction
Abstract Photoreduction of CO 2 to ethanol (C 2 H 5...
Advancing Structure Elucidation with a Flexible Multi‐Spectral AI Model
Abstract Validating chemical synthesis success requires confirming the desired product using various analytical techniques. While spectroscopic data collection is increasingly automa...
Asymmetrically Fluorinated Alkoxysilane Single‐Solvent Electrolytes Enable High‐Voltage and Long‐Cycling Lithium Metal Batteries
Abstract High‐voltage lithium metal batteries with nickel‐rich oxide cathodes (LiNi 0.8 Co 0.1...
Photocatalytic Overall Water Splitting at the Integrated Rh–MoRhO <i> <sub>x</sub> </i> Cluster Heterostructure on InGaN/GaN Nanowires
Abstract The quest for efficient solar‐driven water splitting, a promising avenue for clean fuel production, faces challenges due to limited solar energy convers...
Flexible Single‐Crystalline Perovskite Ferroelectric Thin Film for Efficient Self‐Driven X‐ray Detection
Abstract Flexible X‐ray detectors with a direct‐conversion working mode have attracted tremendous attention in security checks, medical diagnostics, industrial i...
Programmable DNA Nanospheres for Photothermal‐Controlled Intracellular Protein Degradation
Abstract Photothermal‐controlled protein degradation has recently emerged as a promising ubiquitin proteasome‐independent strategy for intracellular protein elimination by inducing l...
Phosphorus‐Enhanced Anodes: A Scalable Solution to Transition‐Metal Ion Crosstalk in High‐Energy Lithium‐Ion Batteries
Abstract Lithium‐ion batteries (LIBs) with high‐voltage transition‐metal (TM) oxide cathodes and graphite and/or silicon anodes are widely recognized for their h...
Mechanically Induced Nickel‐Catalyst Activation in Cross‐Coupling Reactions by Abrasion
Abstract In this study, we unravel the noninnocent role of mechanical abrasion in mechanochemical cross‐coupling reactions catalyzed by nickel salts, demonstrati...
The Biicosahedral Complex Anions [M(B <sub>11</sub> H <sub>11</sub> ) <sub>2</sub> ] <sup>3−</sup> (M = Cu, Ag, Au): Synthesis and Unexpected Low‐Temperature Phase Transition of [Ag(η <sup>5</sup> ‐B <sub>11</sub> H <sub>11</sub> ) <sub>2</sub> ] <sup>3−</sup> to [Ag(η <sup>2</sup> ‐B <sub>11</sub> H <sub>11</sub> ) <sub>2</sub> ] <sup>3−</sup>
Abstract We disclose the synthesis and properties of [M(B 11 H 11 )...
Correction to “Fortification of FeS Clusters Reshapes Anaerobic CO Dehydrogenase into an Air‐Viable Enzyme Through Multilayered Sealing of O <sub>2</sub> Tunnels”
Non‐Fused Carbonyl/Nitrogen Multi‐Resonance Emitters Enable Efficient Pure‐Red Narrowband Electroluminescence
Abstract Multi‐resonance (MR) narrowband emitters are attractive for ultrahigh‐definition displays, but their development is hindered by scarcity of red‐emitting...
Metal‐Phase Protection Suppresses Bi Leaching for Durable Acidic CO <sub>2</sub> Electroreduction to Formic Acid
Abstract The electrocatalytic CO 2 reduction reaction (CO 2 RR) in acidic electro...
Inactivation of the <i>Burkholderia</i> Toxin Malleicyprol by Enzymatic Cyclopropanol Ring Opening
Abstract Pathogenic bacteria of the Burkholderia pseudomallei group cause life‐threatening infections in humans and anima...
Ni‐Catalyzed Electrochemical Carbonylative Ketone Synthesis Employing a Radical Sorting Strategy
Abstract The construction of ketones with bulky units is a long‐standing challenge for established nucleophilic addition or transition‐metal‐catalyzed cross coup...
Semi‐Synthesis of Immunogenic Mycobacterial Lipoproteins via Aryl Selenoester‐Mediated Expressed Protein Ligation
Abstract Tuberculosis (TB), caused by infection with the bacterium Mycobacterium tuberculosis ( Mtb...
Thiol–Ene Photoclick Chemistry for Efficient Bicyclic Peptide Synthesis and Genetically Encoded Peptide Library
Abstract Bicyclic peptides have emerged as privileged scaffolds in chemical biology and drug discovery owing to their high target affinity, enhanced metabolic stability, and rigid co...
Regulating the Li/Ni Mixing Ratio to Enhance Transition Metal‐Lattice Oxygen Interaction for Achieving Long Life Lithium‐Rich Layered Oxides
Abstract Lithium‐rich layered oxides (LLOs) emerge as promising cathode materials for next‐generation high‐performance Li‐ion batteries (LIBs) due to their super...
Local Coordination‐Dependent CO <sub>2</sub> Reduction Activity of Bimetallic Cu─Al Catalysts for Selective Ethylene/Ethanol Electrosynthesis
Abstract The formation of bimetallic catalysts has been widely adopted to improve CO 2 reduction selectivity. However, di...
Three‐Dimensional Covalent Thiazolo[5,4‐d]thiazole Frameworks with sur‐a Topology for Coupling Photoactivation of Oxygen and Biomass
Abstract Developing new topological three‐dimensional (3D) covalent organic framework (COF) structures with strong electron donor–acceptor (D–A) properties repre...
Domain‐Trained Language Model for Inverse Design and Synthesis of High‐Performance Hydrogen Storage MOFs
Abstract A domain‐specific large language model, MOFs‐LLM, is developed to accelerate the inverse design and synthesis of metal—organic frameworks (MOFs) for hydrogen storage. Traine...
Homogeneous SnF <sub>2</sub> ‐Induced Strain Modulation in Sn–Pb Perovskites for High‐Performance Monolithic All‐Perovskite Tandem Solar Cells
Abstract Tin fluoride (SnF 2 ) serves as an indispensable antioxidant in Sn–Pb perovskite solar cells, playing a critical...